Results 11 to 20 of about 4,127 (128)

Global Warming and Mass Extinctions Associated With Large Igneous Province Volcanism

open access: yesGeophysical Monograph Series, Page 83-102., 2021

Exploring the links between Large Igneous Provinces and dramatic environmental impact

An emerging consensus suggests that Large Igneous Provinces (LIPs) and Silicic LIPs (SLIPs) are a significant driver of dramatic global environmental and biological changes, including mass extinctions.
David P. G. Bond, Yadong Sun
wiley  

+1 more source

Desymmetrization of Malonic Monoesters and Malonic Acids via Enantioselective Catalytic C(sp3)─H Oxidation

open access: yesAngewandte Chemie, Volume 138, Issue 13, 23 March 2026.
Manganese‐catalyzed enantioselective C(sp3)─H lactonization with hydrogen peroxide enables the direct desymmetrization of malonic monoesters and malonic acids, providing highly enantioenriched γ‐ and δ‐lactones (up to >99% ee) ABSTRACT Malonate derivatives are readily available starting materials widely employed in the synthesis of bioactive compounds.
Nikos Siakavaras   +3 more
wiley   +2 more sources

Protection and Delivery of Phytochemicals from Passive Encapsulation to Guaranteed Self‐Assembly Induced by Amyloid Template for Chronic Disease Prevention via Modulating Microbial‐Host Crosstalk

open access: yesAdvanced Science, EarlyView.
ABSTRACT The rising incidence of chronic diseases globally has drawn widespread attention to phytochemicals, which exert targeted preventive and alleviating effect by modulating gut microbiota; thus, a potential strategy for precision nutritional interventions is offered.
Shiqi Bai   +6 more
wiley   +1 more source

Integrated Flue‐Gas Heat Recovery for Optimized Steam and Power Generation Using Organic Rankine Cycle (ORC): A Technical and Economic Assessment

open access: yesEnergy Science &Engineering, EarlyView.
Integration of a steam cycle with an existing gas turbine increased efficiency from 32% to 51%, reducing fuel consumption by 21.4% and CO2 emissions by 18.6%. The modification generated USD 13.9 million annual savings and lowered the Levelized Cost of Energy to 38.7 USD/MWh, with a 3‐year payback.
Vahid Pirouzfar   +2 more
wiley   +1 more source

Polyethylene‐Polyamide‐6 Diblock Copolymers for Fused Filament Fabrication

open access: yesJournal of Polymer Science, EarlyView.
Linear HDPE‐PA6 block copolymers were prepared by polymerization of ethylene to a macroinitiator and subsequent anionic caprolactam polymerization. The copolymer with a HDPE mass of 6500 Da and PA6 mass of 20.000 Da was used as a filament in 3D printing.
Elsa M. Schoeneberger   +1 more
wiley   +1 more source

Metal‐Free Electrophilic Borylative Cyclizations of Alkynes

open access: yesThe Chemical Record, EarlyView.
Metal‐free borylative cyclizations based on electrophilic alkyne activation by boron Lewis acids provide efficient access to borylated hetero‐ and carbocycles. Early studies using B(C6F5)3 displayed limited scope and application, whereas recent ClBcat‐ and BCl3‐based methods enable mild CB and CC/CX bond formation for the synthesis of cycles ...
Jaime Mateos‐Gil   +3 more
wiley   +1 more source

(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications

open access: yesAngewandte Chemie, Volume 138, Issue 10, 2 March 2026.
In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh   +5 more
wiley   +2 more sources

The Structure of Carboxyl Methyltransferase Provides Insights Into the Substrate Specificity and Divergent Evolution of Iridoid

open access: yesPlant Biotechnology Journal, EarlyView.
ABSTRACT Iridoids constitute a prominent class of plant‐specialised metabolites, with carbocyclic iridoids (e.g., geniposide) and secoiridoids (e.g., loganin) diverging early in their biosynthetic pathways. This divergence is marked by substrate‐specific carboxyl methyltransferases—GjGAMT and CrLAMT—that catalyse the decisive methylation step in ...
Li Li   +7 more
wiley   +1 more source

Electronic Smoking Devices Among University Students: Usage Patterns and Chemical Composition of Inhaled Substances

open access: yesAnalytical Science Advances, Volume 7, Issue 1, June 2026.
ABSTRACT This study investigated the prevalence of electronic smoking device (ESD) use and its associated behavioural and chemical risks among university students in Bahia, Brazil. A cross‐sectional survey was conducted with 355 students from public and private institutions through an online questionnaire between April and May 2023. Among participants,
Eduard F. Valenzuela   +7 more
wiley   +1 more source

Clumped Isotope Temperature Reconstruction Using Stalagmite Drip Cups

open access: yesRapid Communications in Mass Spectrometry, Volume 40, Issue 8, 30 April 2026.
ABSTRACT Rationale Application of clumped isotope palaeothermometry to speleothems (carbonate cave deposits, e.g., stalagmites and flowstones) has been restricted largely to subaqueous samples because of kinetic fractionation processes that occur during subaerial speleothem formation, which lead to erroneously high inferred temperatures.
Stuart Umbo   +11 more
wiley   +1 more source

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