Hydrazone‐Type Ligands for Asymmetric Catalysis
The introduction of trans 2,5‐disubstituted pyrrolidines is the key design element enabling the excellent stereocontrol exerted by hydrazone‐based N‐ligands in a variety of transition metal‐catalyzed transformations, including Diels–Alder cycloadditions, Suzuki/Hiyama/Negishi cross‐couplings, 1,2‐additions to a variety of imines and hydrazones, and ...
Esteban Matador +4 more
wiley +1 more source
Overcoming the Reversibility in the Diels-Alder Reaction of Bio-Based Electron-Poor Furans with Maleimides Through Liquid-to-Solid Phase Transition. [PDF]
Galkin KI +7 more
europepmc +1 more source
Dynamic Covalent Chemistry Enables Self‐Healing and Compatibilization in Polypropylene Composites
A high‐performance polypropylene insulation material is created through dynamic covalent crosslinking. It achieves exceptional dielectric properties, autonomous self‐healing, and easy recycling, offering a sustainable solution for future HVDC transmission systems.
Hongzhe Zhang +3 more
wiley +1 more source
Utilizing the Pentadehydro-Diels-Alder Reaction for Polycyclic Aromatic Compound Synthesis: Diels-Alder-Based Linker Transformation. [PDF]
Xia Y, Liang Q, Zhu C, Sun B.
europepmc +1 more source
Layered π Systems Based on Ferrocenophanes
Syntheses of a variety of ferrocenophanes and extensions of their π systems are reported. These are performed by Knoevenagel reactions and predominantly lead to syn diastereomers. Eight ferrocenophanes were crystallographically characterized. [1.1]Ferrocenophane was prepared by the literature method along with a small amount of [1.1.1.1]ferrocenophane,
Wing‐Yin Tsang, Holger Butenschön
wiley +1 more source
The Scholl reaction of 1,3,6,8‐tetrakis(oligophenyl)‐appended carbazoles afforded stable NH‐containing helical nanographenes, which showed significant redshift and reversible on/off switching of CPL upon the addition of base and acid, respectively. Furthermore, excited‐state proton transfer occurred in dimethyl sulfoxide to generate anionic species ...
Chihiro Maeda +7 more
wiley +2 more sources
Computational Investigation of a CO<sub>2</sub> Conversion Strategy via Diels-Alder Reaction in a Carbon Capture Solvent. [PDF]
Zhang D +6 more
europepmc +1 more source
Catechol‐based annulated aromatics with carbonyl units are ideal ligands for the formation of titanium(IV) containing lithium‐bridged hierarchical helicates. They allow for the first time the use of amide units to obtain the dimeric helicate‐type complexes.
Steffen Schauerte +4 more
wiley +1 more source
Recent advancements in the chemistry of Diels-Alder reaction for total synthesis of natural products: a comprehensive review (2020-2023). [PDF]
Rana A, Mishra A, Awasthi SK.
europepmc +1 more source
Graphical abstract depicting intracellular uptake of nanoparticles, near‐infrared light exposure, release of miRNA from nanoparticles, and proposed mechanistic action via the RNA induced silencing complex. ABSTRACT Current treatment modalities for head and neck cancer often leave patients with severe morbidities including difficulty swallowing ...
Angelica M. Helton +6 more
wiley +1 more source

