Results 31 to 40 of about 2,800 (171)

Acetoxymaleic Anhydride as Ketene Equivalent in the Diels-Alder Reaction

open access: yesCHIMIA, 1992
Acetoxymaleic anhydride (AMA) has been shown to be a versatile ketene equivalent in the Diels-Alder reaction for the conversion of 1,3-dienes into cyclohexanones.
Ernest Wenkert   +2 more
doaj   +2 more sources

Enantioselective synthesis of highly functionalised cyclohexanones starting from R-(-)-Carvone.

open access: yes, 1998
Copper (I) catalysed conjugate addition of methylmagnesium iodide to R-(−)-carvone and trapping the enolate as its trimethylsilyl enol ether, followed by a trityl perchlorate (TrClO4) catalysed Mukaiyama-aldol reaction, is an efficient method for the ...
Meulemans, T.M.   +3 more
core   +2 more sources

Hydroxyl-substituted double Schiff-base condensed 4-piperidone/cyclohexanones as potential anticancer agents with biological evaluation

open access: yesJournal of Enzyme Inhibition and Medicinal Chemistry, 2019
Novel hydroxyl-substituted double Schiff-base 4-piperidone/cyclohexanone derivatives, 3a–e, 4a–e, 5a–d, and 6a–c, were synthesized and fully characterized by 1H NMR, IR and elemental analysis.
Lianshuang Zhang   +4 more
doaj   +1 more source

Diastereo- and enantioselective synthesis of densely functionalized cyclohexanones via double Michael addition of curcumins with nitroalkenes

open access: yes, 2012
The asymmetric double Michael additions of curcumins to nitroalkenes to afford highly functionalized cyclohexanones have been carried out for the first time.
AYYAGARI, N   +3 more
core   +1 more source

Construction of Substituted Cyclohexanones by Reductive Cyclization of 7-Oxo-2,8-alkadienyl Esters

open access: yes, 2016
Cyclization of 7-oxo-2,8-alkadienyl esters upon reaction with triphenylphosphinecopper hydride hexamer stereoselectively yields substituted cyclohexanones having a cis relationship of carbon side chains at C2 and C3.
Larry E. Overman (1264596)   +2 more
core   +1 more source

Synthesis of Novel Heteroaryl Iodonium Salts and Enantioselective a-Arylation of Cyclohexanones

open access: yes, 2006
We have developed a direct arylation reaction of cyclohexanones employing diaryl iodonium(Ill) salts as electrophiles. The reaction was made enantiosilective by the use of a chiral base, resultinginZ,4-disubstituted cyclohexanones in high yields and with
Aggarwal, Varinder K., Olofsson, Berit
core   +1 more source

Stereoselective Synthesis of Cyclohexanones via Phase Transfer Catalyzed Double Addition of Nucleophiles to Divinyl Ketones.

open access: yes, 2016
Functionalized cyclohexanones are formed in excellent yield and diastereoselectivity from a phase transfer catalyzed double addition of active methylene pronucleophiles to nonsymmetrical divinyl ...
David R. Carbery (2062837)   +4 more
core   +2 more sources

Cyclohexanones by Rh-Mediated Intramolecular C–H Insertion

open access: yes, 2016
Some long chain α-aryl α-diazo ketones under Rh catalysis cyclize efficiently to the corresponding cyclohexanones. This is in marked contrast to the cyclizations of α-diazo β-ketoesters, which consistently deliver cyclopentanone ...
Weiwei Tian (1903132)   +3 more
core   +1 more source

Allylation of cyclohexanones in aqueousmedia and influence of facialamphiphilicfructopyranosides

open access: yes, 2010
International audienceThe indium-catalyzed allylation reaction was performed in good yields and short reaction time with various cyclohexanones in water.
Plusquellec, Daniel   +5 more
core   +1 more source

Photostability of Cyanine Dyes and Its Correlation to Their Photothermal and Photodynamic Effects

open access: yesChemistry – A European Journal, EarlyView.
Photostability (PS) of dyes is a crucial parameter for performance in biological applications, yet often underrated. Here PS of several cyanines is investigated. The method is carefully evaluated and designed as a general and easy tool to compare PS of NIR dyes.
Clara Schäfer, Bo W. Laursen
wiley   +1 more source

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