Results 121 to 130 of about 27,574 (257)
Benzochromanone and Benzochromene Natural Products: Synthetic Strategies and Total Syntheses
This work outlines synthetic strategies for natural products with benzochromanone and benzochromene cores. Key achievements include total syntheses of xanthones, blennolide C, gonytolide C, and teretifolione B. Spirochromanone intermediates, benzyne–furan Diels–Alder reactions, and enzymatic resolution enabled efficient and enantioselective access to ...
Takuya Kumamoto
wiley +1 more source
Computational insights into the Multi-Diels-Alder reactions of neutral C60 and its Li+ encapsulated analogue: A DFT study [PDF]
Tamalika Ash +3 more
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ABSTRACT Rationale Flavonoids are phenolic compounds with many health‐benefiting properties. However, differentiating different types of flavonoids and their isomers is challenging due to their highly similar structures of various subtypes and different numbers and sites of substituents.
Yanqiu Wang +4 more
wiley +1 more source
How Alkali Cations Catalyze Aromatic Diels‐Alder Reactions [PDF]
Pascal Vermeeren +3 more
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This study focused on Artemisia selengensis leaves (ASL), a discarded agricultural waste. 72 compounds were identified by UPLC‐Q‐TOF‐MS. “Green” extraction with DES was optimized, and ASL's XO—inhibition was explored, presenting new ways for waste utilization. ABSTRACT Artemisia selengensis is a medicinal and edible plant, whose tender stems are widely
Lixia Li +8 more
wiley +1 more source
A series of frustrated Lewis pair (FLP) stabilized arsenic compounds with formal oxidation numbers at As of +1, 0, and −1 are presented. A stable FLP‐chelated complex of As2 was prepared which undergoes the light‐induced release of nascent diarsenic, As2nasc, which reveals clean triple‐bond type reactivity with dienes and metal‐metal bonds under mild ...
Ludwig Zapf +3 more
wiley +2 more sources
π-Facial selectivity in the Diels-Alder reactions of the 1,3-cyclohexadienes bearing allylic oxygen substitution [PDF]
James Gillard
openalex
Diels–Alder reactions and electrophilic substitutions with atypical regioselectivity enable functionalization of terminal rings of anthracene [PDF]
Vinh Ngoc Huynh +7 more
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Thiophene Derivatives as Versatile Precursors for (Hetero)Arene and Natural Product Synthesis
Hidden but Powerful: Thiophenes and their saturated analogues have been demonstrated to be versatile C4‐building blocks that can be rapidly applied to natural product synthesis and the construction of functionalized (hetero)arenes. This minireview aims to provide a concise overview of the strategies and implementations of these sulfur‐containing ...
Anna Keimer, Franz‐Lucas Haut
wiley +1 more source

