Archaeal Genes Code for GGDEF Domain Proteins With Diguanylate Cyclase Activity
A biofilm‐like mode of growth is hypothesized to be required for the emergence of cellular life. Occurrence of common biofilm gene products in current Bacteria and Archaea is an indication for their previous presence in the last universal common ancestor LUCA and perhaps even in the first universal common ancestor FUCA.
Roman Sidorov +6 more
wiley +1 more source
Imine Directed Cp*RhIII -Catalyzed N-H Functionalization and Annulation with Amino Amides, Aldehydes, and Diazo Compounds. [PDF]
Zoll AJ +3 more
europepmc +1 more source
Using enynones and diazo carbonyl compounds as identical starting materials, methods for chemoselective and regioselective constructs of diazo-functionalized 2-methylene-2,3-dihydrofurans and diazo-functionalized trisubstituted furans have been ...
Yu Zhang (12946) +1 more
core +1 more source
Rhodium Catalyzed Arylation of Diazo Compounds with Aryl Boronic Acids
A general and efficient synthesis of diarylacetate, a diarylmethine derivative, was accomplished through rhodium catalyzed direct arylation of diazo compounds with arylboronic acids.
Jayanta Ghorai (1626721) +1 more
core +1 more source
Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu +2 more
wiley +1 more source
SuFExable NH-Pyrazoles via 1,3-Dipolar Cycloadditions of Diazo Compounds with Bromoethenylsulfonyl Fluoride. [PDF]
Yamanushkin P +3 more
europepmc +1 more source
Diazo and diazonium compounds as a primary explosives (except 2-diazo-4,6-dinitrophenol).
Bakalářská práce ?Třaskaviny na bázi diazo a diazoniových sloučenin (bez dinolu)? se zabývá problematikou třaskavin z oblasti diazosloučenin, které již v historii byly zkoumány a které nakonec nenalezly praktické uplatnění jako třaskaviny.
Fučík, Robin
core +1 more source
Selective N‐Functionalization of Pyrazoles
This review traces the evolution of regioselective N‐functionalization strategies for pyrazoles, a key class of nitrogen heterocycles widely used in medicinal chemistry. Due to rapid tautomerism, N‐functionalization often lacks selectivity, leading to poor and unpredictable regioisomeric outcomes.
Lucas Popek +2 more
wiley +1 more source
B(C6F5)3-Catalyzed Diastereoselective and Divergent Reactions of Vinyldiazo Esters with Nitrones: Synthesis of Highly Functionalized Diazo Compounds. [PDF]
Stefkova K +4 more
europepmc +1 more source
Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua +3 more
wiley +1 more source

