Results 131 to 140 of about 2,741,293 (282)
Advanced Science, EarlyView.Stable water‐soluble luminescent tris(2,4,6‐trichlorophenyl)methyl (TTM) radicals, TTM‐trisTP3B and TTM‐trisTP9B, were designed and successfully synthesized. They exhibited deep‐red emissions and high photostability in water. TTM‐trisTP3B exhibited dual functionality as a fluorescence imaging (FI) probe and a magnetic resonance imaging (MRI) contrast ...
Kosuke Anraku +6 more
wiley +1 more source
The In Situ Electrochemical−Chemical Cascade Strategy for Pyruvic Acid Synthesis
Advanced Science, EarlyView.By employing an “unsaturation−oxygen coordination engineering” strategy, the local coordination environment is regulated to achieve efficient electrochemical synthesis of H2O2. Importantly, an electrochemical−chemical coupled cascade strategy is utilized for the efficient preparation of pyruvic acid via lactic acid oxidation. ABSTRACT Hydrogen peroxide
Xueli Mei +6 more
wiley +1 more source
STORAGE OF CHARGE IN REDOX CONDUCTIVE POLYMERS PROBED WITH ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY Storage of Charge in Redox Conductive Polymers Probed with Electron Paramagnetic Resonance Spectroscopy / Kulikov, Ilia Romanovich (Rights reserved) (
Kulikov, Ilia Romanovich
core
Emergence of Unconventional Magnetic Order in Strain‐Engineered RuO2/TiO2 Superlattices
Advanced Science, EarlyView.Epitaxial strain activates unconventional magnetism in rutile RuO2, absent in bulk or relaxed RuO2. Polarized neutron reflectometry with atomic‐layer resolution directly reveals finite magnetization confined to RuO2 layers in fully strained RuO2/TiO2 superlattices on TiO2 (110).
Seung Gyo Jeong +12 more
wiley +1 more source
cis‐Carboxylate Enhancement of Mn(III)‐OH Hydrogen Atom Abstraction through PCET Thermodynamics
Advanced Science, EarlyView.ABSTRACT Manganese(III)‐hydroxo intermediates are proposed as key hydrogen atom abstraction (HAA) species in manganese‐dependent enzymes, yet how first‐sphere carboxylate ligands control their proton‐coupled electron transfer (PCET) thermodynamics remains poorly understood.
Yuri Lee +4 more
wiley +1 more source
Advanced Science, EarlyView.We develop a ligand engineering strategy to construct Ni‐diketimine‐linked COFs with precisely tuned Ni electronic states. By varying the coordinated diketone units, we achieve an optimal electronic configuration that enhances O2 adsorption and lowers the energy barrier for •O2− generation.
Guihong Wu +5 more
wiley +1 more source
Advanced Science, EarlyView.Chemical disorder engineering reconfigures BO6 oxygen‐octahedron rotations in lead‐free K0.5Na0.5NbO3 ceramics from local ordering into a random distribution, dissolving the longstanding trade‐off between optical transparency and electromechanical strain.
Xia Luo +5 more
wiley +1 more source
Advanced Science, EarlyView.Three phenothiazine‐based polyamides featuring gradually strengthened electron‐withdrawing linkers are developed as high‐voltage cathodes for lithium‐organic batteries. The linker motif serves not only as a structural bridge to suppress solubility, but also as a functional design element that governs optoelectronic properties and electron/ion transport
Shujuan Cao +4 more
wiley +1 more source
Advanced Science, EarlyView.Atomically dispersed Fe regulates the local electronic environment and surface properties of SnS, while PMS preferentially coordinates to Sn through Sn–O interaction. Fe incorporation further enhances the Sn–OPMS interfacial interaction, facilitating Sn‐centered PMS activation and the generation of SO4•−/•OH for APAP degradation, thereby clarifying the
Shuhui Liu +5 more
wiley +1 more source