Results 191 to 200 of about 30,084 (266)

Synthesis of functionalized polyolefins in a new continuous bench‐scale reactor apparatus

open access: yesAIChE Journal, EarlyView.
Abstract In‐reactor functionalized polyolefins (FPOs), produced by molecular catalysts, are a new class of polymer materials with applications ranging from high performance adhesives to bitumen compatibilization. In this work, we disclose a procedure for the synthesis of FPOs in a new Continuous Bench‐scale Reactor Apparatus (COBRA).
Miloud Bouyahyi   +7 more
wiley   +1 more source

Modulating the Swelling Behavior of Polymer Brushes via Interfacial Chemistry

open access: yesAngewandte Chemie, EarlyView.
Modulating substrate surface chemistry of surface‐grafted polymer brushes via variation of the chemical composition of spacers that anchor initiators for surface‐initiated atom transfer polymerizations allows to tune swelling of these thin polymer films.
Kuljeet Kaur   +4 more
wiley   +2 more sources

One‐Shot Multimaterial 3D Printing of a Flexible Spine for a Robotic Fish Prototype

open access: yesAdvanced Intelligent Systems, EarlyView.
A one‐shot multimaterial 3D printing approach enables a monolithic soft robotic fish integrating a compliant spine and rigid vertebrae. Electromagnetic linear actuators drive tendon‐based transmission, producing controlled tail oscillations. Finite element modeling and experiments show strong agreement, while optimized material selection improves ...
Marco Colletta   +3 more
wiley   +1 more source

Substrate‐Controlled Enantiodivergence in Ni‐Catalyzed Access to Phosphorylated Oxindoles With Quaternary Stereocenters

open access: yesAngewandte Chemie, EarlyView.
An efficient, enantiodivergent synthesis of phosphorylated oxindoles with quaternary stereocenters is achieved via a nickel‐catalyzed intermolecular Heck‐phosphorylation cascade. Employing a single chiral catalyst, either product enantiomer is selectively accessed simply by changing the alkene leaving group. DFT calculations trace this stereodivergence
Haimeng Zhu   +4 more
wiley   +2 more sources

Electrostatic Actuation Induces Competing Adhesion and Vibration Regimes at Fingertip Contact

open access: yesAdvanced Intelligent Systems, EarlyView.
Electric fields modulate fingertip–surface contact to create artificial touch sensations. The mechanisms underlying electrostatic friction, however, remain unclear. Direct imaging and friction measurements under oscillating electric fields showed that adhesion dominates at high frequencies, while vibration contributes substantially at the lower ...
Celal Umut Kenanoglu   +2 more
wiley   +1 more source

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