Ring-Chain Tautomerism. Part 10. The Reaction of Oxocarboxylic Acids with Diazodiphenylmethane
Collection of Czechoslovak Chemical Communications, 1999 The rate coefficients for the esterification of a series of oxocarboxylic acids with diazodiphenylmethane have been determined in ethanol or 2-methoxyethanol at 30.0 °C. These and the rates of reaction with model compounds have been used to estimate the equilibrium constants for ring-chain tautomerism for the oxocarboxylic acids.
Keith Bowden +2 more
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Kinetics and mechanism of the reaction of substituted 4-pyrimidine carboxylic acids with diazodiphenylmethane in dimethylformamide [PDF]
Journal of Chemical Research, 2000 Correlation of the data for the reaction of 11 substituted 4-pyrimidine carboxylic acids with diazodiphenylmethane (DDM) in dimethylformamide (DMF) with calculated atomic charges on the carboxylic group showed that the reaction in this solvent may proceed via a concerted transition state.
Jovanović, Bratislav +4 more
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Investigations of the reactivity of pyridine carboxylic acids with diazodiphenylmethane in protic and aprotic solvents. [PDF]
Journal of the Serbian Chemical Society, 2005 Rate constants for the reaction of diazodiphenylmethane with isomeric pyridine carboxylic acids were determined in chosen protic and aprotic solvents at 30 °C, using the well known UV spectrophotometric method.
ALEKSANDAR D. MARINKOVIC +3 more
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International Journal of Chemical Kinetics, 2005 AbstractThe rate constants for the reaction of different cycloalkenylcarboxylic, cycloalkenylacetic acids, and phenylacetic acid with diazodiphenylmethane were determined in 12 aprotic solvents at 30°C. In order to explain the kinetic results through solvent effects, the second‐order rate constant of the examined acids was correlated using the Kamlet ...
Nikolić, Jasmina +2 more
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Diazodiphenylmethane, C13H10N2.
Journal of Synthetic Organic Chemistry, Japan, 1992 Yoshihiko HIRAYAMA, Yukitomo KOUNO
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Effects of solvent and structure on the reactivity of 6-substituted nicotinic acids with diazodiphenylmethane in aprotic solvents [PDF]
Journal of the Serbian Chemical Society, 2009 The rate constants for the reactions of diazodiphenylmethane (DDM) with 6-substituted nicotinic acids in aprotic solvents at 30°C were determined. The obtained second order rate constants in aprotic solvents, together with literature data for benzoic and
Drmanić Saša Ž. +2 more
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Microsolvation Of Carbenes In Superfluid Helium Nanodroplets [PDF]
, 2021 Carbenes are classified as an important reactive intermediate in chemical reactions owing to their multiple spin states. Recent studies in matrix isolation technique (3 K) demonstrated that a single water molecule is able to switch the spin state of ...
Khatri, Jai
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A linear solvation energy relationship study for the reactivity of 2-substituted cyclohex-1-enecarboxylic and 2-substituted benzoic acids with diazodiphenylmethane in aprotic and protic solvents [PDF]
Journal of the Serbian Chemical Society, 2007 The rate constants for the reaction of 2-substituted cyclohex-1-enylcarboxylic acids and the corresponding 2-substituted benzoic acids with diazodiphenyl methane were determined in various aprotic solvents at 30 ºC.
JASMINA B. NIKOLIC, GORDANA S. USCUMLIC
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The influence of the solvent on organic reactivity. Part II. Hydroxylic solvent effects on the reaction rates of diazodiphenylmethane with 2-(2-substituted cyclohex-1-enyl)acetic and 2-(2-substituted [PDF]
Journal of the Serbian Chemical Society, 2004 The rate constants for the reaction of diazodiphenylmethane with 2-(2-substituted cyclohex-1-enyl)acetic acids and 2-(2-substituted phenyl)acetic acids, previously determined in seven hydroxylic solvents, were correlated using the total solvatochromic ...
Nikolić Jasmina B. +2 more
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Investigations of the reactivity of pyridine carboxylic acids with diazodiphenylmethane in protic and aprotic solvents. Part II. Pyridine mono-carboxylic acid N-oxides [PDF]
Journal of the Serbian Chemical Society, 2006 The rate constants for the reaction of three isomeric pyridine mono-carbocylic acid N-oxides with diazodiphenylmethane were determined at 30 ºC in thirty two protic and aprotic solvents by the well known UV spectrophotometric method.
MILICA MISIC-VUKOVIC +3 more
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