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A LFER Kinetic Study of The Reaction of 5‐Substituted Orotic Acids with Diazodiphenylmethane
International Journal of Chemical Kinetics, 2016ABSTRACTLinear free energy relationships (LFER) were applied to the kinetic data for the reaction of 5‐substituted orotic acids, series 1, with diazodiphenylmethane (DDM) in N,N–dimethylformamide and compared with results obtained for 2‐substituted benzoic acids, series 2.
Assaleh, Fathi H. +6 more
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Die Makromolekulare Chemie, 1974
AbstractSyndiotactic poly(methacrylic acid) has been partially esterified with diazotoluene or diazodiphenylmethane in extension of work carried out with diazomethane1. The sequence statistics of the resulting cosyndiotactic benzyl methacrylate–methacrylic acid and diphenylmethyl methacrylate–methacrylic acid copolymers have been studied with 1H‐NMR ...
Dieter Strasilla, Ernst Klesper
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AbstractSyndiotactic poly(methacrylic acid) has been partially esterified with diazotoluene or diazodiphenylmethane in extension of work carried out with diazomethane1. The sequence statistics of the resulting cosyndiotactic benzyl methacrylate–methacrylic acid and diphenylmethyl methacrylate–methacrylic acid copolymers have been studied with 1H‐NMR ...
Dieter Strasilla, Ernst Klesper
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Journal of the Chemical Society, Perkin Transactions 2, 1981
Thermal decomposition at 80 °C of diazodiphenylmethane in oxygen-saturated chlorobenzene in the presence of sulphur compounds (5)–(8) affords tetraphenylethylene, benzophenone, benzophenone azine, as well as small amounts of bisdiphenylmethyl ether.
Luisa Benati +2 more
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Thermal decomposition at 80 °C of diazodiphenylmethane in oxygen-saturated chlorobenzene in the presence of sulphur compounds (5)–(8) affords tetraphenylethylene, benzophenone, benzophenone azine, as well as small amounts of bisdiphenylmethyl ether.
Luisa Benati +2 more
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Bulletin of the Chemical Society of Japan, 1983
Abstract A high pressure kinetic study was made of the 1,3-dipolar cycloaddition reaction of Ph2CN2 with dimethyl maleate (DMM), dimethyl fumarate (DMF), methyl acrylate (MA), maleonitrile (MN), fumaronitrile (FN), and acrylonitrile (AN) in toluene at 25 °C. The activation volumes (ΔV\eweq) at 1 bar obtained for DMM, DMF, MA, MN, FN, and
Yosuke Yoshimura +2 more
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Abstract A high pressure kinetic study was made of the 1,3-dipolar cycloaddition reaction of Ph2CN2 with dimethyl maleate (DMM), dimethyl fumarate (DMF), methyl acrylate (MA), maleonitrile (MN), fumaronitrile (FN), and acrylonitrile (AN) in toluene at 25 °C. The activation volumes (ΔV\eweq) at 1 bar obtained for DMM, DMF, MA, MN, FN, and
Yosuke Yoshimura +2 more
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J. Chem. Soc., Perkin Trans. 2, 1994
The reactivities of 2-substituted cyclohex-1-enylacetic acids with diazodiphenylmethane in eleven alcohols has been investigated. The solvent effect is interpreted in terms of the influence of the relative permittivity on the rate constants. The multiple linear correlation of log k with the Kirkwood function of relative permittivity, Taft σ* value for ...
Gordana S. Ušćumlić +1 more
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The reactivities of 2-substituted cyclohex-1-enylacetic acids with diazodiphenylmethane in eleven alcohols has been investigated. The solvent effect is interpreted in terms of the influence of the relative permittivity on the rate constants. The multiple linear correlation of log k with the Kirkwood function of relative permittivity, Taft σ* value for ...
Gordana S. Ušćumlić +1 more
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The Reactivity of 2‐(4‐Phenylsubstituted)‐α,β‐Unsaturated Carboxylic Acids with Diazodiphenylmethane
Quantitative Structure-Activity Relationships, 1991AbstractIn connection with a study of the transmission of polar effects through ring double bonds, double bonds in open chain systems and delocalized double bonds, the reactivity of 2‐(4‐phenylsubstituted)‐α,β‐unsaturated carboxylic acids with diazodiphenylmethane in ethanol was investigated.
Gordana S. Ušćaumlića +2 more
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ChemInform, 1987
AbstractResults of a reinvestigation of the anodically initiated chain reaction of Ph2CN2 in dry MeCN or in solvents containing H2O or MeOH lead to the suggestion that H+ is the chain carrier.
J. M. BAKKE, D. BETHELL, V. D. PARKER
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AbstractResults of a reinvestigation of the anodically initiated chain reaction of Ph2CN2 in dry MeCN or in solvents containing H2O or MeOH lead to the suggestion that H+ is the chain carrier.
J. M. BAKKE, D. BETHELL, V. D. PARKER
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J. Chem. Soc., Perkin Trans. 2, 1993
The reactivities of 2-substituted cyclohex-1-enecarboxylic acids with diazodiphenylmethane in several alcohols were investigated. The rate data for these acids were correlated with a simple Hammett equation by means of the σp constants. The transmission of polar effects through the double bond, in terms of polar susceptibility constant ρ, has been ...
Gordana S. Ušćumlić +2 more
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The reactivities of 2-substituted cyclohex-1-enecarboxylic acids with diazodiphenylmethane in several alcohols were investigated. The rate data for these acids were correlated with a simple Hammett equation by means of the σp constants. The transmission of polar effects through the double bond, in terms of polar susceptibility constant ρ, has been ...
Gordana S. Ušćumlić +2 more
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Chemischer Informationsdienst, 1976
AbstractDurch Oxidation der Hydrazone (I) mit Peressigsäure in Gegenwart von Tetramethylguanidin (TMG) als Base und einer Spur Jod in einem organischen Lösungsmittel (Methode A) werden die Diazomethanderivate (II) dargestellt.
J. ROBERT ADAMSON +5 more
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AbstractDurch Oxidation der Hydrazone (I) mit Peressigsäure in Gegenwart von Tetramethylguanidin (TMG) als Base und einer Spur Jod in einem organischen Lösungsmittel (Methode A) werden die Diazomethanderivate (II) dargestellt.
J. ROBERT ADAMSON +5 more
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