Results 41 to 50 of about 4,036 (208)

Redox Biocatalysis in Lidocaine‐Based Hydrophobic Deep Eutectic Solvents: Non‐Conventional Media Outperform Aqueous Conditions

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
Two hydrophobic DESs, lidocaine/oleic acid and lidocaine/decanoic acid, were utilized as reaction media that were enzyme‐compatible and highly substrate‐solubilizer for carbonyl reduction catalyzed by horse liver alcohol dehydrogenase, focusing on the effect of water contents and on maximizing substrate loadings, which showcases for the first time the ...
Ningning Zhang, Viktoria Lahmann, Jan Philipp Bittner, Pablo Domínguez de María, Sven Jakobtorweihen, Irina Smirnova, Selin Kara   +6 more
wiley   +1 more source

Cooperative effects between arginine and glutamic acid in the amino acid catalyzed aldol reaction [PDF]

, 2017
Catalysis of the aldol reaction between cyclohexanone and 4-nitrobenzaldehyde by mixtures of L-Arg and of L-Glu in wet DMSO takes place with higher enantioselectivity (up to a seven-fold enhancement in the anti- aldol for the 1:1 mixture) than that ...
Moyano i Baldoire, Albert, Valero González, Guillem   +1 more
core   +1 more source

Multi‐Dimensional Conductive Nanocomposites for Flexible Electronics

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Multi‐dimensional conductive nanocomposites integrate 0D, 1D, and 2D nanomaterials through spatial structure regulation and interface engineering, achieving “1 + 1 > 2” synergistic effects. By leveraging 0D filling to reduce contact resistance, 1D bridging to construct continuous conductive paths, and 2D supporting to enhance mechanical stability ...
Tianyu Wang, Ruimin Cai, Abbas Ali, Lizhe Li, Li Yang, Hulin Zhang, Xuge Fan, Yumin Xia, Wenyong Lai, Linmao Qian, Tiehu Li, Guosheng Shao, Liang Tian   +12 more
wiley   +1 more source

Effect of structural ordering of the carbon support on the behavior of Pd catalysts in aqueous-phase hydrodechlorination [PDF]

, 2019
Catalysts consisting of Pd supported on virgin and heat-treated carbon blacks (homemade and commercial), graphites (natural and synthetic) and commercial carbon nanofibers were prepared and tested in the aqueous phase hydrodechlorinaton (HDC) of 4 ...
Alonso-Morales, Noelia, Baeza, José A., Calvo, Luisa, Eser, Semih, Gilarranz, Miguel A., Heras, Francisco, Rodríguez, Juan J.   +6 more
core   +1 more source

Correlation Between the Molecular Structure of Metal‐Supporting Ligands and Catalysis in the Oxygenase‐Mimicking Immobilized Metal Complex Catalysts

European Journal of Inorganic Chemistry, EarlyView.
The correlation between the structures of metal complexes immobilized in the mesopores of hydrophobically modified silicate supports was examined in relation to the catalytic activities toward C‐H oxidation. On the alkene oxidation with H2O2, the iron catalyst bearing bis(imidazolyl)methane ligand promotes allylic oxidation, whereas the mononuclear ...
Yuta Akizawa, Hiroe Fukuzaki, Nana Aizawa, Sho Ikeda, Airi Kawabe, Saori Nishiyama, Iori Nagasawa, Masaya Okamura, Shiro Hikichi   +8 more
wiley   +1 more source

Preparation of organic hydrazides [PDF]

, 1959
Thesis (M.A.)--Boston UniversityDue to the actual high price of hydrazine, this chemical cannot be used in an economical preparation of organic hydrazides. A synthesis of such hydrazides can be envisaged by the reduction of N-nitroamides.
Amiel, Jean-Pierre L.
core   +1 more source

Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application

European Journal of Organic Chemistry, EarlyView.
Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley   +1 more source

Exceptional activity of gallium(III) chloride and chlorogallate(III) ionic liquids for Baeyer–Villiger oxidation [PDF]

, 2016
The extremely high activity of chlorogallate(iii) ionic liquids and GaCl3 in promoting Baeyer–Villiger oxidation of cyclic ketones with H2O2 to lactones is reported.
Chrobok, Anna, Markiton, Magdalena, Matuszek, Karolina, Seddon, Kenneth R., Swadzba-Kwasny, Malgorzata   +4 more
core   +1 more source

1,1‐Disubstituted Vinylbromides: Versatile Building Blocks for the Synthesis of Nitrogen‐Containing Heterocycles

European Journal of Organic Chemistry, EarlyView.
1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer, Jun Fang, Chonghuo Liu, Guillaume Lefèvre, Gérard Guillamot, Phannarath Phansavath, Virginie Ratovelomanana‐Vidal   +6 more
wiley   +1 more source

Convergent Valorization via Scalable C═N Bond Electrosynthesis Through Metal‐Dopant Interfacial Engineering in a Flow Electrolyzer

Angewandte Chemie, Volume 138, Issue 20, 11 May 2026.
This study establishes an innovative approach to synthesize organonitrogens featuring C═N bonds efficiently using non‐precious metal‐doped MoS2 in a flow electrolyzer. Fe dopant significantly enhances Faradaic efficiency and yield rate, achieving over 81% and 2630 mmol h−1 g−1 for formaldoxime production. This platform upcycles pollutants into valuable
Ruijie Yi, Jiu Chen, Xiaoyong Mo, Tian Zeng, Jingtao Zhou, Fulai Liu, Shu‐Chih Haw, Yong Chen, Ruosong Li, Edmund C. M. Tse   +9 more
wiley   +2 more sources