Results 141 to 150 of about 337,569 (307)

Exchange Phenomena in the Electron Paramagnetic Resonance Spectra of the Nitroxyl and Trityl Radicals: Multifunctional Spectroscopy and Imaging of Local Chemical Microenvironment.

Analytical Chemistry, 2017
V. Khramtsov, A. Bobko, M. Tseytlin, B. Driesschaert   +3 more
semanticscholar   +1 more source

Enzyme‐Activated MRI for In Vivo Glucose Imaging via a Biodegradable Chromium Nanoprobe

Advanced Science, EarlyView.
Enzyme‐activated MRI (eaMRI) using a biodegradable CrGOx@Lip nanoprobe enables glucose‐specific imaging in vivo. GOx catalyzes glucose oxidation, triggering in situ formation of paramagnetic chromium gluconate and amplifying T1. This radiation‐free strategy maps tumor glucose uptake via the Warburg‐effect, quantifies hepatic glucose accumulation in ...
Yan Xu, Weitao Yang, Yanjing Yun, Hui Wang, Zhuoyao Wu, Youyi Yu, Bingbo Zhang   +6 more
wiley   +1 more source

Electron Delocalization Induced by 3d–4f Orbital Hybridization of Co─Ce Atom Pairs Toward Enhanced Electromagnetic Wave Attenuation and Antibacterial Performance

Advanced Science, EarlyView.
Co─Ce dual atomic configuration anchored on the surface of NC matrix has been constructed to regulate the local electron structure. The higher occupied states induced by the Co 3d‐Ce 4f orbital hybridization facilitate the formation of polarized electric fields, which in turn strengthens the polarization relaxation and partially repairs the effective ...
Da Li, Yinyin Zhao, Yang Zhang, Cui Ni, Xiaoguang Zhao, Chongchang Zhou, Guoqiang Ren, Pengfei Liu, Xiubo Xie   +8 more
wiley   +1 more source

Unsaturated Coordination Oxygen in Zn─V─O Vacancy Clusters Enables Superb Zinc Storage Capability

Advanced Science, EarlyView.
Zn3(VO4)2 with Zn─V─O vacancy clusters was synthesized and innovatively applied as cathode material in aqueous Zn‐ion batteries. In‐situ XRD, HRTEM and ab initio molecular dynamics simulations unveil the double reaction mechanism of zinc ions. Adsorption of zinc ions on unsaturated coordination O and H+ on O in ‐VO4 contributes to the main capacity. It
Yulong Chi, Fulong Li, Yangxian Wang, Longwei Li, Haolin Li, Xiaodong Shi, Xinlong Tian, Yihui Zou, Dongjiang Yang   +8 more
wiley   +1 more source

Functional electron paramagnetic resonance imaging of ischemic rat heart: Monitoring of tissue oxygenation and pH

Magnetic Resonance in Medicine, 2016
Artem A. Gorodetsky, I. Kirilyuk, V. Khramtsov, D. Komarov   +3 more
semanticscholar   +1 more source

Robust and Thermally Stable Silicone Aerogels with Hyperconnected Network via Kinetically Optimized Hyperbranched Silane Precursors

Advanced Science, EarlyView.
Reactivity‐Programmed Assembly: A kinetic‐control strategy is reported for constructing hyperconnected silicone aerogels with a robust “thick‐neck” architecture. By exploiting the reactivity disparity of precursors, flexible segments are uniformly embedded within a rigid skeleton.
Aoqing Yan, Guixiang Li, Yaolan Li, Yi Luo, Bin Liu, Zhe Su, Hao Tian, Wei Shi, Bo Niu, Donghui Long   +9 more
wiley   +1 more source

Electron paramagnetic resonance of individual atoms on a surface

Science, 2015
S. Baumann, W. Paul, T. Choi, C. Lutz, A. Ardavan, A. Heinrich   +5 more
semanticscholar   +1 more source

Self‐Amplifying Redox Cycle Triggers Ferroptosis/Cuproptosis Synergy for Enhanced Bacterial Eradication

Advanced Science, EarlyView.
This study designs a targeted nanocomposite (ct@HMCF‐Dex) that responds to acidic infection microenvironments, releasing components which amplify oxidative stress. It disrupts bacterial redox balance, chelates metals to sustain lipid peroxidation, and synergistically induces cuproptosis/ferroptosis‐like death.
Zehui Xiao, Shaolong Qiu, Jiangli Cao, Jifeng Liu, Zhiyong Song, Ting Du, Xinjun Du   +6 more
wiley   +1 more source

Natural Maghemite Nanoparticles in Crude Oil Seen by Electron Paramagnetic Resonance. [PDF]

ACS Omega
Pessoa MS, Moscon PS, Vicente M, Santos MFP, Flores EMM, Morais PC, Narcizo de Souza PE, Sousa M, Passamani EC.   +8 more
europepmc   +1 more source

Nanocurvature‐Activated Dipolar Polarization in M–N4 Single‐Atom Sites for High‐Performance Electromagnetic Wave Absorption

Advanced Science, EarlyView.
Increasing nanocurvature effectively enriches the local electron density of the M–N4 motif, which facilitates electron transfer from the metal center to nitrogen atoms. This electronic behavior intensifies the localization and asymmetric distribution of charge, thereby significantly amplifying the dipole moment and polarizability.
Daohu Sheng, Siyao Cheng, Mengmeng Zhang, Jinglei Zhang, Xufei Zhu, Weijin Li, Bo Zhang, Aming Xie   +7 more
wiley   +1 more source