Diastereoselective synthesis of highly substituted cyclohexanones and tetrahydrochromene-4-ones via conjugate addition of curcumins to arylidenemalonates [PDF]
Beilstein Journal of Organic ChemistryA cascade inter–intramolecular double Michael strategy for the synthesis of highly functionalized cyclohexanones from curcumins and arylidenemalonates is reported. This strategy works in the presence of aqueous KOH using TBAB as a suitable phase transfer
Deepa Nair +3 more
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Ni-catalysed acceptorless dehydrogenative aromatisation of cyclohexanones enabled by concerted catalysis specific to supported nanoparticles [PDF]
Nature CommunicationsThe dehydrogenative aromatisation of cyclohexanone derivatives has had a transformative influence on the synthesis of aromatic compounds because functional groups can be easily introduced at desired positions via classic organic reactions without being ...
Takehiro Matsuyama +3 more
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Correction: Diastereoselective synthesis of highly substituted cyclohexanones and tetrahydrochromene-4-ones via conjugate addition of curcumins to arylidenemalonates [PDF]
Beilstein Journal of Organic ChemistryDeepa Nair +4 more
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Synthesis of Spiro Pyrrolidines From the Addition of Schiff Bases to -Arylidene Cyclohexanones [PDF]
مجلة التربية والعلم, 2008 A series of -arylidene cyclohexanones (1-4) had been prepared via Claisen-Schmidt condensation, while other series of N-arylidene benzylamines (Schiff bases 5-10) had also been synthesized by equimolar addition.
A Al-Hamdany, A Mustafa, ِA Hamza
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Reactions, 2022 A systematic study of the Diels–Alder reaction of α-nitrocinnamate was performed. The reaction of p-substituted α-nitrocinnamate with 2,3-dimethyl-1,3-butadienes smoothly proceeded regardless of the p-substituent, which was either an electron-donating or
Takumi Hamada +2 more
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Molecules, 2022 Zr-containing MOF-808 is an excellent heterogeneous catalyst for the diastereoselective Meerwein–Ponndorf–Verley reduction of substituted cyclohexanones.
Hans Hilmar Mautschke +1 more
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The xanthate route to six-membered carbocycles
Journal of Chemical Research, 2022 Convergent routes to various six-membered carbocyclic architectures exploiting the unique radical chemistry of xanthates are described in this brief review. Three approaches are discussed.
Samir Z Zard
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Stereoselective (3+3)-Carbocyclization of Enamines with Nitroallylating Reagents
CHIMIA, 1985 The enamines from open-chain (3-pentanone) and cyclic (cyclopentanone, cyclohexanones, β-tetralone) ketones and the amines pyrrolidine, morpholine or (S)-2-methoxymethyl-pyrrolidine combine with E-3-phenyl-2-nitro-2-propen-1-yl or E-2-nitro-2-hepten-1 ...
Dieter Seebach +4 more
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Radical-mediated C-C cleavage of unstrained cycloketones and DFT study for unusual regioselectivity
Nature Communications, 2020 C-C bond scission of unstrained cycloketones with high regioselectivity is a challenging synthetic task. Here, the authors show a facile C-C cleavage of cyclohexanones and cyclopentanones with unusual selectivity under mild conditions with the aid of an ...
Mingyang Wang +5 more
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Beilstein Journal of Organic Chemistry, 2020 β-Nitrostyrenes underwent a Diels–Alder reaction with Danishefsky’s diene to afford cyclohexenes together with the corresponding hydrolyzed products, 3-arylated-5-methoxy-4-nitrocyclohexanones.
Haruyasu Asahara +2 more
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