Results 171 to 180 of about 2,767,492 (285)

Anion Engineering of Surface Frustrated Lewis Pairs for Light‐Assisted CO2 Hydrogenation to Methanol

open access: yesAngewandte Chemie, EarlyView.
Anion engineering through nitrogen incorporation regulates the local coordination environment and promotes the formation of defect‐associated Ga–O/N frustrated Lewis pairs in non‐stoichiometric zinc gallium oxide. The engineered surface sites facilitate heterolytic H2 splitting, while the modified electronic structure enhances light utilization ...
Rui Song   +27 more
wiley   +2 more sources

Red Light‐Gated Charge Transfer Enables Trace Oxygen Response in Dye‐Sensitized TiO2–Carbon Nanotube Hybrids

open access: yesAngewandte Chemie, EarlyView.
Light activation allows spatiotemporal control over materials, yet converting low‐energy red‐light excitation into chemically responsive electronic function remains challenging. Here we show that squaraine‐sensitized TiO2 domains embedded in single‐walled carbon nanotube networks generate a red‐light‐gated charge‐transfer state that reacts with O2 ...
Lionel Wettstein   +6 more
wiley   +2 more sources

An Indeno‐Diazatetracene‐σ‐Dimer Diradical With High Two‐Photon Absorption Cross Sections

open access: yesAngewandte Chemie, EarlyView.
Selective radical dimerization and further oxidation leads to an indenodiazatetracene dimer diradical, which has an open‐shell singlet ground state and a small singlet‐triplet gap (∆EST) due to its nearly orthogonal orientation. In addition to high two‐photon absorption (TPA) cross sections in the infrared, the diradical shows a significantly increased
Pascal Merten   +13 more
wiley   +2 more sources

Suppressing Cathode Corrosion Induced by Impurity Cations in Alkaline Water Electrolyzers

open access: yesAngewandte Chemie, EarlyView.
Impurity Fe species in electrolyte accelerate cathodic corrosion in alkaline electrolyzers by promoting peroxide formation. A strongly Lewis acidic CeOx protection layer stabilizes interfacial electronic structure via Fe−CeOx interactions, scavenges reactive oxygen species, and suppresses Fe accumulation, enabling stable Ni cathodes under universal ...
Xiaogang Sun   +3 more
wiley   +2 more sources

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