A Comprehensive View on the Molecular Mechanism of the Diels-Alder Reaction Between 2,3-Dimethylbutadiene and E-2-Phenyl-1-Nitroethene: CDFT/ELF, <sup>14</sup>C Kinetic Isotope Effects, Electron Density Transfers, Reaction Profiles and BET Analyses. [PDF]
Woliński P, Łącka W, Jasiński R.
europepmc +1 more source
Self‐Immolative Poly(Benzyl Ether)s: Design Principles and Controlled Depolymerization
Unzipping to Sustainability: This Concept article explores the thermodynamic design of quinone‐methide (QM)‐based poly(benzyl ether)s (PBEs). It explains how a low ceiling temperature (Tc), QM stability, and an entropic gain drive rapid depolymerization (“unzipping”) of PBEs into monomers.
Ji Woo Kim, Yewon Kang, Hyungwoo Kim
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Systematic C-C Bond Cleavage in Oligomers via Diels-Alder Reaction on Au(111). [PDF]
Li D +7 more
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An on-surface Diels-Alder reaction. [PDF]
Castro-Esteban J +5 more
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Inverse-Electron-Demand Diels-Alder Reaction of Tropone with Graphene Supported on Cu(111). [PDF]
Tu J, Zhou W, Wolf LM, Yan M.
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Fibrillar Hydrogel Based on Cellulose Nanocrystals Crosslinked via Diels-Alder Reaction: Preparation and pH-Sensitive Release of Benzocaine. [PDF]
Morozova SM, Korzhikova-Vlakh EG.
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“Smelltronics”—From Gas to Smell Sensing
The emerging field of smelltronics, encompassing sensing technologies for complex volatile organic compounds, holds significant potential for extracting valuable chemical information. It facilitates the noninvasive, real‐time monitoring of humans, food, and the environment.
Takeshi Ono +7 more
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Pericyclic Umpolung in a Catalytic Asymmetric Diels-Alder Reaction of Tropone with Enol Ethers. [PDF]
Zheng T +6 more
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The Elements of Chiral Brønsted Acids for Stereoselective Transformations
This review focuses on chiral Brønsted acids (CBAs), examining how each structural component influences the stereochemical outcome. For each element—scaffold, acidic site, substituents—we identify advantages and disadvantages relevant to the catalyst design and selection.
Diego A. Cruz‐Aguilar +3 more
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Development of a Vinylated Cyclic Allene: A Fleeting Strained Diene for the Diels-Alder Reaction. [PDF]
Mizoguchi H +4 more
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