Site-selective bromination of anthracene-maleimide Diels-Alder crystals for tunable afterglow and white light emission. [PDF]
Yang G +5 more
europepmc +1 more source
Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua +3 more
wiley +1 more source
The elusive <i>endo</i>-product of the archetypal Diels-Alder reaction of furan and maleic anhydride - observed in the solid state at last. [PDF]
Lennox CB +10 more
europepmc +1 more source
Surface‐bound ferulate phenolate complexes undergo styrene‐like polymerization on alumina, yielding a polymeric carbonaceous layer that progressively transforms into polyaromatic carbon domains with concomitant release of aromatic products, while parallel surface‐assisted decarboxylation produces 4‐vinylguaiacol. ABSTRACT A fundamental understanding of
Tetiana V. Kulik +11 more
wiley +1 more source
Diels-Alder Reactions in [Pd<sub>6</sub>L<sub>4</sub>]<sup>12+</sup> Metallocages: The Key Roles of Preorganization and Confinement. [PDF]
Sciortino G +3 more
europepmc +1 more source
Chelation‐Assisted Metal‐Catalyzed Ligation and Cleavage Reactions for Chemical Biology
Chelation‐assisted transition metal catalysis has emerged as a promising complement to bioorthogonal click chemistry for studying biological processes. By pre‐organizing catalytic metal centers, designed coordinating substrates enhance reactivity and biocompatibility, enabling site‐selective ligation and decaging reactions in complex biological media ...
Emilie Plantiveau +3 more
wiley +1 more source
Diels-Alder Click Chemistry as a Dynamic-Covalent Crosslinking Method in Spheroid-Encapsulating Hydrogels for Cartilage Engineering. [PDF]
van de Looij SM +8 more
europepmc +1 more source
Molybdooxaziridine Catalysis: Synthesis of α‐Hydroxysulfones From Styrenes Through an ATRA Process
This work has discovered that molybdooxaziridine catalysts promote the hydroxysulfonation of substituted α‐methyl‐styrenes using N‐Ts‐hydroxylamine as the nitrogen source. An atom‐transfer‐radical‐addition mechanism involving the stepwise addition of Ts and hydroxy radicals takes place.
Alyssa N. Singer, Gustavo Moura‐Letts
wiley +1 more source
Erneuerbare Guajacole werden durch Phenyliodid(III)diacetat rasch zu maskierten ortho‐Chinonen oxidiert und bilden eine neue Monomerklasse, die mit Multithiolen selektive Michael‐Typ‐Polyadditionen zu Polymeren mit Thiol‐Guajacol‐Verknüpfungen eingeht.
Dominik P. Hoch +7 more
wiley +1 more source
Sulfonyl-Directed Photoinduced Dehydro-Diels-Alder Reaction of Aryl Maleimides: Enabling Regioselective Naphthalene Synthesis. [PDF]
Song XH +5 more
europepmc +1 more source

