Results 61 to 70 of about 77,395 (287)

3D Printing of Self‐Healing Polymers by Material Extrusion: A Process‐Centric Review of Setups, Parameters, and Applications

open access: yesAdvanced Robotics Research, EarlyView.
This review highlights recent advances in material extrusion 3D printing of self‐healing polymers, focusing on the interplay between material chemistry, rheology, hardware customization, and process optimization. Filament‐ and ink‐based extrusion strategies, multimaterial architectures, and postprocessing approaches are discussed for applications in ...
Antonio Pavone   +2 more
wiley   +1 more source

Heat‐ and Light‐Directed Cycloadditions Enable a Pericyclic Cascade Reaction From a Molecular Precursor

open access: yesAngewandte Chemie, EarlyView.
A multi‐stimuli‐responsive material is designed that responds to light, heat, and mechanical force through distinct chemical reaction pathways. The pathway is directed by self‐assembly and the applied stimulus. A novel pericyclic reaction cascade is also achieved, and the mechanism is supported through density functional theory calculations.
Liulei Ma   +4 more
wiley   +2 more sources

Studies of novel diazanaphthoquinones and ion-responsive fluorescent quinoxaline derivatives [PDF]

open access: yes, 1994
This thesis was submitted for the degree of Doctor of Philosophy and awarded by Brunel University.The work reported is divided into two parts: fIrstly a section dealing with the preparation of some novel diazanaphthoquinones and their reactions ...
Ahmad, Abid Rafiq
core   +5 more sources

Diels–Alder Cycloaddition Reactions in Sustainable Media

open access: yesMolecules, 2022
Diels–Alder cycloaddition reaction is one of the most powerful strategies for the construction of six-membered carbocyclic and heterocyclic systems, in most cases with high regio- and stereoselectivity.
Maria I. L. Soares   +2 more
doaj   +1 more source

A Universal Protein Ladder for Standardization of Diverse FRET Assays

open access: yesAdvanced Science, EarlyView.
Translating FRET measurements from in vitro to intracellular environments requires universal benchmarks. We present a modular protein ladder using TPR motifs to harmonize data across diverse platforms. This predictable calibration curve bridges single molecule FRET measurements, with cell based measurements including FLIM‐FRET.
Evelyn R. Smith   +5 more
wiley   +1 more source

Farnesyltransferase Enables Modular Assembly of Dual‐Functional Nanobody Conjugates for in Vivo Imaging of Inflammation

open access: yesAngewandte Chemie, EarlyView.
A modular farnesyltransferase‐based chemoenzymatic platform enables fast, site‐specific labeling of nanobodies for PET imaging of inflammation. CD11b‐targeted PET agents selectively image myeloid‐driven inflammation, while CD45‐targeted PET agents provide sensitive whole‐body immune mapping.
Sneha Venkatachalapathy   +7 more
wiley   +2 more sources

Growth of Fullerene Fragments Using the Diels-Alder Cycloaddition Reaction: First Step towards a C60 Synthesis by Dimerization

open access: yesMolecules, 2013
Density Functional Theory has been used to model the Diels-Alder reactions of the fullerene fragments triindenetriphenilene and pentacyclopentacorannulene with ethylene and 1,3-butadiene.
Julio A. Alonso   +2 more
doaj   +1 more source

Self-Healing and High Interfacial Strength in Multi-Material Soft Pneumatic Robots via Reversible Diels–Alder Bonds

open access: yesActuators, 2020
In new-generation soft robots, the actuation performance can be increased by using multiple materials in the actuator designs. However, the lifetime of these actuators is often limited due to failure that occurs at the weak multi-material interfaces that
Seppe Terryn   +4 more
doaj   +1 more source

Aza-Diels-Alder reaction of both electron-deficient azoalkenes with electron-deficient 3-phencaylideneoxindoles and 3-aryliminooxindol-2-ones

open access: yesGreen Synthesis and Catalysis, 2021
An uncommon aza-Diels-Alder reaction of electron-deficient azoalkenes and electron-deficient 3-phenacylideneoxindoles was successfully developed for convenient construction of the heterocyclic spirooxindoles.
Wenjing Shi, Jing Sun, Chao-Guo Yan
doaj   +1 more source

Electrochemically Driven Regioselective Radical Functionalization of Allenes: Scope and Mechanistic Insights

open access: yesAdvanced Science, EarlyView.
Allenes emerge as powerful platforms for electrochemical functionalization through radical pathways. Selective radical addition at the central carbon triggers anodic oxidation and intramolecular cyclization, enabling efficient synthesis of oxazolines and oxazolidine‐2‐imines without external oxidants.
Pranjal Pyne   +5 more
wiley   +1 more source

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