Results 201 to 210 of about 1,764 (217)
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ChemInform Abstract: DEPSIDONE SYNTHESIS. IV. CALOPLOICIN
Chemischer Informationsdienst, 1976AbstractNach Beschreibung eines ‐ wegen zu geringer Ausbeute bei einer Ullmann‐Reaktion ‐ erfolglosen Reaktionsweges zur Titelverbindung (Vb) wird diese wie folgt dargestellt: Rhizinonsäure (I) wird mit Surfurylchlorid in 5‐Stellung chloriert (73% Ausbeute), dibenzyliert und sofort die Benzylestergruppe zu (II) hydrolysiert (91%).
MELVYN V. SARGENT, PAUL VOGEL
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Structure of the lichen depsidone gangaleoidin
Journal of the Chemical Society, Perkin Transactions 1, 1975As a result of degradative, spectroscopic, and synthetic evidence the structure of the lichen depsidone gangaleoidin is revised to methyl 2,4-dichloro-3-hydroxy-8-methoxy-1,6-dimethyl-11-oxo-11H-dibenzo [b,e][1,4]dioxepin-7-carboxylate. Gangaleoidin was degraded to methyl 3-(2-methoxycarbonyl-5-methoxy-3-methylphenoxy)-4,6-dimethoxy-2-methylbenzoate ...
Melvyn V. Sargent +2 more
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Depsidone synthesis. VII. Vicanicin and norvicanicin
Australian Journal of Chemistry, 1976The lichen Psoroma sphinctrinurn (Mont.) Nyl. occurs in two or more chemical strains. 2,7-Dichloro- 3 - hydroxy -8-methoxy- 1,4,6,9 - tetramethyl - 11H- dibenzo[b,e][l,4]dioxepin- 11-one (vicanicin) (2), a known depsidone, is a metabolite of one strain, and 2,7-dichloro-3,8-dihydroxy-1,4,6,9-tetramethyl-1lH-dibenzo[b,e][1,4]dioxepin-11-one ...
MV Sargent +3 more
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Colensionsäure, ein neues depsidon aus stereocaulon colensoi
Phytochemistry, 1970Zusammenfassung Stereocaulon colensoi Bab. enthalt Atranorin, d -Mannit, d -Arabit, Tetrahydroxyfettsauren und Colensoinsaure (I), ein neues Depsidon.
Cecil H Fox +2 more
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Journal of the Chemical Society, Perkin Transactions 1, 1981
The isolation, from the lichen Buellia canescens(Dicks.) De Not., and structural determination of the new depsidones 2,7,9-trichloro-3-hydroxy-8-methoxy-1,6-dimethyldibenzo[b,e][1,4]dioxepin-11-one (dechlorodiploicin)(1) and its methyl ether dechloro-O-methyldiploicin (9), together with the novel phthalides 4-chloro-7-(3,5-dichloro-4,6-dimethoxy-2 ...
Tony Sala +2 more
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The isolation, from the lichen Buellia canescens(Dicks.) De Not., and structural determination of the new depsidones 2,7,9-trichloro-3-hydroxy-8-methoxy-1,6-dimethyldibenzo[b,e][1,4]dioxepin-11-one (dechlorodiploicin)(1) and its methyl ether dechloro-O-methyldiploicin (9), together with the novel phthalides 4-chloro-7-(3,5-dichloro-4,6-dimethoxy-2 ...
Tony Sala +2 more
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ChemInform Abstract: DEPSIDONE SYNTHESIS. PART 18. DIHYDRONIDULIN
Chemischer Informationsdienst, 1981AbstractCycloaddition des Ketoesters (II) an das Olefin (I) gibt das Oxocyclohexenylcarboxylat (III), dessen Umsetzung mit 1 Moläquiv. Brom unter Aromatisierung zu (IVa) verläuft.
P. F. FINLAY‐JONES +2 more
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Depsidone synthesis. Part 20. Lecideoidin and dechlorolecideoidin
Journal of the Chemical Society, Perkin Transactions 1, 1981The synthesis of methyl 2,9-dichloro-3,8-dihydroxy-1,6-dimethyl-11-oxo-11H-dibenzo[b,e][1,4]dioxepin-7-carboxylate (lecideoidin)(1) and methyl 2-chloro-3,8-dihydroxy-1,6-dimethyl-11-oxo-11H-dibenzo[b,e][1,4]-dioxepin-7-carboxylate (dechlorolecideoidin)(2) by oxidation of benzophenones and subsequent steps is described.
Peter M. McEwen, Melvyn V. Sargent
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ChemInform Abstract: DEPSIDONE SYNTHESIS. PART 19. SOME β‐ORCINOL DEPSIDONES
Chemischer Informationsdienst, 1981T. SALA, M. V. SARGENT
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