Results 131 to 140 of about 39,740 (295)
Heavier Alkyne‐Ni0 Complexes, [R2E2·Ni] (E = Sn, Pb), Exhibiting σ‐Complex Character
Angewandte Chemie, EarlyView.Using a reductive group elimination strategy, heavier alkyne (LEEL; E = Sn, Pb) complexes of Ni0 are accessed. In contrast to classical alkyne coordination, these systems are best described as σ‐complexes, driven by ligand‐induced constraints and the established poor π‐bonding in heavier alkyne analogues.
Leopold Junge +3 more
wiley +2 more sources
Synergetic effect between NiO and Ni3V2O8 in propane oxidative dehydrogenation
, 2002 The oxidative dehydrogenation (ODH) of propane was investigated on Ni-V-O catalysts in a wide range of vanadium contents (5-40%). The addition of a small amount of vanadium significantly increased the catalytic activity of NiO for oxidative ...
Kieffer, R +3 more
core
Novel Non‐Cytotoxic Acylphosphinates and Acylphosphine Oxides Photoinitiators
Angewandte Chemie, EarlyView.Novel acylphosphine oxide (APO) and acylphosphinate photoinitiators based on DPO and DOPO were designed to investigate structure–property relationships including photochemical performance, polymerization efficiency and cytotoxicity. While DPO derivatives showed excellent reactivity, DOPO‐based systems also displayed good efficiency and significantly ...
Jiansong Yin +13 more
wiley +2 more sources
Angewandte Chemie, EarlyView.Heterogeneous iron‐catalyzed environmentally benign and sustainable CH‐oxidative esterification methodology has been developed for the synthesis of esters. This challenging reaction has been achieved by the rational design of specific single atom iron‐based catalyst with Fe‐N4 active centers, which empowered the oxidative esterification of methyl and ...
Zhuang Ma +8 more
wiley +2 more sources
Synthesis and dehydrogenation of LiCa(NH2)3(BH3)2
, 2012 Synthesis and dehydrogenation of LiCa(NH2)3(BH3)
蔡永胜 +4 more
core
The effect of doping NiCl2 on the dehydrogenation properties of LiAlH4
, 2008 To investigate the effect of NiCl2 dopant and doping processes on the dehydrogenation behavior of LiAlH4, powder mixtures of LiAlH4 and NiCl2 dopant were prepared by designed mixing and milling processes.
Zhu, M. +5 more
core +1 more source
Nucleophilic Gallyl Anions Enable Ga─Au Bimetallic Ammonia Activation
Angewandte Chemie, EarlyView.Unlocking gallyl nucleophiles: Counterion control enables formation of an unsupported gallyl─gold complex. Gold coordination induces a polarity switch at gallium, enabling cooperative activation of NH3 and related N─H/O─H substrates under mild conditions.
Hellen Videa +3 more
wiley +2 more sources
Potassium‐Ligand Cooperation Facilitated Chemical Bond Activation and Catalytic Hydrogenation
Angewandte Chemie, EarlyView.A new strategy for alkali metal‐mediated catalysis based on metal–ligand cooperation (MLC) is presented. Potassium pincer complexes exhibit remarkable reactivity toward a range of molecules via an unprecedented potassium–ligand cooperative mechanism. This reactivity enables potassium‐catalyzed hydrogenation, providing efficient reduction of ketones and
Yaoyu Liang +6 more
wiley +2 more sources
Oxidative dehydrogenation of ethane and propane over Mn-based catalysts
, 2000 The catalytic performances of Mn-based catalysts have been investigated for the oxidative dehydrogenation of both ethane (ODE) and propane (ODP). The results show that a LiCl/MnOx/PC (Portland cement) catalyst has an excellent catalytic performance for ...
Ge, QJ +4 more
core
, 2013 Copper nanoparticles dispersed rod-shaped La2O2CO3 efficiently catalyzed transfer dehydrogenation of primary aliphatic alcohols with an aldehyde yield of up to 97%. This high efficiency was achieved by creating a catalytically active nanoenvironement for
Wang, Fei +11 more
core +1 more source