Results 161 to 170 of about 2,767,492 (285)

Tunable Raman Scattering of Fe(II) Coordination Networks With Magnetic Fields

Angewandte Chemie, EarlyView.
Four heavy Hg(II) coordination networks with paramagnetic Fe(II) sites reveal strong and halogen‐tunable low‐frequency (LF) sub‐terahertz phonons and field‐dependent magnetic transitions. LF phonon spectroscopy and Raman magnetospectroscopy are powerful probes of structure, low‐energy vibration, zero‐field splitting, and spin–phonon coupling supported ...
Guanping Li, Olaf Stefanczyk, Joseph M. Flitcroft, Jonathan M. Skelton, William T. Morrillo, Meagan Oakley, Lulu Xiong, Koji Nakabayashi, Dmitry Smirnov, Komalavalli Thirunavukkuarasu, Mykhaylo Ozerov, Shin‐ichi Ohkoshi, Nicholas F. Chilton   +12 more
wiley   +2 more sources

Au Quantum Dots Anchored Y‐MOF Enabling Directional Interfacial Charge Transfer for Synergistic Redox Photocatalysis

Advanced Science, EarlyView.
Metal‑support interaction and directional interfacial charge transfer in Au QDs‐anchored Y‐MOF synergistically greatly boost redox photocatalysis for hydrogen evolution and acetaldehyde removal. ABSTRACT The synergistic photocatalytic production of hydrogen coupled with pollutant degradation offers a transformative pathway toward sustainable energy and
Hui Yang, Dong Xu, Xue Lu, Yinbao Wu, Feng Tang, Linfu Xie, Saisai Yuan, Xiaozhi Wang, Qitao Zhang, Bin Xu   +9 more
wiley   +1 more source

Guest Transition Metals in Host Keplerate Nanocapsules as Supramolecular Inorganic Functional Mimics of Monooxygenase Enzymes

Angewandte Chemie, EarlyView.
A Keplerate, an inorganic, porous buckyball was used as a host for copper metal cations ligated by histidine surrogates. Prepared by a simple assembly technique, the guest–host complex was used as a primitive biomimetic model of a monooxygenase enzyme complex, where C─H bonds were electrocatalytically hydroxylated by oxygen under reducing conditions ...
Eynat Haviv, Hagai Cohen, Ayelet Vilan, Liat Avram, Ronny Neumann   +4 more
wiley   +2 more sources

Orbital and Electrical Dual Function of Polymer Intercalant for Promoting NH4+ Storage in Vanadium Oxide Anode

Advanced Energy Materials, Volume 15, Issue 11, March 18, 2025.
The impact of polyaniline insertion on the atomic orbitals and electronic structure of vanadium oxide anode is systematically investigated for the first time. The electrode exhibits an outstanding capacity and unprecedent long‐term cycling life, owing to the electron transition to the V 3dxy state and the enhanced diffusion kinetics.
Yue Zhang, Zihang Huang, Lei Lei, Hua Fan, Xu Han, Hui Li, Tianyi Ma   +6 more
wiley   +1 more source

Simultaneous Electronic and Crystallographic Modulation of Cs3Bi2Br9 by Single‐Element Sn Substitution for Enhanced CO2 Photoreduction

Advanced Energy Materials, EarlyView.
Aliovalent B‐site substitution with Sn2+ in lead‐free perovskite, Cs3Bi2Br9, is employed to simultaneously induce lattice contraction and bromine vacancy through charge imbalance and ionic radius mismatch. The resulting structural distortion modulates the electronic structure and improves charge separation, leading to enhanced visible‐light‐driven CO2 ...
Justin Khor, Jiale Lee, Xin Ying Kong, Qixin Zhou, Yongfa Zhu, Jingxiang Low, Siang‐Piao Chai, Lling‐Lling Tan   +7 more
wiley   +1 more source

Mechanochemical Defluorination of Polytetrafluoroethylene (PTFE) With Base Metals

Angewandte Chemie, EarlyView.
Polytetrafluoroethylene (PTFE) mechanochemically reacts with safe‐to‐handle, abundant, and inexpensive base metals Zn and Al, as well as with metals like Cd and Pb, to produce sp2‐carbon and industrially important metal fluorides. The reactivity presents PTFE as a mechanochemical fluorination agent, with opportunities for closed‐loop reductive ...
Anže Zupanc, A. R. Bonnie J. Lutton Gething, Alex J. Green, Shrestha Banerjee, Moosa Wasim, Luis Simbari, Benjamin B. Duff, Peter R. Slater, Dominik J. Kubicki, Erli Lu, Tomislav Friščić   +10 more
wiley   +2 more sources

Covalent Immobilisation of PVA‐MA Hydrogels on Plasma‐Activated Coatings: Achieving Superior Adhesion by Reagent‐Free Formation of a Nanoscale Primer Layer

Advanced NanoBiomed Research, EarlyView.
Robust attachment of hydrogels to solid substrates is critical to success in cell culture where hydrostatic and contractile forces can contribute to delamination of weakly adhered gels. This novel approach forms a nanometer‐scale, reagent‐free hydrogel primer layer to provide improved resistance to delamination of subsequent bulk hydrogel layers in a ...
Sophia C. Franklin, Clara T. H. Tran, Matthew Hadden, David Martinez‐Martin, Laura Poole‐Warren, Marcela M. M. Bilek, Ulises Aregueta Robles, Aaron D. Gilmour   +7 more
wiley   +1 more source

Controlled Hydrogen Delivery by Single‐Atom Ru Accelerates Electrocatalytic Ammonia Synthesis

Angewandte Chemie, EarlyView.
Single Ru atoms anchored on Co3O4 guide reactants along a hydrogen‐rich surface pathway, enabling efficient and selective conversion of NO to NH3. By linking atomic design to catalytic performance, this strategy clarifies the reaction mechanism and offers a versatile platform for engineering oxide catalysts for electrochemical ammonia synthesis ...
Zheng Liu, Xingchi Li, Zhenggang Xue, Jiayi Liu, Zhenlin Wang, Evangelina Pensa, Donglin Han, Jialing Song, Haiyan Duan, Chaoqi Zhang, Lupeng Han, Ming Xie, Yongjie Shen, Wenqiang Qu, Emiliano Cortes, Dengsong Zhang   +15 more
wiley   +2 more sources

Gold Clusters With Open‐Shell Ligands: Superatom Mediated Magnetic Interaction

Angewandte Chemie, EarlyView.
Open‐shell verdazyl radicals were covalently integrated with atomically precise Ir‐doped Au12 (Ir@Au12) superatoms. The resulting radical–superatom hybrids exhibit photoinduced electron transfer, spin delocalization onto the metal‐cluster core, and weak ferromagnetic communication between radicals mediated by the superatomic electronic structure ...
Katsuya Mutoh, Kosei Hayashi, Yoichi Kobayashi, Kazunobu Sato, Rika Tanaka, Daichi Kitagawa, Tatsuya Tsukuda, Takuya Nakashima   +7 more
wiley   +2 more sources

Electron Paramagnetic Resonance (EPR) Spectroscopy Reveals Nucleotide- and Partner-Dependent Conformational Ensembles in Hsp90. [PDF]

J Phys Chem B
Fiotaki C, Goldfarb D, Giannouli A.
europepmc   +1 more source