The Role of Charge in Microdroplet Redox Chemistry [PDF]
arXivIn charged water microdroplets, which occur in nature or in the lab upon ultrasonication or in electrospray processes, the thermodynamics for reactive chemistry can be dramatically altered relative to the bulk phase. Here, we provide a theoretical basis for the observation of accelerated chemistry by simulating water droplets of increasing charge ...
arxiv
A Novel Merocyanine Derivative for Probing Polarity at Cubosome Interfaces
Asian Journal of Organic Chemistry, Accepted Article.This study reports the development of a synthetic route for the chemical environment sensor C10SP, designed for incorporation into phytantriol‐based cubosomes. The molecule combines an apolar aliphatic tail for lipid bilayer anchoring with a polarity‐sensitive chromophore.
Marcelo J. Eberhardt +3 more
wiley +1 more source
Single‐Step Synthesis of a Heterometallic [Cu2PdL4]2+ Hybrid Metal–Organic Coordination Cage
Angewandte Chemie, EarlyView.A heterotrimetallic [Cu2PdL4]2+ lantern‐type cage has been synthesized in a single self‐assembly step from a low‐symmetry heterotopic ligand containing terminal groups with different metal coordination preferences, hybridizing the metallosupramolecular motifs of Cu4L4 and Pd2L4 cages.
Shannon Thoonen +10 more
wiley +2 more sources
Alterations in gut microbiota and metabolites contribute to postoperative sleep disturbances
Animal Models and Experimental Medicine, EarlyView.In this study, we classified postoperative patients into poor sleepers (PS) and good sleepers (GS) based on the bispectral index (BIS), and transplanted their fecal microbiota to pseudo‐germ‐free rats to analyze the sleep changes in rats and the potential mechanism.
Hui Zhong +7 more
wiley +1 more source
A Bench‐Stable Fluorophosphine Nickel(0) Complex and Its Catalytic Application
Angewandte Chemie, EarlyView.We herein present the synthesis of a bench‐stable Ni(0) complex, [Ni(PFPh2)4], stabilized by vastly underexplored fluorophosphine ligands. The application of [Ni(PFPh2)4] in Suzuki–Miyaura and Kumada‐Tamao‐Corriu cross‐coupling reactions as well as in Buchwald–Hartwig C─N bond formation reactions, indicates its promising potential as alternative to ...
Franziska Flecken +3 more
wiley +2 more sources
Increased Glutathionyl Hemoglobin in Diabetes Mellitus and Hyperlipidemia Demonstrated by Liquid Chromatography/Electrospray Ionization-Mass Spectrometry [PDF]
, 2000 Toshimitsu Niwa +3 more
openalex +1 more source
Animal Models and Experimental Medicine, EarlyView.Cannabidiol (CBD) has numerous therapeutic properties, and is used to treat neurological conditions, such as neuroinflammation. However, the optimal dose of CBD to penetrate the brain requires further investigation. The primary aim of this study was to use a mouse model and the intrabuccal route for CBD administration to determine the optimal dose at ...
Oluwadara Pelumi Omotayo +4 more
wiley +1 more source
Rapid Determination of Total Homocysteine in Blood Spots by Liquid Chromatography-Electrospray Ionization-Tandem Mass Spectrometry [PDF]
, 2000 Klaus Gempel +3 more
openalex +1 more source
ChemBioChem, Volume 23, Issue 23, December 5, 2022., 2022 Fifteen new dinuclear arene‐ruthenium (II)‐BODIPY conjugates were synthesized. Despite a fluorescence quenching effect, these conjugates can be used as fluorescent tracers. Their antiparasitic activity but also their toxicity against healthy human foreskin fibroblasts (HFFs) was reduced compared to the parent ruthenium compounds.
Oksana Desiatkina +6 more
wiley +1 more source
Electrospray ionization mass spectrometry analyses of nuclear membrane phospholipid loss after reperfusion of ischemic myocardium [PDF]
, 2000 S. D. Williams +2 more
openalex +1 more source