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Synthetic studies toward the kempane diterpenes. Diels–Alder additions to bicyclic dienes

Journal of the Chemical Society, Perkin Transactions 1, 2001
Diels–Alder additions of 2,6-dimethyl-p-benzoquinone to the bicyclic dienes 24, 30 and 32 took place with very high regio-, stereo- and facial selectivity. Reduction and then alkylation of a tetracyclic adduct with 1,3-dithienium tetrafluoroborate provided compound 56, which has the correct stereochemistry at three key carbons for elaboration to the ...
Chunjian Liu   +2 more
openaire   +1 more source

Intramolecular Diels–Alder reactions of N-substituted oxazolones

Chemical Communications, 2002
The first intramolecular Diels-Alder reactions of simple trienes featuring an N-substituted oxazolone as the dienophilic component have been investigated and are reported herein.
Stephen Philip, Fearnley   +1 more
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Stereocontrolled construction of rigid tricyclic bis(α-amino acid) derivatives by Ru(Ii)-catalyzed cascade and Diels–Alder reactions

Journal of the Chemical Society, Perkin Transactions 1, 2001
In the preparation of rigid and annulated tricyclic bis(α-amino acid) derivatives the key construction was effected by a Ru(II)-catalyzed RCM cascade reaction of gem-dienynes. The substrates were available by stepwise and stereocontrolled alkynylations and alkenylations of (2R)-2,5-dihydro-2-isopropyl-3,6-dimethoxypyrazine.
Jon Efskind   +2 more
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Competing Diels–Alder reactions of activated nitroethylene derivatives and [3,3]-sigmatropic rearrangements of the cycloadducts

Chemical Communications, 2002
AbstractFor Abstract see ChemInform Abstract in Full Text.
Peter A, Wade   +3 more
openaire   +2 more sources

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