Results 141 to 150 of about 7,607,880 (287)

Conjugated Polymers Engineered for Flexible/Stretchable Electronics

Journal of Polymer Science, EarlyView.
This review highlights glass transition temperature (Tg) as the central parameter linking molecular structure to device performance in conjugated polymers. By tuning backbone rigidity, side‐chain architecture, and dynamic bonding, Tg governs the balance between π–π stacking–enabled charge transport and mechanical compliance.
Yunchong Yang, Josh Bass, Weijia Yan, Ashwath Anand, Chunka Zhou, Jingjing Qiu   +5 more
wiley   +1 more source

Design and synthesis of responsive glycopolymers for biomedical and environmental applications

Responsive Materials, EarlyView.
This review highlighted recent advances in the synthetic methodology of polymerization and post‐polymerization modification, which enable precise structural control and broaden the applications of responsive glycopolymers in biomedical and environmental fields. Abstract Glycopolymers are a unique class of synthetic polymers bearing pendant carbohydrate
Arpita Samal, Shubhi Dwivedi, Mahesh Peddigari, Abhijit Sau   +3 more
wiley   +1 more source

Preserving Hierarchical Integrity During Primary Structure Modification of Spherulitic MOFs

Small, EarlyView.
A MOF‐74‐type zinc framework self‐organizes into well‐defined spherulitic superstructures while allowing precise covalent post‐synthetic modification (PSM) of the linkers. A built‐in tetrazine enables fast inverse electron‐demand Diels–Alder (iEDDA) functionalization to uniformly install primary amines.
Gabriela Kowacz, Damian Jędrzejowski, Dariusz Matoga   +2 more
wiley   +1 more source

Direct Growth of BODIPY‐Based Conjugated Porous Polymer Shell on Upconversion Nanoparticles for NIR‐Driven Photocatalysis

Small, EarlyView.
Monomer prefunctionalization of upconversion nanoparticles directs uniform growth of BODIPY‐based conjugated porous polymers shells, affording precise control over polymer loading and optimized NIR‐triggered photocatalytic activity. ABSTRACT The great applications of upconversion nanoparticles (UCNPs) can be further extended by their encapsulation ...
Teresa Naranjo, Laura Francés‐Soriano, Delia Bellezza, Julia Pérez‐Prieto, Víctor A. de la Peña O´Shea, Marta Liras, María González‐Béjar   +6 more
wiley   +1 more source

Role of 1D and 2D Materials in Achieving Transparent and Flexible Lithium‐Ion Batteries for Wearable Electronics

Small, EarlyView.
Hybrid 1D–2D architectures redefine material design strategies for TFLIBs by decoupling competing performance parameters. This approach accelerates the transition of TFLIBs from proof of concept to practical wearable technologies. ABSTRACT Transparent and flexible lithium‐ion batteries (TFLIBs), enabled by advanced nanomaterials and flexible ...
Raviraj Madesan, Anand Sreekantan Thampy
wiley   +1 more source

The Oxidative Gassman-Type Diels-Alder Reaction. [PDF]

Org Lett
Geaneotes PJ, Floreancig PE.
europepmc   +1 more source

Enhanced through‐bond energy transfer‐based bioorthogonal probe enables catalytic‐amplified and sensitive detection of microRNA‐21 for clinical lung cancer diagnosis

Smart Molecules, EarlyView.
Inverse Diels‐Alder Cycloaddition Reaction was developed for ultrasensitive miR‐21 detection. Based on the enhanced Through‐Bond Energy Transfer and catalytic amplification, it shows a detection limit of 3.58 × 10−18 M and 100 aM–100 nM linear range. It enables high‐contrast cell/tissue imaging and distinguishes lung cancer patients in serum, promising
Yikun Li, Fuping Han, Haiqiao Huang, Danhong Zhou, Saran Long, Wen Sun, Jianjun Du, Jiangli Fan, Jing Ning, Chong Peng, Xiaojun Peng   +10 more
wiley   +1 more source

On the Role of Hydrogen Bond Strength and Charge Transfer in an On-Water Diels-Alder Reaction: Semiempirical and Free Energy Calculations. [PDF]

J Comput Chem
Henao A, Gohar Y, Wilhelm R, Kühne TD.
europepmc   +1 more source

The Diels-Alder reaction : doomed to academic praise only?

, 2018
The Diels-Alder reaction is universally acknowledged for its atom-efficient and simple access to molecular complexity. This textbook example of a green reaction forms one of the most efficient routes towards six-membered rings.
Stevens, Christian, Seghers, Sofie, Thybaut, Joris   +2 more
core  

Five Decades of Dispute: A Triptych. E. J. Corey

The Chemical Record, EarlyView.
In his 2004 Priestley Medal address, E. J. Corey stated, “On May 4, 1964, I suggested to my colleague R. B. Woodward a simple explanation involving the symmetry of the perturbed (HOMO) molecular orbitals for the stereoselective cyclobutene/1,3‐butadiene and 1,3,5‐hexatriene/cyclohexadiene conversions that provided the basis for the further development ...
Jeffrey I. Seeman
wiley   +1 more source