Heterocoagulation of Inorganic Pigments for Solvent‐Based Recycling of Polystyrene
Heterocoagulation is demonstrated as an effective strategy for removing inorganic pigments from polymer solutions in solvent‐based recycling. High turbidity reductions are achieved using selected heterocoagulants, even in the presence of dissolved polymer.
Elisabetta Carrieri +4 more
wiley +1 more source
The chemistry of ynol and thioynol ethers [PDF]
Alkynyl ethers and alkynyl thioethers (‘ynol ethers’ and ‘thioynol ethers’) are appealing building-blocks in synthetic chemistry due to their ease of manipulation and predictable reactivity.
Gray, VJ, Wilden, JD
core +1 more source
Cyclohexanone 2,4-dinitrophenylhydrazone
Crystals of the title compound, C12H14N4O4 were obtained by a condensation reaction between cyclohexanone and 2,4-dinitrophenylhydrazine. Within the dinitrophenyl group, the distances of 1.420 (2) and 1.422 (2) A for the C—C bonds close to the imino group are appreciably longer than the average distance of 1.377 (2) A for the rest of the C—C ...
Shang Shan, Duan-Jun Xu, Wei-Xiao Hu
openaire +1 more source
Studies on Selective Hydrogenation of Levulinic Acid and Paracetamol over Supported Ruthenium and Palladium Catalysts [PDF]
本论文以重要的生物质平台化合物乙酰丙酸(LA)加氢制备γ-戊内酯(GVL)以及对乙酰氨基苯酚选择加氢制备酮为目标,针对选择性加氢的控制,系统研究了碳材料负载钌催化剂上乙酰丙酸加氢性能及硅烷化改性SiO2负载钯基催化剂上对乙酰氨基苯酚的加氢性能。通过对催化剂的结构和性质进行较为系统的表征并与其催化活性进行关联,取得了以下主要结果。 论文针对LA选择加氢制备GVL的研究,比较了不同载体,包括不同碳材料及无机氧化物负载钌催化剂的反应性能。实验结果显示,反应产物GVL选择性均较高,达到99%以上 ...
宋文静
core
Glyoxylic Acid versus Ethyl Glyoxylate for the Aqueous Enantioselective Synthesis of α-Hydroxy-γ-Keto Acids and Esters by the N-Tosyl-(S a)-binam-l-prolinamide-Organocatalyzed Aldol Reaction [PDF]
N-Tosyl-(S a)-binam-l-prolinamide is an efficient catalyst for the aqueous aldol reaction between ketones and glyoxylic acid, as the monohydrate or as an aqueous solution, or a 50% toluene solution of ethyl glyoxylate.
Guillena, Gabriela +3 more
core +2 more sources
A biorefinery approach integrates the valorization of agri‐food waste through low‐temperature pyrolysis. The process concurrently yields functional liquid fractions and versatile biochars, which undergo extensive characterization to evaluate their potential in diverse technological applications. These materials serve as efficient renewable catalysts in
Nicola Schiaroli +7 more
wiley +1 more source
Cycloaddition Reactions of Carbonyl Compounds Possessing High Energy Content [PDF]
Detailed structure and kinetic analyses of the photocycloaddition of alkanones to (a) α,β-unsaturated nitriles and (b) enol ethers have been performed. The excited singlet states of alkanones were found to add stereospecifically and regiospecifically to ...
Turro, Nicholas J.
core +2 more sources
Substrate Walking for Selective Ene Reduction
Ene‐reductases (EREDs) efficiently reduce activated C═C bonds. Expanding the current application, they catalyze the selective reduction of highly substituted cyclohexenones. Immobilized, they were scaled to 200 mL, achieving full substrate conversion without enzyme degradation. ABSTRACT Ene‐reductases (EREDs) efficiently reduce activated C═C bonds, but
Hugo Brasselet +8 more
wiley +1 more source
Aqueous Enantioselective Aldol Reaction of Methyl- and Phenylglyoxal Organocatalyzed by N-Tosyl-(S a)-binam-l-prolinamide [PDF]
The direct aldol reaction between methylglyoxal (40% aqueous solution) or phenylglyoxal monohydrate and ketones or aldehydes is catalyzed by N-tosyl-(S a)-binam-l-prolinamide to afford the corresponding chiral γ-oxo-β-hydroxy carbonyl compounds, mainly ...
Guillena, Gabriela +2 more
core +2 more sources
This study mainly consists of two parts. First, after screening for drug‐like metabolites via LC–MS and GC–MS, a comprehensive evaluation model was established using a principal component analysis‐based weighted scoring method, by which the drug‐likeness ranking of three samples was determined.
Han Chen +6 more
wiley +1 more source

