Dual-locked targeted alpha-emitter enhanced tumor immunotherapy via Diels-Alder reaction-based self-immolative molecular cage strategy. [PDF]
Yang MD +10 more
europepmc +1 more source
7-Deaza-2'-Deoxyxanthosine: Impact of Halogens and Vinyl Side Chains on Purine-Purine Base Pairs in Watson-Crick DNA, Functionalization by Bioorthogonal Inverse-Electron-Demand Diels-Alder Reaction, and Mismatch Discrimination. [PDF]
Chandankar S, Kondhare D, Leonard P.
europepmc +1 more source
M. beecheii propolis contains eleven identified PTs, including germanicone and glutinol, reported for the first time in this material. Antioxidant assays reveal Fe(III)‐reducing activity at an effective concentrations lower than DPPH radical‐scavenging activity.
Aarón Santana‐Hernández +7 more
wiley +1 more source
Diversification of the Avarane Skeleton Toward Spiroetherone A
Molecular complexity and diversity were generated from the avarone skeleton, leading, among other transformations, to an oxaspiro[4.5]dienone via Wagner–Meerwein rearrangements, a popolohuanone E‐like dibenzofuran via a (3+2) dimerization, and a pentacyclic imidate via a tandem PIDA‐mediated alkene–phenol cyclization/Ritter reaction.
Guillaume Schoenn +3 more
wiley +1 more source
Dynamic Covalent Chemistry Enables Self‐Healing and Compatibilization in Polypropylene Composites
A high‐performance polypropylene insulation material is created through dynamic covalent crosslinking. It achieves exceptional dielectric properties, autonomous self‐healing, and easy recycling, offering a sustainable solution for future HVDC transmission systems.
Hongzhe Zhang +3 more
wiley +1 more source
Overcoming the Reversibility in the Diels-Alder Reaction of Bio-Based Electron-Poor Furans with Maleimides Through Liquid-to-Solid Phase Transition. [PDF]
Galkin KI +7 more
europepmc +1 more source
Layered π Systems Based on Ferrocenophanes
Syntheses of a variety of ferrocenophanes and extensions of their π systems are reported. These are performed by Knoevenagel reactions and predominantly lead to syn diastereomers. Eight ferrocenophanes were crystallographically characterized. [1.1]Ferrocenophane was prepared by the literature method along with a small amount of [1.1.1.1]ferrocenophane,
Wing‐Yin Tsang, Holger Butenschön
wiley +1 more source
The Scholl reaction of 1,3,6,8‐tetrakis(oligophenyl)‐appended carbazoles afforded stable NH‐containing helical nanographenes, which showed significant redshift and reversible on/off switching of CPL upon the addition of base and acid, respectively. Furthermore, excited‐state proton transfer occurred in dimethyl sulfoxide to generate anionic species ...
Chihiro Maeda +7 more
wiley +2 more sources
Utilizing the Pentadehydro-Diels-Alder Reaction for Polycyclic Aromatic Compound Synthesis: Diels-Alder-Based Linker Transformation. [PDF]
Xia Y, Liang Q, Zhu C, Sun B.
europepmc +1 more source
Catechol‐based annulated aromatics with carbonyl units are ideal ligands for the formation of titanium(IV) containing lithium‐bridged hierarchical helicates. They allow for the first time the use of amide units to obtain the dimeric helicate‐type complexes.
Steffen Schauerte +4 more
wiley +1 more source

