Sulfur-Mediated Ring-Opening Cyclization of Spirocyclopropanes for the Construction of Benzo[b]thiophene Skeleton. [PDF]
Nambu H +5 more
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Photocatalytic construction of <i>N</i>-acyl-<i>N</i>,<i>O</i>-acetal-linked pyridines <i>via</i> aminocyclopropane ring opening. [PDF]
Kim D, Yang E, Cho Y, Hong S.
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Cu-Bpin-mediated dimerization of 4,4-dichloro-2-butenoic acid derivatives enables the synthesis of densely functionalized cyclopropanes. [PDF]
Gómez-Roibás P +2 more
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Divergent and Enantioselective Synthesis of Three Types of Chiral Polycyclic N‑Heterocycles via Copper-Catalyzed Dearomative Cyclization. [PDF]
Luo WF +7 more
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Towards <i>trans</i>-dual deuterated cyclopropanes <i>via</i> photoredox synergistic deuteration with D<sub>2</sub>O. [PDF]
Wu Y +8 more
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Strain-Release Induced 1,2-Metallate Rearrangement of Geminal Diborons: Multicomponent 1,5-Difunctionalization via Ring-Opening Coupling. [PDF]
Gangani AJ +5 more
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Unlocking nucleophilic reactivity in Co-MHAT catalysis: Stereospecific backside-backside displacement by anion-activated organocobalt. [PDF]
Zhao BS, Yin YN, Zhu R.
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A new ionic cyclopropanation process involving the addition of diazo esters to donor-acceptor cyclopropanes (DAC) activated by GaCl3 has been developed. The reactions occur via 1,2-zwitterionic gallium complexes with elimination of nitrogen in all cases to give 1,1,2,3-tetrasubstituted cyclopropanes as the main products.
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The cyclopropanated derivatives of three diesel-compatible biofuels—limonene, turpentine, and canola oil methyl ester—were prepared. Their heats of combustion were both calculated using theoretical methods and measured experimentally, and it was found that for all three compounds the specific energy (in kJ/g) was similar to that of the starting ...
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