Results 21 to 30 of about 1,766 (177)

Intrinsically Stretchable Piezoelectric Nanocomposites for Artificial Ultrasonic Sensory Synapse

open access: yesAdvanced Materials, EarlyView.
Applying ultrasonic stimulations to a soft‐stretchable underwater piezoelectric sensor based on the soft‐stretchable nanocomposite from the thermal cross‐linking between the ─C─F group of P(VDF‐TrFE) and the ─NH2 group of (PEG‐diamine) with incorporating amine‐terminated BTO@APTES nanofillers on the soft PDMS substrates generated high piezoelectric ...
Trung Dieu Do   +11 more
wiley   +1 more source

Synthesis of Cyclohexanone Oxime from Cyclohexanone and Ammonia.

open access: yesJournal of The Japan Petroleum Institute, 1999
シクロヘキサノンとアンモニアのみを原料とするシクロヘキサノンオキシムの合成を検討した結果, Na-ZSM-5が高い活性を示すことを見い出した。この触媒の活性サイトは触媒上の塩基点であると考えられる。主な副生成物は, アルドール脱水縮合反応を経由して生成するピリジンの誘導体であった。反応温度, 反応時間, 原料組成比などを最適化することにより, 高いシクロヘキサノンオキシム選択率を得ることができた。
FAN, Li, LIU, Jialing, FUJIMOTO, Kaoru
openaire   +2 more sources

Hydrophobic MFI‐Type Zeolites via Alkali‐Cation‐Induced Defect Healing: Implications for Adsorbent and Catalyst Design

open access: yesAdvanced Materials, EarlyView.
Sub‐stoichiometric amounts of Na+ or K+ enhance defect healing during Silicalite‐1 (MFI) and TS‐1 calcination by promoting Si–O–Si annealing and healing framework vacancies. The resulting defect‐free zeolites are more hydrophobic and show improved butanol/water separation and improved activity and selectivity in the epoxidation of 1‐hexene, offering a ...
Christos Kanteler   +14 more
wiley   +1 more source

Cobalt/Photoredox Catalyzed Desymmetrization of Oxo and Azabicycles via Asymmetric Reductive Coupling With Alkynes

open access: yesAdvanced Science, EarlyView.
A one‐step, asymmetric reductive coupling of alkynes and oxa‐ and aza‐bicyclic olefins using a cobalt/photoredox catalytic system through desymmetrization. ABSTRACT Bicyclo[2.2.1]heptane frameworks represent a privileged structural motif prevalent in numerous natural products and bioactive molecules.
Subhankar Pradhan   +5 more
wiley   +1 more source

Photothermal catalytic synthesis of cyclohexanones from lignin-derived phenolic bio-oils enabling transparent and elastic polyamides

open access: yesNature Communications
Cyclohexanones, as critical precursors for polyamide 6, are inherently challenging to synthesize from lignin-derived phenolic bio-oils due to the high dissociation energy of the aryl-OCH3 bond and the competitive risk of C=O bond over-hydrogenation.
Shufang Zhao   +16 more
doaj   +1 more source

Reimagining Lignin Valorization: Synthetic Biology–Enabled Sustainable Aromatic Carbon Biomanufacturing

open access: yesAdvanced Science, EarlyView.
The diagram illustrates a sustainable model of lignin valorization and carbon cycling based on microbial cell factories. Using lignin as the feedstock, synthetic biology technologies, including depolymerization, cell factory construction, pathway gene module integration, and metabolic network regulation, are applied to convert lignin into bulk ...
Na Li   +4 more
wiley   +1 more source

Acetoxymaleic Anhydride as Ketene Equivalent in the Diels-Alder Reaction

open access: yesCHIMIA, 1992
Acetoxymaleic anhydride (AMA) has been shown to be a versatile ketene equivalent in the Diels-Alder reaction for the conversion of 1,3-dienes into cyclohexanones.
Ernest Wenkert   +2 more
doaj   +2 more sources

Programmed Interfacial Phase Separation for Spatiotemporal Fungicide Delivery via Tunable Micro/Nano Architectures

open access: yesAdvanced Science, EarlyView.
ABSTRACT Translating dynamic liquid‐liquid phase separation into robust solid‐state architectures remains a challenge in materials engineering. Here, we report a composition‐driven interfacial assembly strategy that couples supramolecular coacervation with metal‐phenolic coordination to engineer tunable fungicide carriers.
Rui Zhang   +7 more
wiley   +1 more source

Hydroxyl-substituted double Schiff-base condensed 4-piperidone/cyclohexanones as potential anticancer agents with biological evaluation

open access: yesJournal of Enzyme Inhibition and Medicinal Chemistry, 2019
Novel hydroxyl-substituted double Schiff-base 4-piperidone/cyclohexanone derivatives, 3a–e, 4a–e, 5a–d, and 6a–c, were synthesized and fully characterized by 1H NMR, IR and elemental analysis.
Lianshuang Zhang   +4 more
doaj   +1 more source

Identification and evaluation of antiviral activity of novel compounds targeting SARS-CoV-2 virus by enzymatic and antiviral assays, and computational analysis

open access: yesJournal of Enzyme Inhibition and Medicinal Chemistry
The viral genome of the SARS-CoV-2 coronavirus, the aetiologic agent of COVID-19, encodes structural, non-structural, and accessory proteins. Most of these components undergo rapid genetic variations, though to a lesser extent the essential viral ...
Ivana Nemčovičová   +22 more
doaj   +1 more source

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