Results 151 to 160 of about 7,607,880 (287)

Five Decades of Dispute: A Triptych. Roald Hoffmann

open access: yesThe Chemical Record, EarlyView.
This article examines the historical Corey–Woodward controversy through Roald Hoffmann's personal perspective, completing a triptych on the prolonged dispute. Drawing on archival records, contemporaneous correspondence, and extensive interviews, it reconstructs Hoffmann's interactions with Corey and Woodward from the 1960s onward.
Jeffrey I. Seeman
wiley   +1 more source

Formal Diels-Alder reaction of saturated carboxylic acids via C-H activation. [PDF]

open access: yesNat Chem
He Q   +6 more
europepmc   +1 more source

Oxaziridines: Versatile Reagents in Modern Organic Synthesis

open access: yesThe Chemical Record, EarlyView.
Being capable of transferring an O atom and N‐group/atom, oxaziridines are considered multitasking agents. These are employed for diverse organic transformations, such as epoxidation of olefins, α‐ and γ‐hydroxylation/amination of carbonyl compounds, oxidation of sulfides, [3+2]cycloaddition with unsaturated systems.
Ajeet Chandra   +2 more
wiley   +1 more source

Metal‐Catalyzed Benzannulation: Recent Advances in Catalyst Design, Mechanistic Insights, and Aromatic Framework Construction

open access: yesThe Chemical Record, EarlyView.
This review offers a contemporary overview of metal‐catalyzed benzannulation (2018–present) encompassing transition, main‐group, post‐transition, and rare‐earth‐metal catalysts. It systematically highlights catalyst design, mechanistic insights, stereo‐ and regioselectivity, and synthetic applications toward aromatic and heteroaromatic scaffolds, while
Sana Jamshaid   +5 more
wiley   +1 more source

Four‐dimensional immuno‐mechanobiomaterials: Dynamic material cues that program host response to prevent fibrosis and enable regeneration

open access: yesVIEW, EarlyView.
Dynamic immuno‐mechanobiomaterials with time‐programmed mechanical adaptation orchestrate host responses through precise mechanotransduction and immune‐stromal regulation. These adaptive biomaterials minimize mechanical mismatch, attenuate the forign dy response and fibrosis, promote angiogenesis and controlled extracellular matrix remodeling, and ...
Gobinath Vellapalayam Manoharan   +4 more
wiley   +1 more source

The elusive <i>endo</i>-product of the archetypal Diels-Alder reaction of furan and maleic anhydride - observed in the solid state at last. [PDF]

open access: yesChem Sci
Lennox CB   +10 more
europepmc   +1 more source

Brief encounters and lasting impressions—How target protein half‐life affects reactive metabolite signaling

open access: yesThe FEBS Journal, EarlyView.
Lipid‐derived reactive electrophile molecules (REMs) are generated from fatty acids through lipoxygenase or cyclooxygenase‐assisted catalysis, or free radical‐induced lipid peroxidation events. REMs so‐produced covalently modify nearby protein‐cysteines, and in the case of ‘first responder’ proteins, can trigger gain‐of‐function signaling with context ...
Marcus J. C. Long   +2 more
wiley   +1 more source

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