Results 11 to 20 of about 630 (149)
Crystals, 2022 Pyrazole-phenylmethanimines (Shiff bases), Py–N=CH–Ph, form molecular crystals whose supramolecular and self-assembly properties can be tuned according to the substitution made on the aromatic and pyrazole rings.
Fernando Cuenú-Cabezas +2 more
doaj +2 more sources
Tröger’s Base-Derived Thermally Activated Delayed Fluorescence Dopant for Efficient Deep-Blue Organic Light-Emitting Diodes [PDF]
Molecules, 2023 The development of efficient deep-blue emitters with thermally activated delayed fluorescence (TADF) properties is a highly significant but challenging task in the field of organic light-emitting diode (OLED) applications.
Ze-Ling Wu +4 more
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Solvent-Free Synthesis of Diazocine
Synthesis, 2017 A convenient two-step synthesis of diazocine starting from 2-nitrotoluene is described. The first step, the oxidative dimerization of 2-nitrotoluene, is improved to 95% yield. The second step, the reductive azo cyclization, is performed as a solvent-free reaction with lead powder in a ball mill (51% yield).
Widukind Moormann +2 more
openaire +2 more sources
Photoswitchable Diazocine Derivative for Adenosine A<sub>3</sub> Receptor Activation in Psoriasis. [PDF]
J Am Chem SocIncorporating photoisomerizable moieties within drugs offers the possibility of rapid and reversible light-dependent switching between active and inactive configurations.
López-Cano M +11 more
europepmc +2 more sources
Photoswitchable Azo- and Diazocine-Functionalized Derivatives of the VEGFR-2 Inhibitor Axitinib. [PDF]
Int J Mol Sci, 2020 In this study, we aimed at the application of the concept of photopharmacology to the approved vascular endothelial growth factor receptor (VEGFR)-2 kinase inhibitor axitinib.
Heintze L +7 more
europepmc +2 more sources
Synthesis and Properties of Cyclic Imide Extended Diazocines: Tweezer-Like, Rigid Photoswitches with Large Switching Amplitudes. [PDF]
ChemistryDiazocines are bridged azobenzenes with improved photophysical properties. One of the main features is the fact that, unlike the azobenzenes, the Z form is more stable than the E isomer. Another important property is the more rigid structure (tricyclic),
Businski A +6 more
europepmc +2 more sources
A Scanning Tunneling Microscopy Study of the Photoisomerization of Diazocine
The Journal of Physical Chemistry LettersAzobenzenes are fascinating molecular machines that can reversibly transform between two isomeric forms by an external stimulus. Diazocine, a type of bridged azobenzene, has been shown to possess enhanced photoexcitation properties. Due to the distortion caused by the ethyl bridge in the E-isomer, the Z-form becomes the thermodynamically stable ...
Chamathka Dehiwala Liyanage +5 more
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Photoswitching of Diazocines in Aqueous Media
The Journal of Organic Chemistry, 2021 We present a systematic investigation of the photophysical properties of diazocines in aqueous media. The Z-E photoconversion yields of CH2CH2- and CH2S-bridged diazocines decrease with increasing water content in acetonitrile. However, there is one exception.
Pascal Lentes +6 more
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Active Ester Functionalized Azobenzenes as Versatile Building Blocks
Molecules, 2021 Azobenzenes are important molecular switches that can still be difficult to functionalize selectively. A high yielding Pd-catalyzed cross-coupling method under mild conditions for the introduction of NHS esters to azobenzenes and diazocines has been ...
Sven Schultzke +2 more
doaj +1 more source
International Journal of Photoenergy, 2022 In this study, we propose dibenzo[b,f][1,5]diazocine/ZnO organic/inorganic hybrid photoanode for application in the photoelectrochemical water splitting.
Sissembayeva Yana +2 more
doaj +1 more source