Subnanometric Platinum–Germanium Clusters for Efficient Propane Dehydrogenation Catalysis
Pt─Ge alloy clusters are regioselectively encapsulated within the sinusoidal channels of pure silica MFI zeolite (PtGe@MFI). The developed Pt─Ge alloy clusters exhibit exceptional performance with 36‐fold higher activity than the most stable catalyst ever reported and twice its stability, and with comparable activity to and 21‐fold higher stability ...
Yuki Nakaya +2 more
wiley +1 more source
Atomic Pathways of Ammonia-Driven Fe<sub>3</sub>O<sub>4</sub> Reduction Revealed by First-Principles Calculations. [PDF]
Zhou Z, Qiao L, Ye S, Wang M, Zhou G.
europepmc +1 more source
Uncertainties exist in computational fluid dynamics (CFD) modeling of complex metallurgical processes, even when partly validated by laboratory experiments. rCFD enables computationally efficient prediction of long‐term RH degassing and can be adapted to vary flow conditions.
Xiaomeng Zhang +3 more
wiley +1 more source
Temperature-driven reaction pathways in alkane direct dehydrogenation over metal-free nitrogen doped carbocatalysts. [PDF]
Zhang J +14 more
europepmc +1 more source
Metal‐Free Electrophilic Borylative Cyclizations of Alkynes
Metal‐free borylative cyclizations based on electrophilic alkyne activation by boron Lewis acids provide efficient access to borylated hetero‐ and carbocycles. Early studies using B(C6F5)3 displayed limited scope and application, whereas recent ClBcat‐ and BCl3‐based methods enable mild CB and CC/CX bond formation for the synthesis of cycles ...
Jaime Mateos‐Gil +3 more
wiley +1 more source
The Radical SAM Enzyme BlsE Can Operate as a Dehydratase, Dehydrogenase, or Epimerase upon Mutation of a Single Active Site Serine Residue. [PDF]
Lee YH +6 more
europepmc +1 more source
Surface Micro‐Discharge Plasma for Multiple Teeth Bleaching: Efficacy, Mechanism and Safety
ABSTRACT Hydrogen peroxide (H2O2) is the commonly‐used bleaching chemical in clinical practice, but its excessive concentrations can cause tooth damage. Atmospheric pressure cold plasma is considered a promising new technique for tooth bleaching. Surface micro‐discharge (SMD) devices can generate large‐scale plasma, which holds potential for treating ...
Ruike Chen +7 more
wiley +1 more source
Ni- and Zn-Doping Effects on Cu/SiO<sub>2</sub> Catalysts in Nonoxidative Ethanol Dehydrogenation. [PDF]
Pokorny T +9 more
europepmc +1 more source
Pyridoxal 5′‐phosphate (PLP) homeostasis relies on salvage enzymes, yet key metabolic branches remain undefined. We identify AKR1C isozymes as previously undescribed contributors that convert pyridoxal into pyridoxine or 4‐pyridoxolactone through reductase and dehydrogenase activities.
Nayu Kito +8 more
wiley +1 more source
Mechanistic Insights in Acceptorless Dehydrogenation of N-Heterocycles Using Graphenes as Carbocatalysts. [PDF]
Mollar-Cuni A +5 more
europepmc +1 more source

