Results 181 to 190 of about 17,373 (214)
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Photolysis of Liquid Cyclohexane and Cyclohexane Solutions in the Vacuum Ultraviolet
The Journal of Chemical Physics, 1968Liquid cyclohexane and cyclohexane solutions were photolyzed at 1236 and 1470 Å. The products and quantum yields for cyclohexane photolysis at 1470 Å are hydrogen (1.0), cyclohexene (0.94), dicyclohexyl (0.06), ethylene (0.003) and butadiene (0.001).
Frank M. Servedio+2 more
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Conformational analysis of cyclohexanes diastereoisomerism in disubstituted cyclohexanes
Resonance, 2005The cycloalkanes most commonly found in nature, viz., in some alkaloids, steroids and terpenoids contain six membered rings because they can exist in a completely strain free chair conformation. The fundamental understanding of the conformations of cyclohexane and the structures of molecules containing cyclohexane ring was developed by Derek H R Barton
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The structure of cyclohexane, F-, Cl-, Br- and I-cyclohexane
Journal of Molecular Structure, 1995Abstract The ground state, r0, and the average, r∗ , structures of cyclohexane were determined from the recently reported rotational constants for several isotopic species of cyclohexane. These structures provide a better description of the heavy atom skeleton in cyclohexane than the rs structure and allow an accurate prediction of the ...
E. Białkowska-Jaworska+2 more
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VAPOR-PHASE RADIOLYSIS OF CYCLOHEXANE AND MIXTURES OF BENZENE AND CYCLOHEXANE
Canadian Journal of Chemistry, 1964The vapor-phase radiolysis of cyclohexane and benzene-cyclohexane mixtures has been studied with isotopic tracer techniques using C6D12 and C6D6. Benzene does not quench the molecular detachment of hydrogen, [Formula: see text] but interacts with the second-order processes giving HD in C6D12–C6H12 mixtures.
J. Blachford, P. J. Dyne
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ChemInform, 1989
The reactions of methyl radicals, generated by the photolysis of acetone, with cyclohexane and a number of methyl-substituted cyclohexanes have been studied. The Arrhenius parameters corresponding to overall hydrogen abstraction have been obtained from experiments in the temperature range 100–200 °C based on the value of the rate constant for ...
Kenneth A. Holbrook+2 more
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The reactions of methyl radicals, generated by the photolysis of acetone, with cyclohexane and a number of methyl-substituted cyclohexanes have been studied. The Arrhenius parameters corresponding to overall hydrogen abstraction have been obtained from experiments in the temperature range 100–200 °C based on the value of the rate constant for ...
Kenneth A. Holbrook+2 more
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Spectrochimica Acta Part A: Molecular Spectroscopy, 1973
Abstract A vibrational analysis has been carried out on cyclohexane, cyclohexane-d12, cyclohexane-1, 1,4,4-d4 and cyclohexane-1,1,2,2,4,4,5,6-d8 utilizing the set of 60 internal coordinates (all 18 bond stretches, all 36 valence angle bends and six CCCC torsional bends) that is compatible with the Snyder and Schachtschneider transferable valence ...
Kenneth B. Wiberg, Andrew Shrake
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Abstract A vibrational analysis has been carried out on cyclohexane, cyclohexane-d12, cyclohexane-1, 1,4,4-d4 and cyclohexane-1,1,2,2,4,4,5,6-d8 utilizing the set of 60 internal coordinates (all 18 bond stretches, all 36 valence angle bends and six CCCC torsional bends) that is compatible with the Snyder and Schachtschneider transferable valence ...
Kenneth B. Wiberg, Andrew Shrake
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Proceedings of the Indian Academy of Sciences - Section A, 1935
(1) An apparatus for continuous distillation has been described which works satisfactorily and is free from the defects of the arrangement described by Pal and Sen Gupta.
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(1) An apparatus for continuous distillation has been described which works satisfactorily and is free from the defects of the arrangement described by Pal and Sen Gupta.
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Radiation Chemistry of Cyclohexane: V. Dilute Solutions of Benzene in Cyclohexane
Radiation Research, 1962In a mixture of cyclohexane and benzene exposed to ionizing radiation, the yields of products derived from cyclohexane are much less than would be expected if the decomposition were proportional to the mole fraction of cyclohexane. This result, one of the most striking in radiation chemistry, was first observed in the yields of hydrogen by Schoepfle ...
J. A. Stone, P. J. Dyne
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Ignition of non-premixed cyclohexane and mono-alkylated cyclohexane flames
Proceedings of the Combustion Institute, 2013Abstract Ignition temperatures of non-premixed cyclohexane, methylcyclohexane, ethylcyclohexane, n-propylcyclohexane, and n-butylcyclohexane flames were measured in the counterflow configuration at atmospheric pressure, a free-stream fuel/N2 mixture temperature of 373 K, a local strain rate of 120 s−1, and fuel mole fractions ranging from 1% to 10 ...
Ning Liu+2 more
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Dehydrogenation of cyclohexane.
1965The kinetics and mechanism of the dehydrogenation of cyclohexane to benzene over several supported and unsupported catalysts in the form of pellets and powders was studied in the temperature range of about 200 to 600°C in a flow system. Catalysts used inthe study included several commercial catalysts---platinum on alumina, palladium on alumina, cobalt ...
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