Results 121 to 130 of about 77,395 (287)

Investigation of domino Knoevenagel-intramolecular Diels Alder reactions with vinyl furan derivatives

open access: yes
Kutatómunkám célkitűzése dominó Knoevenagel-Diels-Alder gyűrűzárási szekvenciák végrehajtása volt vinil-furán alegységet tartalmazó szubsztrátokon, melynek során vizsgáltuk a furán alegység és a reagens reakciómechanizmusra és sztereoszelektivitásra ...
Oláh, Dávid
core  

Time-resolved and static NMR characterization of the structure and folding kinetics of the Diels-Alder ribozyme [PDF]

open access: yes, 2009
Despite the well-known importance of ribonucleic acids (RNA) in cell biology, it is astounding to realize the pace at which new fundamental functions of RNAs have been discovered.
Manoharan, Vijayalaxmi
core  

Well‐Defined Nickel Precatalysts: Form, Function, and Application

open access: yesChemistry – A European Journal, EarlyView.
This review provides guidance on which nickel precatalysts to choose for a given application or which properties to prioritize in reaction development. A summary of the ease of synthesis, stability, diversity, accessibility, modularity, and general applicability is provided along with a related infographic.
Morgan E. John   +3 more
wiley   +1 more source

Partially Biobased Polyurethanes With Reversibly Crosslinkable Furan Units Toward Recyclable Thermosetting Textile Fibres

open access: yesChemistry – A European Journal, EarlyView.
A molecular design strategy combines lignin‐derived aromatic units, sugar‐derived furan groups, and flexible glycol segments to create wet‐spinnable polyurethanes. Thermally reversible Diels–Alder crosslinking chemistry enables formation of crosslinked thermosetting fibers, repeated de‐crosslinking/re‐crosslinking cycles, and tunable fiber properties ...
Rafael N. L. Menezes   +7 more
wiley   +1 more source

La superficie SI(100)-2x1 como dienófilo en una reacción tipo DIELS-ALDER

open access: yesRevista de Química, 1999
Se estudió la adsorción de 1,3-butadieno y de 2,3-dimetil-1,3-butadieno sobre una superficie monocristalina de Si(100)-2x1 bajo condiciones de máximo vacío (ultra-high vacuum, UHV) observándose que, a temperatura ambiente, cada dieno reacciona mediante ...
Maynard Kong Moreno   +2 more
doaj  

Reactivity of substituted 4-Pyridones in normal and inverse demand Diels-Alder cycloaddition [PDF]

open access: yes, 2009
The synthesis of the decahydroquinoline ring system has been explored extensively due to its appearance within many biologically active natural alkaloids. New compounds containing such a moiety are being discovered on an ongoing basis.
NC DOCKS at The University of North Carolina Wilmington   +1 more
core  

Diels-Alder reactions in synthesis and method development: Development of a synthetic pathway to decalin terpenoids and evaluation of phosphordiamides as Diels-Alder catalysts

open access: yes, 2018
This thesis has got two parts within the common theme of Diels-Alder reactions. One part starts with the group of natural products called asmarines. These compounds, which were found in the red sea sponges, were believed to have anti-cancer properties ...
Wåhlander, Jakob
core   +1 more source

Self‐Immolative Poly(Benzyl Ether)s: Design Principles and Controlled Depolymerization

open access: yesChemistry – A European Journal, EarlyView.
Unzipping to Sustainability: This Concept article explores the thermodynamic design of quinone‐methide (QM)‐based poly(benzyl ether)s (PBEs). It explains how a low ceiling temperature (Tc), QM stability, and an entropic gain drive rapid depolymerization (“unzipping”) of PBEs into monomers.
Ji Woo Kim, Yewon Kang, Hyungwoo Kim
wiley   +1 more source

New tandem Ugi/intramolecular Diels–Alder reaction based on vinylfuran and 1,3-butadienylfuran derivatives

open access: yesBeilstein Journal of Organic Chemistry
A new tandem sequence involving the Ugi reaction and Diels–Alder [4 + 2] cycloaddition based on vinylfuran and 1,3-butadienylfuran derivatives was designed and studied.
Yuriy I. Horak   +5 more
doaj   +1 more source

Diels–Alder Versus Michael Adducts of 2‐Methylfuran and Maleate: Consecutive Synthetic Access to Both Product Types

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
More than a century after Albrecht's original proposal, an unexpected synthetic relationship between the historically misassigned Michael adduct type and the genuine Diels–Alder product is revealed. Experimental and theoretical studies show that the Michael adduct is not formed directly from the diene and dienophile, but instead arises through ...
Johanna Buddeberg   +3 more
wiley   +1 more source

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