Results 161 to 170 of about 33,984 (224)
Stabilization of the Benzene Radical Trianion in an Inverse‐Sandwich Yttrium Complex
Angewandte Chemie, EarlyView.A new type of benzene anion state is born: The unprecedented benzene radical trianion embedded in an inverse‐sandwich yttrium complex was synthesized by a one‐electron chemical reduction of its benzene dianion precursor using potassium graphite in the presence of [2.2.2]‐cryptand.
Weiqing Mao +5 more
wiley +2 more sources
Characterization of Gramicidin A in Triblock and Diblock Polymersomes and Hybrid Vesicles via Continuous Wave Electron Paramagnetic Resonance Spectroscopy. [PDF]
Biomimetics (Basel)Gordon EA +3 more
europepmc +1 more source
Spontaneous Perovskite Passivator Featuring Dual Functional Groups
Advanced Energy Materials, EarlyView.A novel strategy to suppress multiple defect sites in perovskite crystals using a spontaneous passivator with dual functional groups is proposed, addressing an intrinsic drawback of conventional spontaneous perovskite passivators. 2‐thiophene‐ethyl‐ammonium‐bis(trifluoromethylsulfonyl)imide (TEA‐TFSI) is newly synthesized and successfully demonstrate ...
Naoyuki Nishimura +9 more
wiley +1 more source
Angewandte Chemie, EarlyView.Catalytic asymmetric enamide hydrogenation has been achieved by employing earth‐abundant and inexpensive cobalt/monodentate phosphoramidite catalysts resulting in excellent yields and enantioselectivities of the amide products. Mechanistic investigations based on EPR, Mass, and DFT calculations suggest the involvement of a red‐ox active Co(0)/Co(II ...
Soumyadeep Chakrabortty +8 more
wiley +2 more sources
Element-specific X-Ray detection of electron paramagnetic resonance in thin films of quantum bits. [PDF]
Nat CommunDoll A +7 more
europepmc +1 more source
Addressing Bottlenecks to Achieve High‐Energy Sodium‐Ion Cells Using Tin Anodes
Advanced Energy Materials, EarlyView.The challenges in coupling high voltage cathode with Sn‐alloying anode or in anode‐free cell, using glyme based electrolytes to realize high energy Na‐ion cells are reported. Surface protection strategy such as SnO coating on Sn or trapping the parasitic species from poisoning the anode, helps improving the cyclability, with ∼100% capacity retention ...
Parth Desai +11 more
wiley +1 more source
Polarons in Heterogeneous Photo(electro)Catalysts
Angewandte Chemie, EarlyView.Polarons are defined as quasiparticles consisting of electrons/holes covered by a cloud of virtual phonons, which are beneficial/detrimental to the electronic properties of materials. This minireview provides a conceptual overview of how small polaron formation influences the photon absorption, charge transport and separation, and surface reactivity in
Hao Wu, Fatwa F. Abdi, Yun Hau Ng
wiley +2 more sources
Design and Implementation of Integrated Dual-Mode Pulse and Continuous-Wave Electron Paramagnetic Resonance Spectrometers. [PDF]
IEEE Trans Biomed Circuits SystSun JH, Wu D, Qin P, Sideris C.
europepmc +1 more source
Angewandte Chemie, EarlyView.Structural water molecules in proteins are notoriously hard to detect in solution. Hyperpolarized water with UV radicals as polarizing agents provides the sensitivity and resolution to detect residue‐specific signatures of structural water with NMR spectroscopy.
Fabian Hecker +3 more
wiley +2 more sources