Generation [via Tetradehydro-Diels-Alder Reactions] and Reactivity of 6-Fluorocyclohexa-1,2,4-triene Intermediates. [PDF]
Kevorkian PV, Hoye TR.
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Dual-Mode Thio-MacMillan Organocatalysts: Stereoselective Diels-Alder Reactions or Sacrificial Self-Cyclization to N-Bridged Bicyclic Lactams. [PDF]
Ebeling MSR +5 more
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Zwitterionic Pathway in the Diels-Alder Reaction: Solvent and Substituent Effects from ωB97XD/6-311G(d) Calculations. [PDF]
Łapczuk A.
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A Remarkable Selectivity Observed in Hetero-Diels-Alder Reactions of Levoglucosenone (LGO) with Thiochalcones: An Experimental and Computational Study. [PDF]
Mlostoń G +5 more
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An Inverse Electron-Demand Diels-Alder Approach to Selective Activity-Based Sensing of Acetaldehyde in Living Cells. [PDF]
Li Y, Li G, Li EL, Kim J, Chang CJ.
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Synthetic studies toward the kempane diterpenes. Diels–Alder additions to bicyclic dienes
Journal of the Chemical Society, Perkin Transactions 1, 2001Diels–Alder additions of 2,6-dimethyl-p-benzoquinone to the bicyclic dienes 24, 30 and 32 took place with very high regio-, stereo- and facial selectivity. Reduction and then alkylation of a tetracyclic adduct with 1,3-dithienium tetrafluoroborate provided compound 56, which has the correct stereochemistry at three key carbons for elaboration to the ...
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Intramolecular Diels–Alder reactions of N-substituted oxazolones
Chemical Communications, 2002The first intramolecular Diels-Alder reactions of simple trienes featuring an N-substituted oxazolone as the dienophilic component have been investigated and are reported herein.
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In the preparation of rigid and annulated tricyclic bis(α-amino acid) derivatives the key construction was effected by a Ru(II)-catalyzed RCM cascade reaction of gem-dienynes. The substrates were available by stepwise and stereocontrolled alkynylations and alkenylations of (2R)-2,5-dihydro-2-isopropyl-3,6-dimethoxypyrazine.
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AbstractFor Abstract see ChemInform Abstract in Full Text.
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