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Dithiocarbamate-Capped Silver Nanoparticles
The Journal of Physical Chemistry B, 2006Nanometer-sized silver particles were synthesized by using didecylamine dithiocarbamates as the protecting ligands. With control of the initial ligand-metal feed ratios, the core diameter of the resulting particles was found to vary from about 5 to 2.5 nm, as determined by transmission electron microscopic measurements.
Moony C, Tong +4 more
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Antiradiation Compounds. II. Dithiocarbamates
Journal of Medicinal and Pharmaceutical Chemistry, 1962Substituted dithiocarbamic acid derivatives, some of which contain metal- chelating functions additional to the dithiocarbamyl group, were synthesized as potential protective agents against ionizing radiation. It appeared that the additional nitrogen-containing chelating function contributed nothing to the radioprotective ability of dithiocarbamates ...
W O, FOYE, J, MICKLES
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The preparation of tin(II) dithiocarbamates from ammonium dithiocarbamate salts
Inorganica Chimica Acta, 1975Abstract Ammonium dithiocarbamate salts, which can be formed directly from carbon disulfide and the appropriate dialkylamine, serviced as convenient precursors for tin(II)DTC complexes. The compounds Sn[S2CNR2]2, (R = CH3 and C2H5) were prepared in this manner and characterized by their ir, nmr, ESCA, and mass spectra as well as by thermogravimetric
Dale Perry, R.A. Geanangle
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Dithiocarbamate therapy for nickel dermatitis
Contact Dermatitis, 1978Increased internal exposure to nickel can cause an exacerbation of nickel contact dermatitis. Nickel ions are chelated by diethyldithiocarbamate (DDC) and thereby inactivated. An oral dose of about 1 g DDC/day was given to a patient. The nickel excretion in the urine increased about tenfold; the nickel elimination in scalp hair did not increase.
D, Spruit, P J, Bongaarts, G J, de Jongh
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Studies on the stability of dithiocarbamic acids
Talanta, 1969The influence of the substituent on the nitrogen atom with respect to the rate and pattern of decomposition of N,N-disubstituted dithiocarbamie acids has been studied. The rates of decomposition with respect to such variables as pH, temperature (activation parameters) and heavy water medium (solvent isotope effect), have been determined, and a ...
K I, Aspila +2 more
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Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1969
The interaction of sodium dimethyldithiocarbamate with acetone solutions of chlorotris(triphenylphosphine)rhodium(I) and trans-chlorocarbonylbis(triphenylphosphine)rhodium(I) leads to the new complexes RhI(S2CNMe2)(PPh3)2, RhI(S2CNMe2)(CO)PPh3, RhIII(S2CNMe2)3(PPh3), and RhIII(S2CNMe2)3(CO)PPh3. I.r. and n.m.r. spectra of the last two complexes suggest
Charmian O'Connor +2 more
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The interaction of sodium dimethyldithiocarbamate with acetone solutions of chlorotris(triphenylphosphine)rhodium(I) and trans-chlorocarbonylbis(triphenylphosphine)rhodium(I) leads to the new complexes RhI(S2CNMe2)(PPh3)2, RhI(S2CNMe2)(CO)PPh3, RhIII(S2CNMe2)3(PPh3), and RhIII(S2CNMe2)3(CO)PPh3. I.r. and n.m.r. spectra of the last two complexes suggest
Charmian O'Connor +2 more
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Thin Layer Chromatography of Dithiocarbamate Fungicides
Bulletin of Environmental Contamination and Toxicology, 1966During the course of studies on the transformation of dithiocarbamate fungicides on leaf surfaces, it became necessary to develop a procedure which would distinguish the residue of the applied substance from its transformation products. Thin layer chromatography proved to be the most effective method for this separation and the following procedure was ...
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Current electroanalytical approaches in the carbamates and dithiocarbamates determination
Food Chemistry, 2023Djenaine De Souza
exaly
Dithiocarbamates. I. Quaternary Ammonium Dithiocarbamates
The Journal of Organic Chemistry, 1959K. C. KENNARD, D. M. BURNESS
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