Results 231 to 240 of about 297,282 (382)

Cucurbit[7]Uril‐Based Supramolecular Polymers With Dual Photochromism and Fluorescence: From Host‒Guest Design to Smart Applications

open access: yesAggregate, EarlyView.
The supramolecular complexes of cucurbit[7]uril with thiophene‐pyridinium guests formed by different assembly ratios exhibit different photochromic and fluorescence properties, which render them suitable for applications in multi‐level anti‐counterfeiting and advanced information encryption.
Long‐Jing Wu   +5 more
wiley   +1 more source

Real‐Time Eco–AI, Electrophoresis‐Correlative Data‐Dependent Acquisition with AI‐Based Data Processing Broadens Access to Single‐Cell Mass Spectrometry Proteomics

open access: yesAngewandte Chemie, EarlyView.
An affordable single‐cell proteomics workflow combines capillary electrophoresis, real‐time ion sorting, and AI‐aided spectral deconvolution to profile early Xenopus embryonic cells. Despite using a legacy Orbitrap, this strategy matches or exceeds the sensitivity of modern instruments, uncovering proteome dynamics at sub‐nanogram scale.
Bowen Shen, Fei Zhou, Peter Nemes
wiley   +2 more sources

A Fast-Pass, Desorption Electrospray Ionization Mass Spectrometry Strategy for Untargeted Metabolic Phenotyping. [PDF]

open access: yesJ Am Soc Mass Spectrom
Shepard HS   +6 more
europepmc   +1 more source

Rapid authentication of different herbal medicines by heating online extraction electrospray ionization mass spectrometry. [PDF]

open access: yesJ Pharm Anal, 2023
Qiu Z   +11 more
europepmc   +1 more source

Natural Polyphenol–Metal Supramolecular Nanocomplex for Ferroptosis Activation in Chemoresistant Hepatocellular Carcinoma

open access: yesAggregate, EarlyView.
This study presents a supramolecular nanocomplex assembled from a natural polyphenol and Cu(II) that enables cascade glutathione (GSH) depletion through synthesis inhibition, redox cycling, and Michael addition. The system induces dual cytoplasmic and mitochondrial ferroptosis in cisplatin‐resistant hepatocellular carcinoma (HCC), reverses drug ...
Yan Qin   +6 more
wiley   +1 more source

Mechanistic Divergence in Sulfur‐Ligated Iron(III)‐Alkylperoxo Reactivity: Aldehyde Oxidation Prevails over Deformylation

open access: yesAngewandte Chemie, EarlyView.
This study explores the mechanistic investigation into an unusual reactivity of a thioether‐ligated low‐spin Fe(III)‐alkylperoxide with cyclohexane–carboxaldehyde as a mimic of nonheme iron(II) enzyme intermediates and highlights that only efficient catalysis happens from a high‐valent iron(IV)‐oxo species.
Jagnyesh K. Satpathy   +6 more
wiley   +2 more sources

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