Results 121 to 130 of about 21,746 (290)

Chemo-, regio- and enantioselective hydroformylation of trisubstituted cyclopropenes: access to chiral quaternary cyclopropanes

open access: yesNature Communications
Catalytic asymmetric synthesis of polysubstituted chiral cyclopropane presents a significant challenge in organic synthesis due to the difficulty in enantioselective control.
Shuailong Li   +7 more
doaj   +1 more source

OPTICALLY ACTIVE CHRYSANTHEMIC ACID AND ITS ANALOGUES [PDF]

open access: yesChemistry Journal of Moldova: General, Industrial and Ecological Chemistry, 2010
Optically active chrysanthemic acid and its analogues have received considerable attention in recent years due to their practical importance. This review will focus on describing the developments in the synthesis of optically active chrysanthemic acid ...
L. Bets   +5 more
doaj  

Efficient Synthesis of Cyclopropane-Fused Heterocycles with Bromoethylsulfonium Salt [PDF]

open access: yes, 2013
Aggarwal   +66 more
core   +3 more sources

Observation of unusual outer-sphere mechanism using simple alkenes as nucleophiles in allylation chemistry

open access: yesNature Communications
Transition-metal catalyzed allylic substitution reactions of alkenes are among the most efficient methods for synthesizing diene compounds, driven by the inherent preference for an inner-sphere mechanism.
Yaxin Zeng   +7 more
doaj   +1 more source

Epinephrine-Cyclopropane Effects on Purkinje Fibers [PDF]

open access: bronze, 1969
Larry D. Davis   +2 more
openalex   +1 more source

Synthesis and Structure of Titanium Imido Complexes With Bi‐ and Tridentate PN and PNP Ligands

open access: yesZeitschrift für anorganische und allgemeine Chemie, Volume 652, Issue 1, January 6, 2026.
The synthesis of PN and PNP supported titanium imido complexes is presented with a variety of alkyl and aryl imido donors on the titanium center, giving access to new potential precatalysts in hydroamination catalysis. We report the synthesis of alkyl and aryl imido titanium(IV) complexes supported by bi‐ or tridentate PNMes and PNP ligands (PNMes = (2‐
Philipp Boos   +4 more
wiley   +1 more source

Ringspannungs‐vermittelte Aktivierung von Pyridinen durch einen gesättigten BSi2‐Ring

open access: yesAngewandte Chemie, Volume 138, Issue 1, 2 January 2026.
Wir berichten über ein stark gespanntes Boratadisiliran mit dem bisher nicht zugänglichen anionischen BSi2‐Ringmotiv. Die Spaltung der S–Si‐Bindung während der Reaktionen mit Pyridinderivate aktiviert diese auf drei verschiedene Arten: (1) Bei Pyridin selbst erfolgt eine selektive ortho‐CH‐Aktivierung und ein gleichzeitiger Wasserstofftransfer zu einem
Nasrina Parvin   +5 more
wiley   +1 more source

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