Results 31 to 40 of about 17,650 (294)

Structure and mobility of cyclohexane as a solvent for Trans-Polyisoprene

, 2002
Solutions of {\it trans}$-$polyisoprene in cyclohexane are investigated in atomistic detail at different compositions at two different temperatures. We investigate the influence of polymer concentration on the dynamics of the solvent molecules and the ...
Faller, Roland
core   +1 more source

Synthesis of selectively fluorinated cyclohexanes : the observation of phenonium rearrangements during deoxyfluorination reactions on cyclohexane rings with a vicinal phenyl substituent [PDF]

, 2015
A study focused on the synthesis of a derivative of all-cis phenyl-2,3,5,6-tetrafluorocyclohexane, incorporating a methyl group at the benzylic position, found that the fluorination reactions of diepoxide and diol precursors, were susceptible to ...
Al-Maharik, Nawaf, Bykova, Tanya, O'Hagan, David, Slawin, Alexandra Martha Zoya   +3 more
core   +1 more source

Is the Ring Conformation the Most Critical Parameter in Lipase-Catalysed Acylation of Cycloalkanols? [PDF]

, 2004
Financial support of this work by the Spanish Ministerio de Ciencia y Tecnología (Project No. PPQ-2001-2683) and by Principado de Asturias (Project No.
Gotor Santamaría, Vicente Miguel, Lavandera García, Iván, Levy, Laura Mariana   +2 more
core   +2 more sources

Fluorinated liquid crystals: evaluation of selectively fluorinated facially polarised cyclohexyl motifs for liquid crystal applications [PDF]

, 2016
The authors thank the European Research Council for and Advanced Grant and DO’H acknowledges the Royal Society for a Wolfson Merit Award.This paper explores the synthesis of a series of prototype negative dielectric liquid crystalline (LC) compounds ...
Al-Maharik, Nawaf, Cordes, David B., Kirsch, Peer, O'Hagan, David, Slawin, Alexandra M. Z.   +4 more
core   +1 more source

Synthesis of 2,3-dihydronaphtho[2,3-d][1,3]thiazole-4,9-diones and 2,3-dihydroanthra[2,3-d][1,3]thiazole-4,11-diones and novel ring contraction and fusion reaction of 3H-spiro[1,3-thiazole-2,1'-cyclohexanes] into 2,3,4,5-tetrahydro-1H-carbazole-6,11-diones

Beilstein Journal of Organic Chemistry, 2013
Treatment of N-substituted 2-(methylamino)naphthoquinones 3 and -anthracene-1,4-diones 4 with S2Cl2 and DABCO in chlorobenzene gave the corresponding 2,3-dihydronaphtho[2,3-d][1,3]thiazole-4,9-diones 1 and 2,3-dihydroanthra[2,3-d][1,3]thiazole-4,11 ...
Lidia S. Konstantinova, Kirill A. Lysov, Ljudmila I. Souvorova, Oleg A. Rakitin   +3 more
doaj   +1 more source

Selective Benzene Capture by Metal‐Organic Frameworks

Advanced Functional Materials, EarlyView.
Metal‐organic frameworks (MOFs) hold significant potential for capturing benzene from air emissions and hydrocarbon mixtures in liquid phases. This capability stems from their precisely engineered structures, versatile chemistries, and diverse binding interactions.
Zongsu Han, Ankit Mondal, Jiatong Huo, Yihao Yang, Hong‐Cai Zhou   +4 more
wiley   +1 more source

Upconversion Nanoparticles Embedded Photonic Contact Lens for Transepithelial Corneal Crosslinking Using Hyaluronate – Riboflavin Conjugate

Advanced Functional Materials, EarlyView.
A minimally invasive, transepithelial corneal cross‐linking (TE‐CXL) approach is presented using upconversion nanoparticles (UCNPs)‐loaded contact lenses (UCLs), after topical delivery of hyaluronate–riboflavin conjugates. The NIR‐to‐UV/blue light conversion by UCNPs in a UCL can activate riboflavin for TE‐CXL, resulting in the biomechanical strength ...
Gibum Lee, Inhoo Choi, Anara Molkenova, Yengwoo Son, Seungmin Yang, Mina Kwon, Tae‐Im Kim, Ki Su Kim, Sei Kwang Hahn   +8 more
wiley   +1 more source

Electroactive Liquid Crystal Elastomers as Soft Actuators

Advanced Functional Materials, EarlyView.
Electroactive liquid crystal elastomers (eLCEs) can be actuated via electromechanical, electrochemical, or electrothermal effects. a) Electromechanical effects include Maxwell stress, electrostriction, and the electroclinic effect. b) Electrochemical effects arise from electrode redox reactions.
Yakui Deng, Min‐Hui Li
wiley   +1 more source

Fluorinated cyclohexanes: Synthesis of amine building blocks of the all-cis 2,3,5,6-tetrafluorocyclohexylamine motif

Beilstein Journal of Organic Chemistry, 2017
This paper reports the synthesis of three amine stereoisomers 5a–c of the tetrafluorocyclohexyl ring system, as building blocks for discovery chemistry programmes. The synthesis starts from a Birch reduction of benzonitrile, followed by an in situ methyl
Tetiana Bykova, Nawaf Al-Maharik, Alexandra M. Z. Slawin, David O'Hagan   +3 more
doaj   +1 more source

Photo‐Switching Thermal and Lithium‐Ion Conductivity in Azobenzene Polymers

Advanced Functional Materials, EarlyView.
Light‐responsive azobenzene polymers control thermal and ionic transport simultaneously through structural transitions. UV illumination disrupts π–π stacking, converting crystalline trans states to amorphous cis configurations. Thermal conductivity drops from 0.45 to 0.15 W·m−1·K−1 while Li+ diffusivity increases 100 fold. This dual transport switching
Jaeuk Sung, Jungwoo Shin, Qiujie Zhao, Minjee Kang, Christopher Evans, Cecilia Leal, Paul V. Braun, David G. Cahill   +7 more
wiley   +1 more source