Comparative chemistry of protected phosphines within the synthesis of cyclopropanes
On treatment with base, diphenylphosphinoyl esters 3 (X=O) give cyclopropanes 4 via a series of steps including intramolecular acyl and phosphinoyl transfer processes.
Clarke, C
core
Reaction of Halogenated Cyclopropanes and Nitrosyl Cation: Preparation of Isoxazoles
Reaction of Halogenated Cyclopropanes and Nitrosyl Cation: Preparation of ...
Shing-Huey Kuo (3040113) +2 more
core +1 more source
Butyllithium requires activation in order to become capable of abstracting a proton from weakly acidic hydrocarbons like cyclopropanes, simple olefins, or arenes.
Florence Mongin +2 more
doaj +2 more sources
Synthesis and reactivity of α-lithio α-trimethylsilyl cyclopropanes and related derivatives
α-lithio α-trimethylsilyl cyclopropanes have been prepared by two different routes. They have been tested as precursors of alkylidene cyclopropanes, cyclopropylidienes and α-silyl α-vinyl ...
Halazy, S., Krief, A., Dumont, W.
core
Highly efficient construction of angular polycycles
Angular tricyclic and polycyclic skeletons feature typical cores in an intriguing type of natural products. We herein report the Lewis acids-catalyzed dearomative (3 + 2) cycloadditions of donor-acceptor cyclopropanes with benzene ring, by which ...
Yi Sun +3 more
doaj +1 more source
Deuterated Cyclopropanation of Alkenes by Iron Catalysis. [PDF]
Rana IK, Nguyen KNM, Ngo DT, Nagib DA.
europepmc +1 more source
Formation of cyclopentanes and cyclopropanes through alkylation of benzylic anions using ethers, thioethers and alcohols as substrates under Grubbs-Stoltz (Et<sub>3</sub>SiH/KO<i>t</i>Bu) conditions. [PDF]
Stewart AJ +10 more
europepmc +1 more source
Asymmetric Carbonium Ion Catalysis: The Intramolecular Hydroalkoxylation of Cyclopropanes. [PDF]
Shi F +6 more
europepmc +1 more source
Mapping the Undirected Borylation of C(sp3)-H Bonds in Strained Rings. [PDF]
La C +3 more
europepmc +1 more source

