Direct arylation catalysis with chloro[8-(dimesitylboryl)quinoline-κN]copper(I) [PDF]
Beilstein Journal of Organic Chemistry, 2016 We report direct arylation of arylhalides with unactivated sp2 C–H bonds in benzene and naphthalene using a copper(I) catalyst featuring an ambiphilic ligand, (quinolin-8-yl)dimesitylborane.
Sem Raj Tamang, James D. Hoefelmeyer
doaj +2 more sources
Novel Diketopyrrolopyrrole-Based π-Conjugated Molecules Synthesized Via One-Pot Direct Arylation Reaction [PDF]
Molecules, 2019 Diketopyrrolopyrrole (DPP) is an important type of π-conjugated building block for high-performance organic electronic materials. DPP-based conjugated materials are usually synthesized via Suzuki, Stille, or Negishi cross-coupling reactions, which ...
Hui Liu +5 more
doaj +2 more sources
Synthesis of a 1,2-Dithienylethene-Containing Donor-Acceptor Polymer via Palladium-Catalyzed Direct Arylation Polymerization (DArP) [PDF]
Molecules, 2018 This paper reports the synthesis of D-A polymers containing 1,2-dithienylethene (DTE) units via palladium-catalyzed direct arylation polymerization (DArP).
Masayuki Wakioka +4 more
doaj +2 more sources
Palladium-catalyzed direct arylation and cyclization of o-iodobiaryls to a library of tetraphenylenes. [PDF]
Sci Rep, 2016 Aryl–aryl bond formation constitutes one of the most important subjects in organic synthesis. The recent developments in direct arylation reactions forming aryl–aryl bond have emerged as very attractive alternatives to traditional cross-coupling ...
Zhu C, Zhao Y, Wang D, Sun WY, Shi Z.
europepmc +2 more sources
N-Benzoyl dithieno[3,2-b:2′,3′-d]pyrrole-based hyperbranched polymers by direct arylation polymerization [PDF]
Chemistry Central Journal, 2017 Background Although poly(N-acyl dithieno[3,2-b:2′,3′-d]pyrrole)s have attracted great attention as a new class of conducting polymers with highly stabilized energy levels, hyperbranched polymers based on this monomer type have not yet been studied. Thus,
Tam Huu Nguyen +6 more
doaj +2 more sources
Palladium single-atom/cluster cocatalyst supported on non-enzymatic browning glucose breaks the activity-selectivity trade-off in C(sp3)-H arylation [PDF]
Communications ChemistryUsing Pd homogeneous catalysts for direct C–H arylation is an attractive approach for synthesizing natural products and organic functional materials, but limitations in terms of cost and catalyst recovery could be alleviated by alternative heterogeneous ...
Xiaojie He +6 more
doaj +2 more sources
Palladium-Catalyzed C2-Selective Direct Arylation of Benzo[b]thiophene 1,1-Dioxides with Arylboronic Acids [PDF]
ACS Omega, 2023 Xinwei Zhang +5 more
doaj +2 more sources
Direct Arylation of 1,10-Phenanthroline Using an Organomagnesium Reagent [PDF]
ACS OmegaNathanael A. Hirscher +4 more
doaj +2 more sources
Gold-Catalyzed Direct Arylation [PDF]
Science, 2012 Gently Coupled Linked aryl rings are found in a broad range of commercial chemical products. Currently, the most versatile synthetic route to this motif involves cross-coupling of one ring with a halide substituent to another ring with a boron or metal-based substituent. Recent research has focused on eliminating the need for one
Ball, Liam T +2 more
openaire +3 more sources
Direct arylation reaction of heteroarenes mediated by photoinduced electron transfer
Journal of Photochemistry and Photobiology, 2023 Electron donor–acceptor (EDA) complexes are interesting chemical species that function as molecular complexes. In this context, chemists have actively studies the use of halogen bonding as a noncovalent interaction in photochemistry.
Eiji Yamaguchi, Oe Karin, Akichika Itoh
doaj +1 more source