Alkoxyallenes in Modern Synthesis: Reactivity, Catalysis, and Complexity Generation
The last decade has witnessed a remarkable transformation in alkoxyallene chemistry. Although historically employed as synthetic equivalents of acrolein or as versatile 3C synthons, alkoxyallenes are now increasingly recognized as highly adaptable platforms for synthetic design.
A. Lanfranco +5 more
wiley +1 more source
Real-Time Visualisation of Reaction Kinetics and Dynamics: Single-Molecule Insights into the Iminium-Catalysed Diels-Alder Reaction. [PDF]
Park M +7 more
europepmc +1 more source
Surface and Interfacial Engineering toward Durable Mechanically Coupled Flexible Electronics
This Review highlights how surface and interfacial engineering governs the reliability, durability, and functional stability of mechanically coupled flexible electronics. By integrating fundamental interfacial theory, failure mechanisms, multiscale engineering strategies, and representative applications, it provides a design‐oriented framework for ...
Qian Wang, Fangfang Dai, Wei Wu
wiley +1 more source
Chiral Morphing of Liquid Crystal Polymer Networks
This paper reviews how macroscopic chirality spontaneously arises from liquid crystal polymer materials. It describes how alignment is utilized to create the mechanical anisotropy, geometric misorientation and asymmetry that leads to chiral shape morphing, how shape selection between helicoids and helices arises, the techniques used to prepare these ...
Laurens T. de Haan
wiley +1 more source
Synthesis of benzoquinone compounds by a microdroplet-accelerated retro-Diels-Alder reaction. [PDF]
Malkoti N, Meng Y, Zare RN, Gnanamani E.
europepmc +1 more source
Dual-locked targeted alpha-emitter enhanced tumor immunotherapy via Diels-Alder reaction-based self-immolative molecular cage strategy. [PDF]
Yang MD +10 more
europepmc +1 more source
7-Deaza-2'-Deoxyxanthosine: Impact of Halogens and Vinyl Side Chains on Purine-Purine Base Pairs in Watson-Crick DNA, Functionalization by Bioorthogonal Inverse-Electron-Demand Diels-Alder Reaction, and Mismatch Discrimination. [PDF]
Chandankar S, Kondhare D, Leonard P.
europepmc +1 more source
M. beecheii propolis contains eleven identified PTs, including germanicone and glutinol, reported for the first time in this material. Antioxidant assays reveal Fe(III)‐reducing activity at an effective concentrations lower than DPPH radical‐scavenging activity.
Aarón Santana‐Hernández +7 more
wiley +1 more source
Diversification of the Avarane Skeleton Toward Spiroetherone A
Molecular complexity and diversity were generated from the avarone skeleton, leading, among other transformations, to an oxaspiro[4.5]dienone via Wagner–Meerwein rearrangements, a popolohuanone E‐like dibenzofuran via a (3+2) dimerization, and a pentacyclic imidate via a tandem PIDA‐mediated alkene–phenol cyclization/Ritter reaction.
Guillaume Schoenn +3 more
wiley +1 more source

