Results 121 to 130 of about 19,882 (280)
Abstract Various methods exist for identifying and quantifying lipid unsaturation, including mass spectrometry and Raman spectroscopy. A disadvantage of these existing approaches is the need for sophisticated equipment and software, placing them beyond the means of many laboratories.
Maria Monserrat Roman‐Lara+3 more
wiley +1 more source
Iron-mediated Preparation of Vinylcyclopropanes. Scope, Mechanism, and Applications [PDF]
The addition of stabilized carbon nucleophiles to tricarbonyl(1-methoxycarbonylpentadienyl)iron(1+) cation (1a) proceeds via attack at C2 on the face of the ligand opposite the Fe(CO)3 group to generate tricarbonyl(pentenediyl)iron complexes 2. Oxidation
Cao, Yeyu+3 more
core +1 more source
Abstract Affinity photolabeling is a smart method to study noncovalent and transient interactions and provide a submolecular picture of the contacts between interacting partners. In this review, we will focus on the identification of peptide partners using photoaffinity labeling coupled to mass spectrometry in different contexts such as in vitro with a
Astrid Walrant, Emmanuelle Sachon
wiley +1 more source
Ring Tension, Hydrocarbon Acidity, and New «Super-Bases»
Addition of disodium pinacolate or, particularly, potassium tert-butoxide considerably increases the transmetalating power of pentylsodium. A hexane slurry of such «NACNAOR» or «NACKOR» reagent mixtures readily and selectively converts 3,3-dimenthyl-1 ...
Manfred Schlosser+5 more
doaj +1 more source
CIRCULATORY EFFECTS OF CHLORPROMAZINE BEFORE AND DURING CYCLOPROPANE ANESTHESIA IN MAN [PDF]
Benjamin E. Etsten, Tsung‐Han Li
openalex +1 more source
[1‐(Ethoxycarbonyl)cyclopropyl] triphenylphosphonium tetrafluoroborate is a limiting key reagent for synthesis of the tricyclic 5,6‐dihydropyrimido[5,4‐e]indolizine and related scaffolds, which are central to First‐in‐Class covalent inhibitors of the protein kinase monopolar spindle 1/threonine tyrosine kinase (TTK).
Leon Rebhan+4 more
wiley +1 more source
Preliminary Calculations of Mean Amplitudes of Vibration in Cyclopropane. [PDF]
Otto Bastiansen+6 more
openalex +1 more source
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openaire +2 more sources
The continuing significance of chiral agrochemicals
In the time frame 2018–2023, around 43% of the 35 chiral agrochemicals introduced to the market (herbicides, fungicides, insecticides, acaricides, and nematicides) contain one or more stereogenic centers in the molecule, and almost 69% of them have been marketed as racemic mixtures of enantiomers or stereoisomers.
Peter Jeschke
wiley +1 more source
Antimicrobial peptides (AMPs) are promising candidates for next‐generation antibiotics, acting through mechanisms such as membrane disruption and intracellular targeting. This review examines how variations in bacterial membrane composition critically influence AMP activity.
Paolo Rossetti+5 more
wiley +1 more source