Results 81 to 90 of about 2,590,996 (283)

Efficient Hydroxyl Diffusion Triggers Surface Hydronium Enrichment and Bulk Proton Participation to Boost Alkaline Hydrogen‐Evolving Reaction

Advanced Materials, EarlyView.
For the first time, we shed light on the surface‐to‐bulk diffusion, induction, and reaction behaviors of OH−, H+, and H2O species on model oxides for alkaline hydrogen‐evolving reaction (HER). We first demonstrate that bulk OH− diffusion significantly affects the generation of proton sources and the diffusion/reaction behaviors of protons, thus ...
Daqin Guan, Hengyue Xu, Xiao Sun, Leqi Zhao, Chun‐Kuo Peng, Chao Jing, Yu‐Cheng Huang, Jiayi Tang, Nai Shi, Zezhou Lin, Xiaomin Xu, Zhiwei Hu, Zongping Shao   +12 more
wiley   +1 more source

Engineering Metal‐Pocket Cooperativity in Single‐Atom COF Nanozymes for Selective Cascade Catalysis

Advanced Materials, EarlyView.
A multilevel programming strategy is developed to engineer single‐atom COF nanozymes with tunable metal centers and chiral pockets inspired by heme–pocket cooperativity. This approach enables controlled metal–pocket interplay for asymmetric cascade catalysis, delivering high activity, selectivity, and recyclability in an asymmetric oxidation–aldol ...
Ziping Li, Qijun Sun, Yawen Hao, Haotian Wen, Shery Chang, Fengwang Li, Jiangtao Xu, Kang Liang   +7 more
wiley   +1 more source

Incorporation of Spin Labels and Paramagnetic Tags for Magnetic Resonance Studies Using Cycloaddition Reactions as a Tool

Reactions
The cycloaddition reaction is one of the most common reactions in organic chemistry. It has been applied in various fields. Herein, we focus on the application of cycloaddition reactions in investigating biological molecules and materials using magnetic ...
Amarendra Nath Maity, Amiya Kumar Medda, Shyue-Chu Ke   +2 more
doaj   +1 more source

Side‐Chain‐Induced Interlayer Slipping in Metalloporphyrin COFs Enables Microenvironment and Spin‐State Regulation for Photocatalytic CO2 Reduction

Advanced Materials, EarlyView.
Alkoxy chain length drives a continuous transition from eclipsed AA to a serrated, slipped AA* configuration over Co‐porphyrin COFs. A moderate slip both contracts the pore channel to enrich CO2 and suppress hydrogen evolution, and enhances collective high‐spin of Co sites, which delivers a record CO production rate with high selectivity.
Jie He, Qingxuan Chen, Minxian Zhang, Wenhao Zhao, Aoni Xu, Jinqiang Zhang, Hongqi Sun, Shaobin Wang, Xiaoguang Duan   +8 more
wiley   +1 more source

Binuclear Complexes (2):Electron Paramagnetic Resonance Study of Binuclear Copper Complexes with α-Diimine Ligand

, 2009
A series of biouclear copper (II) complexes containing a-diimine ligand has been synthesized and characterized by electron paramagnetic resonance spectroscopy.
Wang, Wen-jwu
core   +1 more source

Hierarchical Flexible Ceramic Nanofiber Membrane for Simultaneous Membrane Distillation and Photocatalytic Hydrogen Evolution

Advanced Materials, EarlyView.
A hierarchical flexible ceramic nanofiber membrane integrates a La‐stabilized ZrO2 scaffold with superhydrophobic UiO‐66‐NH2/CdS heterojunctions. The gas–liquid–solid interfacial architecture sustains vapor‐selective desalination, visible‐light charge separation, and rapid H2 extraction, enabling simultaneous freshwater production and photocatalytic ...
Pengfei Lin, Xiaochen Lu, Jiawei Sun, Shuai Guo, Xinping He, Chunhai Yi, Zhenyao Wang, Jiaxin Guo, Swee Ching Tan, Alicia Kyoungjin An   +9 more
wiley   +1 more source

Metalloproteins and protein-protein complexes investigated by CW and pulsed EPR spectroscopy [PDF]

, 2006
One of the central research topics in the field of biophysical chemistry is the structure and function of membrane proteins involved in energy transduction.
Lyubenova, Sevdalina
core  

Decoding Synergistic Pathways in Bimetallic MOFs for Advanced Oxidation Processes

Advanced Materials, EarlyView.
This review presents a unified framework linking metal pairing and framework design with electronic structure, redox cycling, oxidant activation, reactive‐species generation, and catalytic performance across photocatalytic and oxidant‐based BMOF‐AOPs. The resulting design principles guide the development of hydrolytically stable and efficient BMOFs for
Karim El‐Naggar, Huayang Zhang, Shaobin Wang   +2 more
wiley   +1 more source

Moiré Phase Mapping in Twisted Bilayer Liquid Crystals with Reconfigurable Light Polarization States

Advanced Materials, EarlyView.
Twisted bilayer liquid crystals are developed by vertical stacking assembly of two liquid crystals having designer domains and optical properties. These moiré‐symmetry, twisted liquid crystals demonstrate reconfigurable polarization states, moiré patterns and phases controlled by twist angles, providing a route to design active optical devices for ...
Jordan A. Wilson, Rui Huang, Allen Sun, Zixian Fang, Doreen Mwangombe, Keerthna Naina Rawat, Oliver Jacobs, Zhiwei Li   +7 more
wiley   +1 more source

Effective coupling of rapid freeze-quench to high-frequency electron paramagnetic resonance.

PLoS ONE, 2020
We report an easy, efficient and reproducible way to prepare Rapid-Freeze-Quench samples in sub-millimeter capillaries and load these into the probe head of a 275 GHz Electron Paramagnetic Resonance spectrometer.
E Gabriele Panarelli, Harmen van der Meer, Peter Gast, Edgar J J Groenen   +3 more
doaj   +1 more source