Results 201 to 210 of about 7,607,880 (287)

Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles

European Journal of Organic Chemistry, Volume 29, Issue 40, 27 October 2026.
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu, Mauro Uras, Angelo Frongia   +2 more
wiley   +1 more source

Emergent Atropisomerism Through Diels–Alder Reactions of Vinylallenes

European Journal of Organic Chemistry, Volume 29, Issue 40, 27 October 2026.
Cycloaddition‐induced geometric reorganization transforms achiral vinylallenes into atropisomeric styrenes. Conformational flexibility governs atropisomerization barriers, thermodynamic preferences, and configurational stability. Atropisomeric styrenes remain comparatively underdeveloped because configurational stability about the C(sp2)C(sp2) bond is
Kusum Sai, Asja A. Kroeger, Michelle L. Coote, Michael S. Sherburn   +3 more
wiley   +1 more source

7-Deaza-2'-Deoxyxanthosine: Impact of Halogens and Vinyl Side Chains on Purine-Purine Base Pairs in Watson-Crick DNA, Functionalization by Bioorthogonal Inverse-Electron-Demand Diels-Alder Reaction, and Mismatch Discrimination. [PDF]

Chemistry
Chandankar S, Kondhare D, Leonard P.
europepmc   +1 more source

Biomimetic Total Synthesis and Paired Omics Identify an Intermolecular Diels-Alder Reaction as the Key Step in Lugdunomycin Biosynthesis. [PDF]

J Am Chem Soc
Uiterweerd MT, Nuñez Santiago I, Cunha AV, Havenith RWA, Du C, Zhang L, van der Heul HU, Elsayed SS, Minnaard AJ, van Wezel GP.   +9 more
europepmc   +1 more source

Utilizing the Pentadehydro-Diels-Alder Reaction for Polycyclic Aromatic Compound Synthesis: Diels-Alder-Based Linker Transformation. [PDF]

Molecules
Xia Y, Liang Q, Zhu C, Sun B.
europepmc   +1 more source

Cyclopropylamine‐Derived Distonic Iminium Radicals: Photoinduced Strategies in Chemo‐ and Stereo‐Selective Synthesis

Chemistry – A European Journal, Volume 32, Issue 39, 22 October 2026.
Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua, Alberto Luridiana, Francesco Secci, Emanuele Cocco   +3 more
wiley   +1 more source

Overcoming the Reversibility in the Diels-Alder Reaction of Bio-Based Electron-Poor Furans with Maleimides Through Liquid-to-Solid Phase Transition. [PDF]

Int J Mol Sci
Galkin KI, Zakharova DV, Aysin RR, Danshina AA, Pak AM, Sandulenko IV, Novikov RA, Egorova KS.   +7 more
europepmc   +1 more source

Mechanistic Insights Into Sustainable Catalytic Pyrolysis of Biomass‐Derived Ferulic Acid: The Role of Alumina Regeneration

Chemistry – A European Journal, Volume 32, Issue 39, 22 October 2026.
Surface‐bound ferulate phenolate complexes undergo styrene‐like polymerization on alumina, yielding a polymeric carbonaceous layer that progressively transforms into polyaromatic carbon domains with concomitant release of aromatic products, while parallel surface‐assisted decarboxylation produces 4‐vinylguaiacol. ABSTRACT A fundamental understanding of
Tetiana V. Kulik, Borys B. Palianytsia, Mykola M. Ilchenko, Nataliia S. Nastasiienko, David J. Morgan, Liudmila P. Storozhuk, David J. Willock, Greg Shaw, Duncan F. Wass, Rafael Luque, Philip R. Davies, Mykola T. Kartel   +11 more
wiley   +1 more source

Chelation‐Assisted Metal‐Catalyzed Ligation and Cleavage Reactions for Chemical Biology

European Journal of Organic Chemistry, Volume 29, Issue 39, 22 October 2026.
Chelation‐assisted transition metal catalysis has emerged as a promising complement to bioorthogonal click chemistry for studying biological processes. By pre‐organizing catalytic metal centers, designed coordinating substrates enhance reactivity and biocompatibility, enabling site‐selective ligation and decaging reactions in complex biological media ...
Emilie Plantiveau, Maxime Riberaud, Frédéric Taran, Antoine Sallustrau   +3 more
wiley   +1 more source

Layer-by-layer assembled film can serve as an enhanced reaction environment for Diels-Alder reaction. [PDF]

Front Chem
Fujisawa N, Ebara M.
europepmc   +1 more source