Results 191 to 200 of about 81,193 (228)

Cyclopropylamine‐Derived Distonic Iminium Radicals: Photoinduced Strategies in Chemo‐ and Stereo‐Selective Synthesis

open access: yesChemistry – A European Journal, Volume 32, Issue 39, 22 October 2026.
Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua   +3 more
wiley   +1 more source

The elusive <i>endo</i>-product of the archetypal Diels-Alder reaction of furan and maleic anhydride - observed in the solid state at last. [PDF]

open access: yesChem Sci
Lennox CB   +10 more
europepmc   +1 more source

Mechanistic Insights Into Sustainable Catalytic Pyrolysis of Biomass‐Derived Ferulic Acid: The Role of Alumina Regeneration

open access: yesChemistry – A European Journal, Volume 32, Issue 39, 22 October 2026.
Surface‐bound ferulate phenolate complexes undergo styrene‐like polymerization on alumina, yielding a polymeric carbonaceous layer that progressively transforms into polyaromatic carbon domains with concomitant release of aromatic products, while parallel surface‐assisted decarboxylation produces 4‐vinylguaiacol. ABSTRACT A fundamental understanding of
Tetiana V. Kulik   +11 more
wiley   +1 more source

Chelation‐Assisted Metal‐Catalyzed Ligation and Cleavage Reactions for Chemical Biology

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 39, 22 October 2026.
Chelation‐assisted transition metal catalysis has emerged as a promising complement to bioorthogonal click chemistry for studying biological processes. By pre‐organizing catalytic metal centers, designed coordinating substrates enhance reactivity and biocompatibility, enabling site‐selective ligation and decaging reactions in complex biological media ...
Emilie Plantiveau   +3 more
wiley   +1 more source

Diels-Alder Click Chemistry as a Dynamic-Covalent Crosslinking Method in Spheroid-Encapsulating Hydrogels for Cartilage Engineering. [PDF]

open access: yesAdv Healthc Mater
van de Looij SM   +8 more
europepmc   +1 more source

Molybdooxaziridine Catalysis: Synthesis of α‐Hydroxysulfones From Styrenes Through an ATRA Process

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 39, 22 October 2026.
This work has discovered that molybdooxaziridine catalysts promote the hydroxysulfonation of substituted α‐methyl‐styrenes using N‐Ts‐hydroxylamine as the nitrogen source. An atom‐transfer‐radical‐addition mechanism involving the stepwise addition of Ts and hydroxy radicals takes place.
Alyssa N. Singer, Gustavo Moura‐Letts
wiley   +1 more source

Transformative Chemie maskierter Ortho‐Chinone: Über die direkte Aktivierung von Guajacol zu Lignin‐basierten Klebstoffen

open access: yesAngewandte Chemie, Volume 138, Issue 43, 19 October 2026.
Erneuerbare Guajacole werden durch Phenyliodid(III)diacetat rasch zu maskierten ortho‐Chinonen oxidiert und bilden eine neue Monomerklasse, die mit Multithiolen selektive Michael‐Typ‐Polyadditionen zu Polymeren mit Thiol‐Guajacol‐Verknüpfungen eingeht.
Dominik P. Hoch   +7 more
wiley   +1 more source

Home - About - Disclaimer - Privacy