Results 111 to 120 of about 66,029 (249)

Dual‐Mode Thio‐MacMillan Organocatalysts: Stereoselective Diels–Alder Reactions or Sacrificial Self‐Cyclization to N‐Bridged Bicyclic Lactams

open access: yesChemistry – A European Journal, EarlyView.
The study of the Diels–Alder reaction of cinnamaldehyde and cyclopentadiene, catalyzed by chiral imidazolidine‐4‐thiones, led to the discovery of a highly regio‐ and stereoselective Michael‐addition and consecutive ring closure. Here, the imidazolidine‐4‐thione not only catalytically activates cinnamaldehyde but also participates as the nucleophile to ...
Marian S. R. Ebeling   +5 more
wiley   +1 more source

Expanding the scope of cyclopropene reporters for the detection of metabolically engineered glycoproteins by Diels–Alder reactions

open access: yesBeilstein Journal of Organic Chemistry, 2014
Monitoring glycoconjugates has been tremendously facilitated by the development of metabolic oligosaccharide engineering. Recently, the inverse-electron-demand Diels–Alder reaction between methylcyclopropene tags and tetrazines has become a popular ...
Anne-Katrin Späte   +5 more
doaj   +1 more source

One‐Pot Transition‐Metal‐Free Methods for the Synthesis of All Three Bonds of the Alkyne's Triple Bond

open access: yesChemistry – A European Journal, EarlyView.
One‐pot transition‐metal‐free methods for the synthesis of all three bonds of the alkyne's triple bond are reviewed. After analysis of several named reactions and discussion of improvements, recent advances in the synthesis of alkynes are discussed. Each section contains a proposed reaction mechanism and analysis of the strengths and weaknesses of the ...
Eugene Kim   +4 more
wiley   +1 more source

The synthesis, characterization and thermal chemistry of modified norbornenyl PMR endcaps [PDF]

open access: yes, 1985
As part of a program to further the understanding of the polymerization of Nadic-Endcapped PMR systems, a series of model Norbornenyl-Imides has been synthesized and their thermal behavior explored.
Malhotra, V.   +3 more
core   +1 more source

Dynamic Covalent Chemistry Enables Self‐Healing and Compatibilization in Polypropylene Composites

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A high‐performance polypropylene insulation material is created through dynamic covalent crosslinking. It achieves exceptional dielectric properties, autonomous self‐healing, and easy recycling, offering a sustainable solution for future HVDC transmission systems.
Hongzhe Zhang   +3 more
wiley   +1 more source

Diels-Alder reaction between indoles and cyclohexadienes photocatalyzed by a (thia)pyrylium salt [PDF]

open access: yes, 2007
"Thiapyrylium salt 1 is an efficient photocatalyst in the Diels-Alder reaction between indoles (InHs) and 1,3-cyclohexadienes (CHDs). For instance, irradiation of deaerated dichloromethane solutions containing 1 (1 mM), indole (20 mM) and cyclohexadiene (
González Béjar, María   +2 more
core  

Ring Formation in Sesquiterpene Synthesis: Biomimetic vs. Non‐Biomimetic Strategies

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A short review of cyclase enzyme‐mediated ring formation in sesquiterpene biosynthesis is presented as a prelude to six case studies examining the merits and demerits of biomimetic vs. non‐biomimetic strategies for carbocyclisation in the total synthesis of this iconic natural product class.
Bohan Lin, Chen Dai, Alan C. Spivey
wiley   +1 more source

Ladder polymers for use as high temperature stable resins or coatings [PDF]

open access: yes, 1990
An object of the invention is to synthesize a new class of ladder and partial ladder polymers. In accordance with the invention, the new class of ladder and partial ladder polymers are synthesized by polymerizing a bis-dienophile with a bis-diene ...
Meador, Mary Ann
core   +1 more source

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