Results 31 to 40 of about 7,561 (225)

Critical Role of Semiquinones in Reductive Dehalogenation

open access: yes, 2023
Quinones and products of their redox reactions (hydroquinones and semiquinones) have been suggested as important players in the reductive dehalogenation of organohalogens mediated by natural and pyrogenic organic matter, although based on limited direct ...
Lard, Myron L.   +3 more
core   +2 more sources

Single-Cell Genomics Reveals a Diverse Metabolic Potential of Uncultivated Desulfatiglans-Related Deltaproteobacteria Widely Distributed in Marine Sediment

open access: yesFrontiers in Microbiology, 2018
Desulfatiglans-related organisms comprise one of the most abundant deltaproteobacterial lineages in marine sediments where they occur throughout the sediment column in a gradient of increasing sulfate and organic carbon limitation with depth ...
Lara M. Jochum   +5 more
doaj   +1 more source

The Electroreductive Dehalogenation Reaction of 5-Bromo-2-chlorobenzoic Acid on Dendritic Ag/Cu

open access: yesInternational Journal of Electrochemical Science, 2015
Dendritic Ag/Cu electrode was synthesized by galvanic replacement of AgNO3 and Cu, and was investigated by scanning electron microscopy, transmission electron microscopy and X-ray diffraction.
Fen Wang   +4 more
doaj   +1 more source

Bioremediation of halogenated compounds: comparison of dehalogenating bacteria and improvement of catalyst stability [PDF]

open access: yes, 2006
Five bacterial strains were compared for halogenated compounds conversion in aqueous media. Depending on the strain, the optimal temperature for dehalogenase activity of resting cells varied from 30 to 45 degrees C, while optimal pH raised from 8.4 to 9 ...
Legoy, Marie-Dominique   +5 more
core   +1 more source

Bromide-assisted chemoselective Heck reaction of 3-bromoindazoles under high-speed ball-milling conditions: synthesis of axitinib

open access: yesBeilstein Journal of Organic Chemistry, 2018
A mechanically-activated chemoselective Heck coupling for the synthesis of 3-vinylindazoles has been developed with the aid of catalytic amounts of TBAB and NaBr as both dehalogenation restrainer and grinding auxiliary.
Jingbo Yu   +5 more
doaj   +1 more source

Phenol Is the Initial Product Formed during Growth and Degradation of Bromobenzene by Tropical Marine Yeast, Yarrowia lipolytica NCIM 3589 via an Early Dehalogenation Step

open access: yesFrontiers in Microbiology, 2017
Bromobenzene (BrB), a hydrophobic, recalcitrant organic compound, is listed by the environmental protection agencies as an environmental and marine pollutant having hepatotoxic, mutagenic, teratogenic, and carcinogenic effects.
Aakanksha A. Vatsal   +2 more
doaj   +1 more source

Mechanism and application of halogenation–dehalogenation in the development of pitch-based carbon fiber: A review

open access: yesJournal of Engineered Fibers and Fabrics, 2023
Pitch-based carbon fiber, as one of the important engineering materials, has been widely used in aerospace, defense, sports, and other fields. In the long production process of pitch-based carbon fiber, the property of pitch precursor is significant for ...
Jinchang Liu   +5 more
doaj   +1 more source

High frequency of phylogenetically diverse reductive dehalogenase-homologous genes in deep subseafloor sedimentary metagenomes

open access: yesFrontiers in Microbiology, 2014
Marine subsurface sediments on the Pacific margin harbor diverse microbial communities even at depths of several hundreds meters below the seafloor (mbsf) or more.
Mikihiko eKawai   +17 more
doaj   +1 more source

Understanding the sources, function, and irreplaceable role of cobamides in organohalide-respiring bacteria

open access: yesFrontiers in Microbiology
Halogenated organic compounds are persistent pollutants that pose a serious threat to human health and the safety of ecosystems. Cobamides are essential cofactors for reductive dehalogenases (RDase) in organohalide-respiring bacteria (OHRB), which ...
Yongfeng Lu   +6 more
doaj   +1 more source

Remediation of Polychlorinated Biphenyls (PCBs) in Contaminated Soils and Sediment: State of Knowledge and Perspectives

open access: yesFrontiers in Environmental Science, 2018
Polychlorinated biphenyls (PCBs) are one of the persistent organic pollutants (POPs) used worldwide between the 1930 and 1980s. Many PCBs can still be found in the environment such as in soils and sediments, even though their use has been heavily ...
Ran Jing   +2 more
doaj   +1 more source

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