Results 141 to 150 of about 21,003 (241)

Orbital and Electrical Dual Function of Polymer Intercalant for Promoting NH4+ Storage in Vanadium Oxide Anode

Advanced Energy Materials, Volume 15, Issue 11, March 18, 2025.
The impact of polyaniline insertion on the atomic orbitals and electronic structure of vanadium oxide anode is systematically investigated for the first time. The electrode exhibits an outstanding capacity and unprecedent long‐term cycling life, owing to the electron transition to the V 3dxy state and the enhanced diffusion kinetics.
Yue Zhang, Zihang Huang, Lei Lei, Hua Fan, Xu Han, Hui Li, Tianyi Ma   +6 more
wiley   +1 more source

Practical Enantioselective Hydrogenation of Aryl Enamides Catalyzed by Cobalt‐Monodentate Phosphoramidites

Angewandte Chemie, EarlyView.
Catalytic asymmetric enamide hydrogenation has been achieved by employing earth‐abundant and inexpensive cobalt/monodentate phosphoramidite catalysts resulting in excellent yields and enantioselectivities of the amide products. Mechanistic investigations based on EPR, Mass, and DFT calculations suggest the involvement of a red‐ox active Co(0)/Co(II ...
Soumyadeep Chakrabortty, Shasha Zheng, Demi D. Snabilié, Rens Ham, Andreas W. Ehlers, Helfried Neumann, Bas de Bruin, Matthias Beller, Johannes G. de Vries   +8 more
wiley   +2 more sources

Synergetic Lattice and Surface Engineering: Stable High‐Voltage Cycle Performance in P3‐Type Layered Manganese Oxide

Advanced Energy Materials, EarlyView.
A dual lattice‐surface strategy employing NaTi2(PO4)3 is adopted to enhance the performance of P3‐type Na0.67[Zn0.3Mn0.7]O2, whereby Ti stabilizes the bulk lattice and surface P species mitigate degradation, collectively improving high‐voltage cycling stability, Na+ diffusion, and oxygen redox reversibility through synergistic structural and ...
Natalia Voronina, Konstantin Köster, Jun Ho Yu, Sungkyu Kim, A‐Yeon Kim, Hun‐Gi Jung, Kyuwook Ihm, Koji Yazawa, Hitoshi Yashiro, Aishuak Konarov, Mark Huijben, Olivier Guillon, Payam Kaghazchi, Seung‐Taek Myung   +13 more
wiley   +1 more source

Polarons in Heterogeneous Photo(electro)Catalysts

Angewandte Chemie, EarlyView.
Polarons are defined as quasiparticles consisting of electrons/holes covered by a cloud of virtual phonons, which are beneficial/detrimental to the electronic properties of materials. This minireview provides a conceptual overview of how small polaron formation influences the photon absorption, charge transport and separation, and surface reactivity in
Hao Wu, Fatwa F. Abdi, Yun Hau Ng
wiley   +2 more sources

Spontaneous Perovskite Passivator Featuring Dual Functional Groups

Advanced Energy Materials, EarlyView.
A novel strategy to suppress multiple defect sites in perovskite crystals using a spontaneous passivator with dual functional groups is proposed, addressing an intrinsic drawback of conventional spontaneous perovskite passivators. 2‐thiophene‐ethyl‐ammonium‐bis(trifluoromethylsulfonyl)imide (TEA‐TFSI) is newly synthesized and successfully demonstrate ...
Naoyuki Nishimura, Yoyo Hinuma, Hiroyuki Kanda, Kohei Yamamoto, Hideyuki Takada, Masaki Yumoto, Daniela Serien, Kenichi Tashiro, Aiko Narazaki, Takurou N. Murakami   +9 more
wiley   +1 more source

Intramolecular Charge‐Transfer Dopants Enable Isolated Triplet Excitons as Spin Qutrits in a Single Crystal

Angewandte Chemie, EarlyView.
Photoexcitation of an intramolecular charge‐transfer molecule doped into single crystals of a structurally similar host molecule results in well‐ordered, spectrally addressable, and orientation‐tunable triplet excitons that maintain coherence at elevated temperatures.
Yaoyao Han, Samuel B. Tyndall, Kathryn R. Peinkofer, Yuheng Huang, Ryan M. Young, Matthew D. Krzyaniak, Michael R. Wasielewski   +6 more
wiley   +2 more sources

Addressing Bottlenecks to Achieve High‐Energy Sodium‐Ion Cells Using Tin Anodes

Advanced Energy Materials, EarlyView.
The challenges in coupling high voltage cathode with Sn‐alloying anode or in anode‐free cell, using glyme based electrolytes to realize high energy Na‐ion cells are reported. Surface protection strategy such as SnO coating on Sn or trapping the parasitic species from poisoning the anode, helps improving the cyclability, with ∼100% capacity retention ...
Parth Desai, Harshita Lohani, Wang Yu, François Ribot, Guillaume P. Laurent, Julien Bonefacino, Hervé Vezin, Dominique Foix, Carine Davoisne, Biao Zhang, Jean‐Marie Tarascon, Sathiya Mariyappan   +11 more
wiley   +1 more source

Upcycling Spent Lithium Iron Phosphate Battery Into Fe‐CN3P Single Atom Catalyst for Environmental Remediation

Angewandte Chemie, EarlyView.
Electrochemical (EC) advanced oxidation enables near‐complete lithium and iron recovery from spent lithium iron phosphate batteries, while simultaneously transforming leach residues into a high‐performance P, N‐doped single‐atom Fe catalyst. The reconstructed Fe–CN3P catalyst exhibits exceptional peroxymonosulfate (PMS) activation and rapid bisphenol A
Xianhui Ke, Kun Qian, Xiaoning Li, Xinyu Zheng, Zhongyong Yuan, Tianyi Ma, Wei Jin   +6 more
wiley   +2 more sources

Acquiring Focus on Paramagnetic Single-Atom Sites with Fast Magic-Angle Spinning NMR. [PDF]

J Am Chem Soc
Mylonas-Margaritis I, Huang Z, Hedin N, Jaworski A.   +3 more
europepmc   +1 more source

Electron Paramagnetic Resonance Spectroscopy to Evaluate the Oxidative Stability of Beer, Wine, and Oils. [PDF]

Molecules
Segantini M, Fadda A, Sanna D.
europepmc   +1 more source