Ring-Opening 1,3-Dichlorination of Donor–Acceptor Cyclopropanes by Iodobenzene Dichloride
Donor–acceptor cyclopropanes are reacted with iodobenzene dichloride to afford ring-opened products bearing chlorine atoms in the 1- and 3-positions, adjacent to the donor and acceptor groups.
Daniel B. Werz (1393828) +3 more
core +2 more sources
Emerging Trends in Organic Photoreactions Utilizing Disulfides
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar +3 more
wiley +1 more source
[3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides
A Sc(OTf)3-catalyzed reaction of vinyl azides with donor–acceptor cyclopropanes affords highly functionalized azidocyclopentanes in a diastereoselective fashion. The resulting azidocyclopentanes could be transformed into various cyclic scaffolds.MOE (Min.
Tamura, Sayako +9 more
core +1 more source
Cyclic Olefin Copolymers as Versatile Materials for Advanced Engineering Applications
Cyclic olefin copolymers (COCs) are presented as highly versatile materials combining tunable synthesis, excellent optical properties, and mechanical robustness. Their potential spans microfluidics, bioengineering, and advanced electronics, while emerging self‐healing and sustainable solutions highlight future opportunities.
Giulia Fredi +3 more
wiley +1 more source
Formal [3 + 2] Cycloadditions of Donor−Acceptor Cyclopropanes and Nitriles
Donor−acceptor cyclopropanes activated with Me3SiOTf cleave to reactive intermediates that can be efficiently intercepted by nitriles in a formal [3 + 2] dipolar cycloaddition reaction.
Ming Yu (78996) +1 more
core +2 more sources
Strain-Released Hydrogenation of Donor-Acceptor Cyclopropane and Cyclobutane via Electrochemical Site Selective Carbonyl Reduction [PDF]
Nakshatra Banerjee +3 more
openalex +1 more source
This review surveys the literature on light‐driven dearomative [2+2] cycloadditions of indoles, highlighting their power to access complex cyclobuta[b]indole frameworks. Advances in photocatalysis, sensitizer design, and reaction engineering enable selective and sustainable assembly of strained three‐dimensional architectures, expanding opportunities ...
Maria Chiara Cabua +4 more
wiley +1 more source
Recent Advances in Intramolecular C─N Bond Formation for Pyrrolidine Synthesis
This review highlights synthetic advances (2013–2025) in intramolecular C─N bond formation for constructing the pharmaceutically relevant pyrrolidine core. The review is organized into five methodological clusters: 1) intramolecular alkene/alkyne amination; 2) tandem annulations, which involve C─N bond formation as the key step; 3) nucleophilic ...
Rasma Kroņkalne, Māris Turks
wiley +1 more source
Carbanion-Induced [3 + 2] Annulation of Donor–Acceptor Cyclopropanes
The [3 + 2] annulation of donor–acceptor cyclopropanes and ylidenemalonates, in which an α-p-tosyl carbanion functions as a donor substituent, is described.
Takuya Nishio (2882783) +3 more
core +1 more source
Imidazol-5-one as an Acceptor in Donor–Acceptor Cyclopropanes: Cycloaddition with Aldehydes
Spiro[imidazol-5-one-4,1′-cyclopropanes] behave as donor–acceptor (D–A) cyclopropanes in a formal cycloaddition reaction with aldehydes. The activation of such type of cyclopropanes is achieved with an equivalent of Brønsted acid.
Alexander A. Korlyukov (1549351) +13 more
core +1 more source

