Results 81 to 90 of about 43,385 (264)
Abstract Oxidation of furfural (FF), a bio‐based platform chemical, was investigated using a range of iron‐, vanadium‐ and iron–zinc‐oxalates supported on silica gel (FeVOx@silica and FeZnOx@silica, respectively) as precursor for FeV@silica and FeZn@silica oxide catalysts and H2O2 as a green oxidant.
Alexander Pokutsa +2 more
wiley +1 more source
This review provides a comprehensive and systematic overview of the multifunctional design strategies for solid polymer electrolytes (SPEs), a pivotal component for enabling high‐performance all‐solid‐state batteries (ASSBs). It begins with a detailed classification of SPE systems and elaborates on their respective molecular design principles. The work
Bin Man +11 more
wiley +1 more source
Molecular distributions of dicarboxylic acids, ketocarboxylic acids and α-dicarbonyls in biomass burning aerosols: implications for photochemical production and degradation in smoke layers [PDF]
Aerosols in the size class <2.5 μm (6 daytime and 9 nighttime samples) were collected at a pasture site in Rondônia, Brazil, during the intensive biomass burning period of 16–26 September 2002 as part of the Large-Scale Biosphere-Atmosphere ...
A. Hoffer +4 more
doaj
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve +4 more
wiley +1 more source
Synthesis of Dithienylcycloalkene Molecular Switches Enabled by a Bench‐Stable Ti‐Complex
Herein we report a set of cycloalkene‐bridged DTEs with ring sizes ranging from 4‐ to 7‐membered rings. The synthesis of these analogs was performed via a key McMurry coupling step, which was enabled by a practical, bench‐stable Ti(IV)‐complex. Remarkably, it is shown that the strained cyclobutene bridge outperforms other rings, even the most commonly ...
Marcell M. Bogner +4 more
wiley +1 more source
Enzymology of dicarboxylic acid metabolism in Corynebacterium sp. strain 7E1C [PDF]
1.Dicarboxylic acid metabolism was investigated in the alkane-utilizing bacterium Corynebacterium 7E1C.2.The best yields of dicarboxylic acid were obtained during growth on dodecane although significant amounts of tetradecanedioic acid were produced ...
Broadway, Neil Michael
core
A scalable carboxylation route to furan-2,5-dicarboxylic acid
2-Furoic acid is converted to furan-2,5-dicarboxylic acid in high yield on a mole scale using carbonate-promoted C–H carboxylation.
Matthew W. Kanan +3 more
core +1 more source
Transitioning Formamide Solvothermal Syntheses of MOFs to Less Toxic Solvents
Metal‐organic Frameworks (MOFs) are commonly synthesized in toxic formamide solvents. This study investigates the synthetic factors required for effective removal of formamides across various classes of MOFs, providing a foundation for designing new sustainable MOF syntheses.
Julia C. Donovan +2 more
wiley +1 more source
REVISION OF INOUYE SYNTHESIS OF CHRYSANTHEMUM-DICARBOXYLIC ACID
SCHARF HD, Mattay J. REVISION OF INOUYE SYNTHESIS OF CHRYSANTHEMUM-DICARBOXYLIC ACID. Chemische Berichte.
Mattay, Jochen, SCHARF, HD
core +1 more source
Tetrazine Ligation in Living Systems: Beyond Fast Kinetics to Effective Bioorthogonality
Rapid reaction kinetics (k2) alone do not ensure successful tetrazine ligation in living systems. This review introduces ‘effective orthogonality’—focusing on chemical survival, availability, and encounter—as a practical framework. We highlight how bottlenecks shift from cellular sinks to in vivo delivery limits, offering design strategies for reliable
Junhyeong Yim +3 more
wiley +1 more source

