Redirecting radical phosphonylation via energy-transfer-enabled diradical rearrangement. [PDF]
Li KD, Tang YH, Huang HM.
europepmc +1 more source
Ring Opening of Donor–Acceptor Cyclopropanes with N-Nucleophiles
E. M. Budynina +3 more
semanticscholar +1 more source
Sodium Hypochlorite Pentahydrate in Organic Synthesis and Beyond
Sodium hypochlorite pentahydrate emerges as a versatile, stable, and practical oxidant for organic synthesis. This review highlights its unique reactivity, broad synthetic applications, and growing impact on sustainable oxidation chemistry, providing a comprehensive overview of recent advances and future opportunities. Sodium hypochlorite pentahydrate (
Masayuki Kirihara +2 more
wiley +1 more source
Formation of cyclopentanes and cyclopropanes through alkylation of benzylic anions using ethers, thioethers and alcohols as substrates under Grubbs-Stoltz (Et<sub>3</sub>SiH/KO<i>t</i>Bu) conditions. [PDF]
Stewart AJ +10 more
europepmc +1 more source
1,3‐Bis(tetrylene)s: Emerging Platforms for Functional Main‐Group Molecules
Bridge design governs the stability and reactivity of 1,3‐bis(tetrylene)s. This review surveys pnictogen‐, chalcogen‐, and tetrel‐bridged systems and shows how geometric preorganization and electronic communication can enable cooperative bond activation and access to unusual heavy‐element π frameworks. Main‐group chemistry has undergone a resurgence as
Daichi Uchida, Yoshiyuki Mizuhata
wiley +1 more source
Adaptive Laboratory Evolution Rewires Pseudomonas putida for Resource‐Efficient Acetate Assimilation
Adaptive laboratory evolution selected key mutations that improved acetate tolerance in genome‐reduced Pseudomonas putida. Multi‐omic analyses showed that adaptation increased biomass yield by reallocating resources away from costly stress‐associated programs and redirecting acetate carbon toward carbon‐conserving metabolism.
Nicolás Gurdo +18 more
wiley +1 more source
Accessing Medium-Sized Bridged Heterocycles via EnT-Catalyzed Intermolecular Dearomative (5 + 4) Cycloaddition of Furans and Oxazoles. [PDF]
Hümpel C +5 more
europepmc +1 more source
A 10‐year nitrogen addition experiment in Eurasian steppe reveals that plant and microbial community succession rates first increase then decrease with rising N intensity, indicating an adaptive threshold. Deterministic processes driven by soil physicochemical changes dominate this response, with management strategies modulating adaptation via ...
Tingting Li +3 more
wiley +1 more source
Asymmetric Carbonium Ion Catalysis: The Intramolecular Hydroalkoxylation of Cyclopropanes. [PDF]
Shi F +6 more
europepmc +1 more source

