Results 121 to 130 of about 11,921 (257)

Dry‑Contact Trimming for All‑Perovskite Tandem Solar Cells via Solid‑Solution Homogenization

open access: yesAdvanced Energy Materials, EarlyView.
Narrow‐bandgap Sn–Pb perovskites are promising bottom absorbers for all‐perovskite tandems but suffer from Sn‐rich surfaces and depth‐dependent lattice/compositional inhomogeneity. Layered‐perovskite‐assisted dry‐contact trimming removes Sn‐rich surface species and reconfigures the Sn–Pb absorber, enabling efficient charge collection, reduced voltage ...
Woocheol Han   +10 more
wiley   +1 more source

Lattice Coherency‐Driven (111)‐Oriented Wide Bandgap Perovskite Films

open access: yesAdvanced Energy Materials, EarlyView.
Methylammonium lead chloride (MAPbCl3)‐derived seed templates regulate wide‐bandgap perovskite crystallization through coupled thermodynamic and kinetic effects. Lattice‐coherent templating lowers the energy cost for (111) epilayer growth, while growth retardation controls crystallization kinetics, ultimately producing highly crystalline face‐up (111 ...
Yu‐Na Lee   +5 more
wiley   +1 more source

Redox‐Modulated σ‐Bond Reactivity in a Radical‐Anion Dimer

open access: yesAngewandte Chemie, EarlyView.
A radialene‐based radical anion σ‐dimer comprising an elongated C‐C bond exhibits orthogonal stimuli responsiveness. Homolytic cleavage of the dimer to the radical state is triggered by mechanical strain and high temperature. Dimer scission is also achieved via oxidation, resulting in formation of neutral radialenes.
Sushil Ranjan Bhatta   +8 more
wiley   +2 more sources

Multiscale Perspectives on Perovskite Instability: From Atomistic Deformation to Device Degradation in Perovskite Solar Cells

open access: yesAdvanced Energy Materials, EarlyView.
Multiscale perspectives on how excess charges in soft lead halide perovskites induce operational instability in photovoltaic devices are presented. Localized carriers formed under thermodynamic non‐equilibrium states modify atomistic interactions and drive lattice distortions, accelerating device degradation.
Joo‐Hong Lee   +6 more
wiley   +1 more source

Supramolecular Protection–Deprotection for Switching Pore‐Surface Functionality in a Crystalline Porous Organic Salt

open access: yesAngewandte Chemie, EarlyView.
A supramolecular protection–deprotection strategy temporally separates the framework construction from pore‐surface activation in a porous organic salt. In Form I, phenolic OH groups are protected by DMSO, enabling framework formation. Stepwise single‐crystal‐to‐single‐crystal phase transformation (SCSC) affords a dormant intermediate (Form II ...
Kazuki Shiga   +4 more
wiley   +2 more sources

A Compact Hollow Fiber Electrode Assembly Architecture for Continuous Electrochemical Marine Carbon Dioxide Removal

open access: yesAdvanced Energy Materials, EarlyView.
A coaxial, membrane‐integrated hollow fiber electrode assembly (HFEA) is developed for continuous marine carbon mineralization. By utilizing a sub‐millimeter inter‐electrode gap, the HFEA minimizes Ohmic losses, achieving 50% energy reduction and over 85% DIC removal.
Inhwan Park   +5 more
wiley   +1 more source

Active‐Site Photothermal Energy Utilization in PET Depolymerization

open access: yesAngewandte Chemie, EarlyView.
Photothermal catalysis enables efficient PET depolymerization, yet the role of active‐site temperature remains unclear. A catalytic activity reversal between Pd–CNG and PdPOM–CNG is observed under thermal and photothermal conditions. Efficient nanoscale photothermal energy delivery raises active‐site temperature, compensates for lower intrinsic ...
Xin Li   +7 more
wiley   +2 more sources

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