Results 1 to 10 of about 921 (148)
Substituted nitrogen-bridged diazocines. [PDF]
Beilstein J Org Chem, 2021 Novel nitrogen-bridged diazocines (triazocines) were synthesized that carry a formyl or an acetyl group at the CH 2 NR-bridge and bromo- or iodo-substituents at the distant phenyl ring. The photophysical properties were investigated in acetonitrile and water.
Lentes P +3 more
europepmc +6 more sources
Photoswitching Lanthanoid Luminescence With Diazocines. [PDF]
ChemistryAbstractThe unique photophysical properties of the lanthanoids provide the core functionality for various high‐tech applications, including optoelectronic materials, lasers, anti‐counterfeiting dyes, or tools for biological sciences. The combination of these luminophores with photoswitches has the potential to make them remote controllable and adds new
Winterholler N, Kreidt E.
europepmc +3 more sources
Light-Powered Dissipative Assembly of Diazocine Coordination Cages. [PDF]
J Am Chem Soc, 2022 Stimuli-responsive coordination cages allow reversible control over guest binding and release, relevant for adaptive receptors, carriers, catalysts, and complex systems. Light serves as an advantageous stimulus, as it can be applied with precise spatial and temporal resolution without producing chemical waste products.
Lee H +5 more
europepmc +5 more sources
Diazocine-functionalized TATA platforms [PDF]
Beilstein Journal of Organic Chemistry, 2019 Recently, it has been shown that the thermochemical cis → trans isomerization of azobenzenes is accelerated by a factor of more than 1000 by electronic coupling to a gold surface via a conjugated system with 11 bonds and a distance of 14 Å.
Roland Löw +4 more
openaire +3 more sources
Photoswitching of Diazocines in Aqueous Media
The Journal of Organic Chemistry, 2021 We present a systematic investigation of the photophysical properties of diazocines in aqueous media. The Z-E photoconversion yields of CH2CH2- and CH2S-bridged diazocines decrease with increasing water content in acetonitrile. However, there is one exception.
Pascal Lentes +6 more
openaire +3 more sources
Reproductive Mechanisms Influenced by a Diazocine
Experimental Biology and Medicine, 1965 Summary2,8-Dichloro-6,12-diphenyl-dibenzo[b,f][l,5] diazocine completely inhibited pregnancy when administered either orally or subcutaneously to female rats at doses as low as 0.5 mg daily for 7 days at time of mating. At higher doses, single treatments prior to completion of implantation were equally effective.
G W, Duncan, S C, Lyster, J B, Wright
openaire +2 more sources
Amino-substituted diazocines as pincer-type photochromic switches [PDF]
Beilstein Journal of Organic Chemistry, 2013 Azobenzenes are robust, reliable, and easy to synthesize photochromic switches. However, their high conformational flexibility is a disadvantage in machine-like applications. The almost free rotation of the phenyl groups can be restricted by bridging two ortho positions with a CH2CH2 group, as realized in the dihydrodibenzo diazocine framework.
Hanno Sell +2 more
openaire +3 more sources
The Pyrolysis of 1,2,3,4,6,7-Hexathia-5,8-diazocine [PDF]
Bulletin of the Chemical Society of Japan, 1990 Abstract Crystals of 1,2,3,4,6,7-hexathia-5,8-diazocine (1,4-S6(NH)2) were transformed around 363 K with a molar enthalpy change of the transformation of 2.40±0.07 kJ mol−1. Crystal systems of the two forms of 1,4-S6(NH)2 were identified to be orthorhombic (α-form) and monoclinic (β-form) below and above this temperature.
Yoshiyuki Kudo +2 more
openaire +1 more source
Triplet sensitization enables bidirectional isomerization of diazocine with 130 nm redshift in excitation wavelengths. [PDF]
Chem Sci, 2023 Isokuortti J +7 more
europepmc +1 more source
Stille vs. Suzuki - cross-coupling for the functionalization of diazocines. [PDF]
RSC Adv, 2023 Walther M +3 more
europepmc +1 more source