Results 91 to 100 of about 252 (117)
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ChemInform, 1995
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
G. S. USCUMLIC, M. D. MUSKATIROVIC
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AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
G. S. USCUMLIC, M. D. MUSKATIROVIC
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Chemischer Informationsdienst, 1982
AbstractWährend die Thermolyse der Titelverbindung (I) in O2‐ gesättigtem Lösungsmittel zu Benzophenon (II) (Ausb. 70%) und dem Azin (III) (30%) führt, wird bei einem Zusatz von S‐Verbindungen wie z.B. 1,2,3‐Benzothiadiazol (BTD) oder Dibenzylsulfid (DBS), der die Reaktion mit steigender Konzentration zunehmend beschleunigt, hauptsächlich das Ethylen ...
L. BENATI +2 more
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AbstractWährend die Thermolyse der Titelverbindung (I) in O2‐ gesättigtem Lösungsmittel zu Benzophenon (II) (Ausb. 70%) und dem Azin (III) (30%) führt, wird bei einem Zusatz von S‐Verbindungen wie z.B. 1,2,3‐Benzothiadiazol (BTD) oder Dibenzylsulfid (DBS), der die Reaktion mit steigender Konzentration zunehmend beschleunigt, hauptsächlich das Ethylen ...
L. BENATI +2 more
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Journal of the Chemical Society, Perkin Transactions 2, 1978
The kinetics of the reactions of meta- and para-substituted diazodiphenylmethanes (DDM) with tetracyanoethylene (TCNE) in benzene are reported. The corresponding 1,1-diaryl-2,2,3,3-tetracyanocyclopropanes were produced almost quantitatively and the second-order rate constants k increased with the electron-donating ability of the substituents; the ...
Takumi Oshima +2 more
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The kinetics of the reactions of meta- and para-substituted diazodiphenylmethanes (DDM) with tetracyanoethylene (TCNE) in benzene are reported. The corresponding 1,1-diaryl-2,2,3,3-tetracyanocyclopropanes were produced almost quantitatively and the second-order rate constants k increased with the electron-donating ability of the substituents; the ...
Takumi Oshima +2 more
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Solvent effects on the reactivity of pyridine and pyridine-N-oxide carboxylic acids and p-substituted benzoic acids in their reaction with diazodiphenylmethane (DDM) in alcohols have been investigated and the rate constants interpreted by Hammett ...
Drmanić, Saša +2 more
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J. Chem. Soc., Perkin Trans. 2, 1974
The empirical Hammett treatment has been applied to the investigation of structure–reactivity relationships for pyridine and pyridine N-oxide carboxylic acids in the reaction with diazodiphenylmethane. The values obtained for the pyridine aza-group (σ2 0·878, σ3 0·740, σ41·105) are in good agreement with the literature values for the alkaline ...
Djordje M. Dimitrijević +3 more
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The empirical Hammett treatment has been applied to the investigation of structure–reactivity relationships for pyridine and pyridine N-oxide carboxylic acids in the reaction with diazodiphenylmethane. The values obtained for the pyridine aza-group (σ2 0·878, σ3 0·740, σ41·105) are in good agreement with the literature values for the alkaline ...
Djordje M. Dimitrijević +3 more
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Journal of the Chemical Society, Perkin Transactions 2, 1982
Rate constants have been determined for the reactions at 30, 35, and 40 °C of diazodiphenylmethane with 4′-substituted biphenyl-4-carboxylic acids and 4-substituted 1-naphthoic acids in 14 alcohols. Hammett ρ values have been evaluated for the reactions in 11 of the alcohols.
P. Ananthakrishnanadar +2 more
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Rate constants have been determined for the reactions at 30, 35, and 40 °C of diazodiphenylmethane with 4′-substituted biphenyl-4-carboxylic acids and 4-substituted 1-naphthoic acids in 14 alcohols. Hammett ρ values have been evaluated for the reactions in 11 of the alcohols.
P. Ananthakrishnanadar +2 more
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Chemischer Informationsdienst, 1979
AbstractDie Geschwindigkeitskonstanten 2. Ordnung für die Titelreaktion nehmen mit der Donatorfähigkeit der Substituenten in den Diazomethanen (I) zu.
T. OSHIMA, A. YOSHIOKA, T. NAGAI
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AbstractDie Geschwindigkeitskonstanten 2. Ordnung für die Titelreaktion nehmen mit der Donatorfähigkeit der Substituenten in den Diazomethanen (I) zu.
T. OSHIMA, A. YOSHIOKA, T. NAGAI
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ChemInform, 1998
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
G. S. USCUMLIC, V. V. KRSTIC
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AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
G. S. USCUMLIC, V. V. KRSTIC
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Chemischer Informationsdienst, 1975
AbstractZahlreiche Cärbonsäuren (I) werden mit Diphenyldiazomethan (II) umgesetzt.
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AbstractZahlreiche Cärbonsäuren (I) werden mit Diphenyldiazomethan (II) umgesetzt.
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Canadian Journal of Chemistry, 1969
A series of 9-substituted 10-triptoic acids have been prepared. Their pKa values in 80% 2-methoxy-ethanol–water and 50% ethanol–water at 25° and rate coefficients for esterification with diazodiphenyl-methane in five alcohols at 30° have been measured. The results have been analyzed by linear free energy relations.
Keith Bowden, D. C. Parkin
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A series of 9-substituted 10-triptoic acids have been prepared. Their pKa values in 80% 2-methoxy-ethanol–water and 50% ethanol–water at 25° and rate coefficients for esterification with diazodiphenyl-methane in five alcohols at 30° have been measured. The results have been analyzed by linear free energy relations.
Keith Bowden, D. C. Parkin
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