Results 171 to 180 of about 28,372 (298)

Verrucacrylic Acids A and B From a Marine Sponge‐derived Verrucosispora sp. FIM06025

open access: yesChemistry &Biodiversity, Volume 23, Issue 10, October 2026.
Three new compounds, including two rare cyclopropane‐containing compounds, verrucacrylic acids A and B (1 and 2), and a new amino acid derivative (3), were isolated from Verrucosispora sp. FIM06025, 1 and 2 exhibited weak cytotoxic activity against HL‐60 and T47D. ABSTRACT Verrucosispora sp.
Minghong Chen   +4 more
wiley   +1 more source

Rhodium(III)-Catalyzed Asymmetric Synthesis of Silanes and Cyclopropanes From Diazo Compounds Using Chiral α-Pinene-Derived Indenyl Ligands. [PDF]

open access: yesAngew Chem Int Ed Engl
Kharitonov VB   +6 more
europepmc   +1 more source

Chemical Composition and Multi‐Target Bioactivity of Salvia sclarea L. Essential Oil From the Algerian Edough Massif: Antimicrobial, Enzyme‐Inhibitory, and Molecular Docking Studies

open access: yesChemistry &Biodiversity, Volume 23, Issue 10, October 2026.
Salvia sclarea essential oil from the Algerian Edough Massif is characterized by a linalyl anthranilate/linalool‐rich chemotype and exhibits antimicrobial, antibiofilm, antioxidant, anti‐inflammatory, acetylcholinesterase, and α‐amylase inhibitory activities.
Manel Lina Djendi   +7 more
wiley   +1 more source

Design, Synthesis, and Antifungal Structure‐Activity Relationship of Hydrazide Derivatives Containing a Cyclopropyl Group Against Phytopathogenic Fungi

open access: yesChemistry &Biodiversity, Volume 23, Issue 10, October 2026.
Twenty‐three cyclopropyl‐containing hydrazide derivatives, including 14 new chemical entities, are designed and synthesized. Compounds 4, 6, and 7 exhibit broad‐spectrum antifungal activity against eight phytopathogenic fungi with EC50 values below 10 µg/mL.
Shanshan Yang   +7 more
wiley   +1 more source

Sulfur-Directed Construction of Vinyl Cyclopropanes from 1,3-Dienes. [PDF]

open access: yesAngew Chem Int Ed Engl
Keimer A   +6 more
europepmc   +1 more source

Mechanistic Study Reveals Hypoboric Acid Catecholate (HAC): An Enhanced Diboron Reagent for Decarboxylative Borylation

open access: yesChemistryEurope, Volume 4, Issue 10, October 2026.
The hidden catalysis of water in the decarboxylative borylation of redox‐active esters with B2cat2 has revealed hypoboric acid catecholate (HAC): an unsymmetric diboron reagent that accelerates the reaction by producing a more reductive boryl chain carrier, upon regioselective radical capture.
B. Meana‐Baamonde   +5 more
wiley   +1 more source

Machine learning-assisted development of a fast Mechanochemical Johnson-Corey-Chaykovsky reaction. [PDF]

open access: yesNat Commun
Mele F   +12 more
europepmc   +1 more source

Oxidative Generation and Reactivity of the Cyclopropyl Radical From a Martin Silicate

open access: yesChemistry – A European Journal, Volume 32, Issue 37, 1 October 2026.
A photoredox strategy employing Martin silicates enables the oxidative generation and controlled capture of cyclopropyl radicals, including the naked one, long considered challenging intermediates. The method affords functionalized cyclopropanes through both Giese‐type additions and dual nickel/photoredox C(sp3)−C(sp2) cross‐couplings.
Amal Lakhal   +3 more
wiley   +1 more source

Deuterated Cyclopropanation of Alkenes by Iron Catalysis. [PDF]

open access: yesOrg Lett
Rana IK, Nguyen KNM, Ngo DT, Nagib DA.
europepmc   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

open access: yesChemistry – A European Journal, Volume 32, Issue 37, 1 October 2026.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

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